A two-part epoxy-based structural adhesive composition comprising a curable epoxy resin, an amine curing agent, a toughening agent, and an oil-displacing agent. The structural adhesive may optionally include reactive liquid modifiers, fillers, secondary curatives, reactive diluents, surfactants, met
A two-part epoxy-based structural adhesive composition comprising a curable epoxy resin, an amine curing agent, a toughening agent, and an oil-displacing agent. The structural adhesive may optionally include reactive liquid modifiers, fillers, secondary curatives, reactive diluents, surfactants, metal salts, pigments and combinations thereof. The structural adhesive may be used to form bonded joints between adherends having clean surfaces, as well as those having surfaces contaminated with hydrocarbon-containing materials, such as oils, processing aids and lubricating agents.
대표청구항▼
1. A two-part adhesive composition having a first part and a second part, the adhesive composition comprising: a curable epoxy resin in the first part;an amine curing agent in the second part;a toughening agent in the first part, the second part, or combination thereof;an oil displacing agent in the
1. A two-part adhesive composition having a first part and a second part, the adhesive composition comprising: a curable epoxy resin in the first part;an amine curing agent in the second part;a toughening agent in the first part, the second part, or combination thereof;an oil displacing agent in the first part, the second part, or combination thereof, wherein the solubility parameter of the oil displacing agent ranges from 7 to 10.5 cal0.5/cm3/2; anda filler in the first part, the second part, or combination thereof, wherein the filler comprises an inorganic mineral fiber comprising from about 37% to about 42% by weight SiO2, from about 18% to about 23% by weight Al2O3, from about 34% to about 39% by weight CaO+MgO, from 0% to about 1% by weight FeO, and about 3% by weight K2O+Na2O;wherein an adhesive is formed when the first part and the second part are combined. 2. The composition of claim 1 wherein the curable epoxy resin comprises a diglycidylether of bisphenol A. 3. The composition of claim 1 wherein the toughening agent comprises a core/shell polymer, an acrylic polymer, a butadiene nitrile rubber or combinations thereof. 4. The composition of claim 1 wherein the toughening agent comprises a core/shell polymer having a core comprising a butadiene polymer, a butadiene copolymer, a styrene polymer, a styrene copolymer or a butadiene-styrene copolymer and a shell comprising a polyacrylate polymer or a polyacrylate copolymer. 5. The composition of claim 1 wherein the oil-displacing agent has a surface tension less than about 35 mN/m. 6. The composition of claim 1 wherein the oil-displacing agent comprises 1,8-cineole, α-pinene oxide, limonene oxide, C1-C10 glycidyl ethers or combinations thereof. 7. The composition of claim 1 wherein the curable epoxy resin has one or more epoxy moieties and the amine curing agent has one or more amine hydrogens and the molar ratio of epoxy moieties on the curable epoxy resin to amine hydrogens on the amine curing agent ranges from about 0.5:1 to about 3:1. 8. The composition of claim 1 further comprising a reactive liquid modifier in the first part, the second part or combination thereof. 9. The composition of claim 8 wherein the reactive liquid modifier comprises a tri-acetoacetate functional ester or an oxamido ester-terminated polypropylene oxide. 10. The composition of claim 1, wherein the filler in the first part, the second part, or combination thereof further comprises an organic fiber, a fiber having aspherical structural, a fiber having platelet structure, or combinations thereof. 11. The composition of claim 10 wherein the filler is a high-density polyethylene fiber. 12. The composition of claim 1, wherein the composition has a lap shear measurement of at least 2500 psi and a T-peel measurement of at least 20 lbf/in-width after being cured for 18 hours at room temperature followed by 30 minutes at 180° C. 13. The composition of claim 1 further comprising a secondary curative in the first part, the second part or combination thereof. 14. A method of making a composite article, the method comprising: applying the two-part adhesive composition of claim 1 to a surface; andcuring the two-part adhesive composition in contact with the surface to form a composite article. 15. The method of claim 14, wherein the surface is contaminated with hydrocarbon-containing material. 16. The method of claim 15, wherein the oil displacing agent exhibits a surface tension lower than that of the hydrocarbon-containing material, a solubility parameter similar to that of the hydrocarbon containing material, or a combination thereof. 17. A method of forming a bonded joint between members, the method comprising: applying the two-part adhesive composition of claim 1 to a surface of at least one of two or more members;joining the members so that the two-part adhesive composition is sandwiched between the two or more members; andcuring the two-part adhesive composition to form a bonded joint between the two or more members. 18. The method of claim 17, wherein the surface of at least one of the two or more members is contaminated with hydrocarbon-containing material. 19. The method of claim 18, wherein the oil displacing agent exhibits a surface tension lower than that of the hydrocarbon-containing material, a solubility parameter similar to that of the hydrocarbon containing material, or a combination thereof.
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