초록 ▼

There is provided a technique and an apparatus for manufacturing a hydrogen-containing gas. An oxygen-containing gas is mixed with a feed gas obtained by mixing steam with a hydrocarbon fuel, this mixture is introduced into a catalytic reaction chamber, and a partial oxidation reaction and a steam r

There is provided a technique and an apparatus for manufacturing a hydrogen-containing gas. An oxygen-containing gas is mixed with a feed gas obtained by mixing steam with a hydrocarbon fuel, this mixture is introduced into a catalytic reaction chamber, and a partial oxidation reaction and a steam reforming reaction are conducted to obtain a hydrogen-containing gas. In this reforming, an antechamber of the catalytic reaction chamber is heated up to a self-ignition temperature in a first catalyst section, where the self-ignition temperature is the temperature at which a mixed gas self-ignites during the advection period required for the mixed gas to move from a mixing chamber to the catalytic reaction chamber, with this temperature being at least a minimum partial-oxidation temperature and lower than a minimum steam reforming temperature.

대표청구항 ▼

1. An apparatus for manufacturing a hydrogen-containing gas, comprising: a mixing chamber having a shell-and-tube type mixing structure, said mixing chamber including, a plurality of tubes into which a feed gas which is a mixture of steam and a hydrocarbon fuel flows, and an oxygen-containing gas ch

1. An apparatus for manufacturing a hydrogen-containing gas, comprising: a mixing chamber having a shell-and-tube type mixing structure, said mixing chamber including, a plurality of tubes into which a feed gas which is a mixture of steam and a hydrocarbon fuel flows, and an oxygen-containing gas chamber provided on the outside, the mixing chamber providing mixing of the feed gas present in the tubes with an oxygen-containing gas so as to form a mixed gas;a catalytic reaction chamber including a first catalyst section containing a first reforming catalyst that catalyzes a partial oxidation reaction and a second catalyst section provided on the downstream side of the first catalyst section and containing a second reforming catalyst that catalyzes a partial oxidation reaction and a steam reforming reaction;an antechamber provided at an inlet of the catalytic reaction chamber, the antechamber communicating the mixing chamber with the catalytic reaction chamber and being configured to hold the mixed gas therein for a period required for the mixed gas to move from the mixing chamber to the catalytic reaction chamber, said antechamber including, an introduction section provided between solid outer peripheral portions with the tubes of the mixing chamber extending therethrough, and an adjustment section configured to introduce the mixed gas from the introduction section to the first catalytic section;a guiding means for guiding the mixed gas from the mixing chamber to the catalytic reaction chamber via the tubes and the adjustment section(s) so that the mixed gas is brought into contact with the first and second reforming catalysts to generate a hydrogen-containing gas through a partial oxidation reaction and a steam reforming reaction of the mixed gas in the catalyst reaction chamber;an antechamber temperature setting means for setting the temperature of the antechamber to a predetermined antechamber temperature which is equal to or higher than a minimum partial oxidation temperature and below a self-ignition temperature which is the temperature at which the mixed gas self-ignites during said period, said minimum partial oxidation temperature being the minimum temperature at which the first reforming catalyst catalyzes the partial oxidation reaction; andsaid first reforming catalyst of said first catalyst section having a first reforming catalyst concentration set to render an outlet temperature of said first catalyst section higher than a temperature at which said second reforming catalyst catalyzes the partial oxidation reaction in response to the setting of said predetermined antechamber temperature by said antechamber temperature setting means. 2. The apparatus for manufacturing a hydrogen-containing gas according to claim 1, wherein the first reforming catalyst is a reforming catalyst selected from the group consisting of ruthenium platinum, and combinations thereof, and the second reforming catalyst is selected from the group consisting of nickel, rhodium, and ruthenium, and combinations thereof. 3. The apparatus for manufacturing a hydrogen-containing gas according to claim 1 or 2, further comprising a heat blocking layer with lower thermal conduction characteristics than the first catalyst section provided between the first catalyst section and the second catalyst section. 4. The apparatus for manufacturing a hydrogen-containing gas according to claim 1 or 2, wherein an inert member that has no catalytic activity is mixed with the first catalyst section to create a suitable state of temperature elevation for the first catalyst. 5. The apparatus for manufacturing a hydrogen-containing gas according to claim 1 or 2, further comprising a desulfurization apparatus that allows the sulfur compound concentration of the mixed gas introduced into the catalyst reaction chamber to be 1 ppb or less.