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Impure aromatic carboxylic acids such as are obtained by liquid phase oxidation of feed materials comprising aromatic compounds with substituent groups oxidizable to carboxylic acid groups, or comprising aromatic carboxylic acid and one or more aromatic carbonyl impurities that form hydrogenated spe

Impure aromatic carboxylic acids such as are obtained by liquid phase oxidation of feed materials comprising aromatic compounds with substituent groups oxidizable to carboxylic acid groups, or comprising aromatic carboxylic acid and one or more aromatic carbonyl impurities that form hydrogenated species more soluble in aqueous solvents or with less color or color-forming tendencies than the aromatic carbonyl impurity, are purified to an aromatic carboxylic acid product with lower levels of impurities by a process comprising contacting an aqueous solution comprising the impure aromatic carboxylic acid with hydrogen at elevated temperature and pressure with an attrition-resistance, acid stable catalyst composition comprising at least one hydrogenation catalyst metal and a support comprising relatively high surface area silicon carbide.

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1. A process for purifying an aromatic carboxylic acid comprising contacting with hydrogen under hydrogenation conditions at a temperature of about 200 to about 370° C. and in the presence of a catalyst an aqueous solution comprising an aromatic carboxylic acid, wherein the catalyst comprises partic

1. A process for purifying an aromatic carboxylic acid comprising contacting with hydrogen under hydrogenation conditions at a temperature of about 200 to about 370° C. and in the presence of a catalyst an aqueous solution comprising an aromatic carboxylic acid, wherein the catalyst comprises particulates comprising a Group VIII hydrogenation catalyst metal disposed substantially on the surface of a support comprising silicon carbide having a BET surface area of at least about 10 m2/g and the catalyst has an initial attrition loss according to ASTM D-4058 up to about 1.2 wt % and the silicon carbide is stable in the aqueous solution under the hydrogenation reaction conditions such that stability of the catalyst is indicated by weight loss of less than about 2 wt % after 20 days exposure to an aqueous 20 wt % solution of terephthalic acid solution at about 275° C. and 850 psig. 2. The process of claim 1 wherein the catalyst contains about 0.1 to about 5 wt % hydrogenation catalyst metal. 3. The process of claim 2 wherein the hydrogenation catalyst metal comprises palladium. 4. The process of claim 1 wherein the aromatic carboxylic acid comprises terephthalic acid. 5. The process of claim 1 wherein the aromatic carboxylic acid comprises a crude aromatic carboxylic acid product obtained by liquid phase oxidation of a feed material comprising an aromatic compound with one or more substituents oxidizable to a carboxylic acid group and comprises aromatic carboxylic acid and at least one oxidation intermediate or by-product. 6. The process of claim 5 wherein the crude aromatic carboxylic acid product comprises terephthalic acid. 7. The process of claim 1 wherein the aromatic carboxylic acid comprises aromatic carboxylic acid and at least one aromatic carbonyl compound that forms a hydrogenated compound more soluble in aqueous solution than the aromatic carbonyl compound and than the aromatic carboxylic acid or with less color or color-forming tendencies. 8. The process of claim 7 wherein the aromatic carbonyl compound comprises at least one of benzaldehyde, 2-, 3- and 4-carboxybenzaldehyde, 2,6-dicarboxyfluorenone and 2,6-dicarboxyanthroquinone. 9. The process of claim 1 further comprising separating from the hydrogenated aqueous reaction liquid a solid aromatic carboxylic acid product. 10. A process for manufacture of a purified aromatic carboxylic acid product comprising steps comprising contacting a feed material comprising an aromatic compound with oxidizable substituents with oxygen in the presence of a heavy metal catalyst in a liquid reaction mixture under oxidation reaction conditions;separating from the liquid reaction mixture a crude product comprising aromatic carboxylic acid and at least one oxidation intermediate or by-product;forming an aqueous solution comprising the crude product;contacting the aqueous solution with hydrogen in the presence of a catalyst in particulate form under hydrogenation reaction conditions at a temperature of about 200 to about 370° C., wherein the catalyst particles comprise a Group VIII hydrogenation catalyst metal disposed substantially on the surface of a support comprising silicon carbide having a BET surface area of at least about 10 m2/g, the catalyst has an initial attrition loss according to ASTM D-4058 up to about 1.2 wt % and the silicon carbide is stable in the aqueous solution under the hydrogenation reaction conditions such that stability of the catalyst is indicated by weight loss of less than about 2 wt % after 20 days exposure to an aqueous 20 wt % solution of terephthalic acid solution at about 275° C. and 850 psig. 11. The process of claim 10 wherein the oxidation intermediate or by-product comprises at least one carboxybenzaldehyde. 12. The process of claim 10 wherein the oxidation intermediate or by-product comprises 4-carboxybenzaldehyde. 13. The process of claim 12 wherein the catalyst metal comprises palladium. 14. The process of claim 10 wherein the catalyst has a BET surface area of at least about 20 m2 μg. 15. A process for purification of an aromatic carboxylic acid product comprising terephthalic acid and at least one impurity comprising 4-carboxybenzaldehyde, hydroxymethyl benzoic acid, p-toluic acid, 2,6-dicarboxyfluorenone, 2,6-dicarboxyanthroquinone, 2,4′,5-tricarboxybiphenyl, 2,5-dicarboxyphenyl-4-carboxyphenyl methane, 3,4′- and 4,4′-dicarboxybiphenyl, and 2,6-dicarboxyfluorene comprising contacting an aqueous solution of the product with hydrogen in the presence of a catalyst in particulate form under hydrogenation reaction conditions at a temperature of about 200 to about 370° C., wherein the catalyst particles comprises a Group VIII hydrogenation catalyst metal disposed substantially on the surface of a support comprising silicon carbide having a BET surface area of at least about 10 m2/g, the catalyst has an initial attrition loss according to ASTM D-4058 up to about 1.2 wt % and the silicon carbide is stable in the aqueous solution under the hydrogenation reaction conditions such that stability of the catalyst is indicated by weight loss of less than about 2 wt % after 20 days exposure to an aqueous 20 wt % solution of terephthalic acid solution at about 275° C. and 850 psig; and recovering from the hydrogenated aqueous solution a purified terephthalic acid. 16. A process for manufacture of terephthalic acid in purified form comprising steps comprising contacting under oxidation reaction conditions a feed material comprising p-xylene with oxygen in the presence of a heavy metal catalyst in a liquid reaction mixture that includes a solvent comprising a low molecular weight monocarboxylic acid and water;separating from the liquid reaction mixture a crude product comprising terephthalic acid and at least one oxidation intermediate or by-product;forming an aqueous solution comprising about 5 to about 50 parts by weight of the crude product per hundred parts by weight solution at process temperature;contacting the aqueous solution with hydrogen in the presence of a catalyst in particulate form at a temperature of about 200 to about 370° C. under pressure effective to maintain a liquid phase comprising the reaction solution, wherein the catalyst particles comprise a Group VIII hydrogenation catalyst metal disposed substantially on the surface of a support comprising silicon carbide having a BET surface area of at least about 10 m2/g, the catalyst has an initial attrition loss according to ASTM D-4058 up to about 1.2 wt % and the silicon carbide is stable in the aqueous solution under the hydrogenation reaction conditions such that stability of the catalyst is indicated by weight loss of less than about 2 wt % after 20 days exposure to an aqueous 20 wt % solution of terephthalic acid solution at about 275° C. and 850 psig; andrecovering from the hydrogenated aqueous solution a purified terephthalic acid with a reduced oxidation intermediate or by-product content.