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A system and method for the conversion of free fatty acids to glycerides and the subsequent conversion of glycerides to glycerin and biodiesel includes the transesterification of a glyceride stream with an alcohol. The fatty acid alkyl esters are separated from the glycerin to produce a first liquid

A system and method for the conversion of free fatty acids to glycerides and the subsequent conversion of glycerides to glycerin and biodiesel includes the transesterification of a glyceride stream with an alcohol. The fatty acid alkyl esters are separated from the glycerin to produce a first liquid phase containing a fatty acid alkyl ester rich (concentrated) stream and a second liquid phase containing a glycerin rich (concentrated) stream. The fatty acid alkyl ester rich stream is then subjected to distillation, preferably reactive distillation, wherein the stream undergoes both physical separation and chemical reaction. The fatty acid alkyl ester rich stream is then purified to produce a purified biodiesel product and a glyceride rich residue stream. Neutralization of the alkaline stream, formed during the alkali-catalyzed transesterfication process, may proceed by the addition of a mineral or an organic acid.

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1. A process for the production of purified biodiesel from glycerides comprising: (A) reacting glycerides with at least one alcohol in a transesterification reaction to produce a fatty acid alkyl ester stream;(B) purifying the fatty acid alkyl ester stream by reactive distillation, wherein the react

1. A process for the production of purified biodiesel from glycerides comprising: (A) reacting glycerides with at least one alcohol in a transesterification reaction to produce a fatty acid alkyl ester stream;(B) purifying the fatty acid alkyl ester stream by reactive distillation, wherein the reactive distillation involves separating fatty acid alkyl esters from glycerin and unreacted alcohol while simultaneously reacting glycerin with fatty acids to produce glycerides; and(C) producing purified biodiesel therefrom. 2. The process of claim 1, wherein the glycerides of step (A) are produced by converting fatty acids in a feedstock. 3. The process of claim 2, wherein the glycerides are prepared by mixing the feedstock and glycerin at an elevated temperature in the absence of a catalyst. 4. The process of claim 1, wherein step (A) comprises reacting the glycerides with the at least one alcohol in the presence of an alkali catalyst to produce a fatty acid alkyl ester stream containing glycerin and fatty acid alkyl esters. 5. The process of claim 2, wherein the feedstock is conditioned to remove solids prior to converting the feedstock to glycerides. 6. The process of claim 1, wherein the product of step (A) is separated gravimetrically into a fatty acid ester rich stream and a glycerin rich stream and further introducing to the glycerin rich stream an organic acid and producing a purified glycerin rich stream therefrom. 7. The process of claim 6, wherein the organic acid is a weak organic acid selected from the group consisting of acetic acid, formic acid and propionic acid. 8. The process of claim 7, wherein the weak organic acid is acetic acid. 9. The process of claim 1, wherein the at least one alcohol is a C1-C5 alcohol. 10. The process of claim 9, wherein the C1-C5 alcohol is methanol. 11. The process of claim 1, wherein the fatty acids are provided by fatty acid alkyl esters. 12. A process for the production of purified biodiesel from glycerides comprising: (A) reacting glycerides with at least one alcohol in a transesterification reaction to produce a fatty acid alkyl ester stream;(B) purifying the fatty acid alkyl ester stream by reactive distillation, wherein the reactive distillation involves separating fatty acid alkyl esters from glycerin and unreacted alcohol while simultaneously reacting glycerin with fatty acid alkyl esters to produce glycerides; and(C) producing purified biodiesel therefrom. 13. A process for producing biodiesel from glycerides comprising: (A) reacting glycerides with at least one alcohol in a transesterification reaction to produce a transesterification effluent stream of fatty acid esters and glycerin;(B) separating the transesterification effluent stream into a fatty acid ester rich stream and a glycerin rich stream;(C) introducing an organic acid to at least one of the: (i.) transesterification effluent stream, and(ii.) glycerin rich stream; and(E) recovering biodiesel therefrom. 14. The process of claim 13, wherein the process is continuous. 15. The process of claim 13, wherein the glycerides of step (A) are obtained by reacting a feedstock containing free fatty acids with glycerin. 16. The process of claim 13, wherein the glycerides in step (A) are reacted with the at least one alcohol in the presence of an alkali catalyst. 17. The process of claim 13, wherein the at least one alcohol is a C1-C5 alcohol. 18. The process of claim 15, wherein the C1-C5 alcohol is methanol. 19. The process of claim 18, wherein the alkali catalyst is selected from the group consisting of sodium hydroxide and potassium hydroxide. 20. The process of claim 18, wherein the alkali catalyst is selected from the group consisting of sodium methoxide and potassium methoxide.