Low emissions combustion apparatus and method
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
F23L-007/00
F23M-003/04
F23N-001/02
F02G-003/00
F02C-007/22
F23B-090/00
F23N-005/18
출원번호
US-0850756
(2010-08-05)
등록번호
US-8475160
(2013-07-02)
발명자
/ 주소
Campbell, Paul Andrew
Hagen, David
출원인 / 주소
Vast Power Portfolio, LLC
대리인 / 주소
Ostrolenk Faber LLP
인용정보
피인용 횟수 :
70인용 특허 :
13
초록▼
Clean combustion and equilibration equipment and methods are provided to progressively deliver, combust and equilibrate mixtures of fuel, oxidant and aqueous diluent in a plurality of combustion regions and in one or more equilibration regions to further progress oxidation of products of incomplete
Clean combustion and equilibration equipment and methods are provided to progressively deliver, combust and equilibrate mixtures of fuel, oxidant and aqueous diluent in a plurality of combustion regions and in one or more equilibration regions to further progress oxidation of products of incomplete combustion, in a manner that sustains combustion while controlling temperatures and residence times sufficiently to reduce CO and NOx emissions to below 25 ppmvd, and preferably to below 3 ppmvd at 15% O2.
대표청구항▼
1. A method of reducing pollutants within a hot reaction fluid formed by reacting reactant fluid comprising a reactant with oxidant fluid comprising an oxidant, diluted by diluent fluid comprising a diluent, within a reaction system having an upstream primary reaction region and a downstream equilib
1. A method of reducing pollutants within a hot reaction fluid formed by reacting reactant fluid comprising a reactant with oxidant fluid comprising an oxidant, diluted by diluent fluid comprising a diluent, within a reaction system having an upstream primary reaction region and a downstream equilibration system having a first equilibration region; the method comprising: generating hot reaction fluid within the primary reaction region;equilibrating the hot reaction fluid within the equilibration system for a residence time greater than a prescribed residence time; andreducing the temperature of the hot reaction fluid within the equilibration system to less than a prescribed temperature at the system outlet;wherein configuring the fluid composition, temperature, residence sequential flow profile sufficiently:to reduce the volume concentration of unreacted reactant components in the hot reaction fluid at the system outlet to less than 25 pmvd at a 15% O2 basis;to reduce the volume concentration of residual dissociated reaction product in the hot reaction fluid at the system outlet to less than 25 pmvd at a 15% O2 basis; andto constrain the volume concentration of byproduct oxidation components formed within the reaction system to less than 25 ppmvd at a 15% O2 basis at the reaction system outlet. 2. The pollutant reduction method of claim 1 wherein the reaction comprises combustion, of fuel fluid comprising a fuel, with oxidant fluid comprising oxygen, diluted by diluent fluid comprising one of water and carbon dioxide, within a combustion system having an upstream primary combustion region and a downstream equilibration system having a first equilibration region; the method comprising: generating hot combustion fluid within the primary combustion region;equilibrating the hot combustion fluid within the equilibration system for a residence time greater than 0.5 ms;reducing the temperature of the hot combustion fluid within the equilibration system by at least 5° C. to less than 1700° C. at the system outlet;wherein configuring the fluid composition, temperature, residence sequential flow profile sufficiently:to reduce the volume concentration of unburned hydrocarbons (UHC) in the equilibrated reaction fluid at the system outlet to less than 25 pmvd at a 15% O2 basis;to reduce the volume concentration of residual carbon monoxide (CO) in the equilibrated fluid at the system outlet to less than 25 pmvd at a 15% O2 basis; andto constrain the volume concentration of byproduct nitrogen oxides (NOx) formed within The equilibration system to less than 25 ppmvd at a 15% O2 basis at the system outlet. 3. The method of claim 2, wherein reducing the fluid temperature comprises flowing diluent fluid comprising added water through an inlet to said equilibration region. 4. The method of claim 3, wherein the equilibration residence time of hot combustion fluid in the system increased to accommodate longer equilibration rates for cooler fluids and lower residual oxidant, than with equivalent systems configured for diluents not comprising water. 5. The method of claim 3, wherein the mass delivery flow rate of water added to said equilibration system is greater than 1% of the hot combustion fluid flow. 6. The method of claim 2, wherein the increase in volume concentration of byproduct NOx within the equilibration system is less than 3 ppmvd at a 15% O2 basis. 7. The method of claim 2, wherein volume concentration of carbon monoxide (CO) exiting the equilibration system is less the CO concentration entering the equilibration system. 8. The method of claim 2, wherein the residual volume concentration of carbon monoxide (CO) exiting the equilibration system is less than 5 ppmvd at a 15% O2 basis. 9. The method of claim 1, wherein equilibrating the hot reaction fluid comprises providing a burnout period to oxidize unreacted reactant components to below a prescribed level. 10. The method of claim 1, wherein the primary reaction system comprises a plurality of primary reaction regions in streamwise sequence, the reaction regions having a critical temperature TCRIT at which the reaction is neutrally stable between a self-ignition temperature TIGN and an adiabatic temperature TADIAB bounding stable and conditionally stable regions, the method comprising the steps of: flowing unreacted oxidant, fuel, and diluent fluids into the plurality of primary reaction regions at respective mass delivery flow ratios of unreacted fluids to hot reaction fluid, whereby forming a plurality of mixed hot reaction fluids,controlling the mass flow delivery ratios to between 0.25 and 1.50 times the critical delivery flow ratio RCRIT for each of said primary reaction regions;controlling the mean temperature of the mixed hot reaction fluid in each of said regions above its ignition temperature and below the adiabatic temperature of oxidant and fuel combustion;controlling one of the composition and the temperature of the fluids delivered to said regions to maintain the combustion temperature of the hot reaction fluid exiting the most downstream of said regions to less than 1700° C.;characterized in that the volume concentration of byproduct reaction components produced by the method is less than 25 ppmvd at a 15% O2 basis. 11. The method of claim 10, wherein controlling the temperature in said plurality of combustion regions to within 33% and 67% of the temperature range between the ignition temperature and adiabatic reaction of said fluid as it exits said plurality of reaction regions by one of controlling the mass delivery flow ratio, controlling the amount of diluent, controlling the amount of air, and controlling the amount of fuel. 12. The method of claim 10, wherein controlling fluid delivery to maintain said mass delivery flow ratio R to less than the critical delivery flow ratio RCRIT in said plurality of regions; and maintaining the temperature of the hot reaction fluid in said plurality of regions to greater than or equal to the critical temperature TCRIT. 13. The method of claim 10, wherein the step of controlling the temperature, includes controlling a temperature in a region within a range including at least some time below the critical temperature TCRIT by controlling the mass delivery flow ratio within a range including at least some time above the critical delivery flow ratio RCRIT. 14. The method of claim 10, wherein controlling the temperature comprises increasing the temperature of the hot reaction fluid in one of said plurality of regions by decreasing said mass delivery flow ratio into said region to a level lower than the critical delivery flow ratio RCRIT, when the temperature of the hot reaction fluid entering the region is less than the critical temperature TCRIT. 15. The method of claim 10, wherein controlling the temperature comprises decreasing the temperature of the hot reaction fluid in one of said plurality of regions by increasing said mass delivery flow ratio into said region to a level higher than the critical flow ratio RCRIT, when the temperature of the hot fluid entering the region is greater than the critical temperature TCRIT. 16. The method of claim 10, comprising flowing diluent fluid and reactant fluid into one of said regions with a mass delivery flow ratio of diluent to fuel of 150% or more. 17. The method of claim 10, wherein adding unreacted fluids to said plurality of regions comprises controlling the delivery of unreacted fluid into the plurality of regions such that a progressive streamwise integrated delivery flow ratio of said fluid is less than or equal to the progressive integrated critical delivery flow ratio RCRIT for the corresponding fluid compositions. 18. The method of claim 10, wherein controlling the mean fluid temperature in the plurality of regions by controlling the diluent mass delivery flow rate relative to the reaction heat released within the plurality of regions. 19. The method of claim 10, wherein delivering fluids to the reaction regions comprises changing the oxidant to reactant ratio in the mixed reaction fluid from an excess of reactant in an upstream reaction region to an excess of oxidant in a downstream reaction region. 20. The method of claim 1, wherein the temperature of the equilibrated hot reaction fluid as it exits the reaction system is controlled to less than about 1300° C. and greater than about 800° C. 21. The method of claim 1, wherein equilibrating the hot reaction fluid comprises delivering and mixing oxidant fluid with the hot reaction fluid in the equilibration region. 22. The method of claim 1, wherein controlling the delivery of oxidant fluid and reactant fluid into said primary combustion region such that the ratio of oxidant to fuel is less than the stoichiometric ratio. 23. The method of claim 1, wherein at least 75% of said temperature reduction occurs in less than 50% of the streamwise fluid path length of said equilibration region. 24. The method of claim 1, wherein reducing the temperature during equilibration by greater than 100° C. 25. The method of claim 1, comprising controlling delivery of fuel, oxidant, and diluent fluids to progressively combust fuel under fuel “rich” conditions while controlling composition to operate within a combustion stability boundaries and below byproduct or NOx production boundaries.
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이 특허에 인용된 특허 (13)
Dobbeling Klaus (Nussbaumen CHX) Knopfel Hans P. (Besenburen CHX) Sattelmayer Thomas (Mandach CHX), Combustion process for atmospheric combustion systems.
Schneider, Anton; Morgenthaler, Klaus; Burkard, Moritz; Dittmann, Rolf, Control of primary measures for reducing the formation of thermal nitrogen oxides in gas turbines.
Toon, Ian J.; O'Dell, Stephen J.; Currin, John H.; Willis, Jeffrey D., Staged gas turbine combustion chamber with counter swirling arrays of radial vanes having interjacent fuel injection.
Moreno Frederick E. (Los Altos CA) Joshi Narendra D. (Phoenix AZ), Staged lean premix low nox hot wall gas turbine combustor with improved turndown capability.
Roberts Richard (Marlborough CT) Vranos Alexander (Rockville CT) Schlein Barry C. (Wethersfield CT) Rummel David H. (Manchester CT), Two-stage premixed combustor.
Minta, Moses; Mittricker, Franklin F.; Rasmussen, Peter C.; Starcher, Loren K.; Rasmussen, Chad C.; Wilkins, James T.; Meidel, Jr., Richard W., Low emission power generation and hydrocarbon recovery systems and methods.
Oelkfe, Russell H.; Huntington, Richard A.; Mittricker, Franklin F., Low emission power generation systems and methods incorporating carbon dioxide separation.
Minto, Karl Dean; Denman, Todd Franklin; Mittricker, Franklin F.; Huntington, Richard Alan, Method and system for combustion control for gas turbine system with exhaust gas recirculation.
Mittricker, Franklin F.; Starcher, Loren K.; Rasmussen, Chad C.; Huntington, Richard A.; Hershkowitz, Frank, Methods and systems for controlling the products of combustion.
Mittricker, Franklin F.; Starcher, Loren K.; Rasmussen, Chad; Huntington, Richard A.; Hershkowitz, Frank, Methods and systems for controlling the products of combustion.
Mittricker, Franklin F.; Huntington, Richard A.; Starcher, Loren K.; Sites, Omar Angus, Methods of varying low emission turbine gas recycle circuits and systems and apparatus related thereto.
Wichmann, Lisa Anne; Simpson, Stanley Frank, Methods, systems and apparatus relating to combustion turbine power plants with exhaust gas recirculation.
Huntington, Richard A.; Denton, Robert D.; McMahon, Patrick D.; Bohra, Lalit K.; Dickson, Jasper L., Processing exhaust for use in enhanced oil recovery.
Gupta, Himanshu; Huntington, Richard; Minta, Moses K.; Mittricker, Franklin F.; Starcher, Loren K., Stoichiometric combustion of enriched air with exhaust gas recirculation.
Denton, Robert D.; Gupta, Himanshu; Huntington, Richard; Minta, Moses; Mittricker, Franklin F.; Starcher, Loren K., Stoichiometric combustion with exhaust gas recirculation and direct contact cooler.
Stoia, Lucas John; DiCintio, Richard Martin; Melton, Patrick Benedict; Romig, Bryan Wesley; Slobodyanskiy, Ilya Aleksandrovich, System and method for a multi-wall turbine combustor.
Huntington, Richard A.; Minto, Karl Dean; Xu, Bin; Thatcher, Jonathan Carl; Vorel, Aaron Lavene, System and method for a stoichiometric exhaust gas recirculation gas turbine system.
Valeev, Almaz Kamilevich; Ginesin, Leonid Yul'evich; Shershnyov, Borys Borysovich; Sidko, Igor Petrovich; Meshkov, Sergey Anatolievich, System and method for a turbine combustor.
Slobodyanskiy, Ilya Aleksandrovich; Davis, Jr., Lewis Berkley; Minto, Karl Dean, System and method for barrier in passage of combustor of gas turbine engine with exhaust gas recirculation.
Minto, Karl Dean; Slobodyanskiy, Ilya Aleksandrovich; Davis, Jr., Lewis Berkley; Lipinski, John Joseph, System and method for controlling the combustion process in a gas turbine operating with exhaust gas recirculation.
Huntington, Richard A.; Dhanuka, Sulabh K.; Slobodyanskiy, Ilya Aleksandrovich, System and method for diffusion combustion in a stoichiometric exhaust gas recirculation gas turbine system.
Huntington, Richard A.; Dhanuka, Sulabh K.; Slobodyanskiy, Ilya Aleksandrovich, System and method for diffusion combustion with fuel-diluent mixing in a stoichiometric exhaust gas recirculation gas turbine system.
Huntington, Richard A.; Dhanuka, Sulabh K.; Slobodyanskiy, Ilya Aleksandrovich, System and method for diffusion combustion with oxidant-diluent mixing in a stoichiometric exhaust gas recirculation gas turbine system.
Subramaniyan, Moorthi; Hansen, Christian Michael; Huntington, Richard A.; Denman, Todd Franklin, System and method for exhausting combustion gases from gas turbine engines.
Huntington, Richard A.; Dhanuka, Sulabh K.; Slobodyanskiy, Ilya Aleksandrovich, System and method for load control with diffusion combustion in a stoichiometric exhaust gas recirculation gas turbine system.
Huntington, Richard A.; Mittricker, Franklin F.; Starcher, Loren K.; Dhanuka, Sulabh K.; O'Dea, Dennis M.; Draper, Samuel D.; Hansen, Christian M.; Denman, Todd; West, James A., System and method for oxidant compression in a stoichiometric exhaust gas recirculation gas turbine system.
Biyani, Pramod K.; Leyers, Scott Walter; Miranda, Carlos Miguel, System and method for protecting components in a gas turbine engine with exhaust gas recirculation.
Biyani, Pramod K.; Saha, Rajarshi; Dasoji, Anil Kumar; Huntington, Richard A.; Mittricker, Franklin F., System and method for protecting components in a gas turbine engine with exhaust gas recirculation.
Stoia, Lucas John; Romig, Bryan Wesley; Johnson, Thomas Edward; Stevenson, Christian Xavier, System and method for supplying a working fluid to a combustor.
O'Dea, Dennis M.; Minto, Karl Dean; Huntington, Richard A.; Dhanuka, Sulabh K.; Mittricker, Franklin F., System and method of control for a gas turbine engine.
Chen, Wei; Melton, Patrick Benedict; DeForest, Russell; Stoia, Lucas John; DiCintio, Richard Martin, System for supplying a fuel and a working fluid through a liner to a combustion chamber.
Oelfke, Russell H.; Huntington, Richard A.; Dhanuka, Sulabh K.; O'Dea, Dennis M.; Denton, Robert D.; Sites, O. Angus; Mittricker, Franklin F., Systems and methods for carbon dioxide capture in low emission combined turbine systems.
Thatcher, Jonathan Carl; West, James A.; Vorel, Aaron Lavene, Systems and methods for controlling exhaust gas flow in exhaust gas recirculation gas turbine systems.
Mittricker, Franklin F.; Huntington, Richard A.; Dhanuka, Sulabh K.; Sites, Omar Angus, Systems and methods for controlling stoichiometric combustion in low emission turbine systems.
Borchert, Bradford David; Trout, Jesse Edwin; Simmons, Scott Robert; Valeev, Almaz; Slobodyanskiy, Ilya Aleksandrovich; Sidko, Igor Petrovich; Ginesin, Leonid Yul'evich, Systems and methods for high volumetric oxidant flow in gas turbine engine with exhaust gas recirculation.
Vorel, Aaron Lavene; Thatcher, Jonathan Carl, Systems and methods of estimating a combustion equivalence ratio in a gas turbine with exhaust gas recirculation.
Thatcher, Jonathan Carl; Slobodyanskiy, Ilya Aleksandrovich; Vorel, Aaron Lavene, Systems and methods to respond to grid overfrequency events for a stoichiometric exhaust recirculation gas turbine.
Allen, Jonathan Kay; Borchert, Bradford David; Trout, Jesse Edwin; Slobodyanskiy, Ilya Aleksandrovich; Valeev, Almaz; Sidko, Igor Petrovich; Subbota, Andrey Pavlovich, Turbine system with exhaust gas recirculation, separation and extraction.
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