[미국특허]
System and method for catalyst preparation
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-019/00
C08F-002/00
출원번호
US-0655024
(2012-10-18)
등록번호
US-8821800
(2014-09-02)
발명자
/ 주소
Benham, Elizabeth A
Masino, Albert P
Yang, Qing
Muninger, Randy S
Gonzales, Rebecca A
출원인 / 주소
Chevron Phillips Chemical Company LP
대리인 / 주소
Fletcher Yoder P.C.
인용정보
피인용 횟수 :
1인용 특허 :
7
초록▼
Techniques are provided for catalyst preparation. A system for catalyst preparation may include an agitator disposed inside a polymerization catalyst tank and configured to mix a polymerization catalyst and a solvent to generate a polymerization catalyst solution. The system may also include a heati
Techniques are provided for catalyst preparation. A system for catalyst preparation may include an agitator disposed inside a polymerization catalyst tank and configured to mix a polymerization catalyst and a solvent to generate a polymerization catalyst solution. The system may also include a heating system coupled to the polymerization catalyst tank and configured to maintain a temperature of the polymerization catalyst solution above a threshold. The system may also include a precontactor configured to receive feed streams comprising an activator and the polymerization catalyst solution from the polymerization catalyst tank to generate a catalyst complex. The system may also include a transfer line configured to transfer the catalyst complex from an outlet of the precontactor to a reactor.
대표청구항▼
1. A system, comprising: a polymerization catalyst tank comprising a polymerization catalyst and a solvent;an agitator disposed inside the polymerization catalyst tank, wherein the agitator actively mixes the polymerization catalyst and the solvent to generate a polymerization catalyst solution when
1. A system, comprising: a polymerization catalyst tank comprising a polymerization catalyst and a solvent;an agitator disposed inside the polymerization catalyst tank, wherein the agitator actively mixes the polymerization catalyst and the solvent to generate a polymerization catalyst solution when the agitator is in operation;a heating system coupled to the polymerization catalyst tank and configured to maintain a temperature of the polymerization catalyst solution above a threshold within the polymerization catalyst tank;a precontactor configured to receive feed streams comprising an activator and the polymerization catalyst solution from the polymerization catalyst tank to generate a catalyst complex, the precontactor comprising the activator and the polymerization catalyst solution mixed with one another in the form of the catalyst complex; anda transfer line comprising the catalyst complex, wherein the transfer line transfers the catalyst complex from an outlet of the precontactor to a reactor when the transfer line is in operation. 2. The system of claim 1, wherein the precontactor comprises: a second agitator disposed inside the precontactor, wherein the second agitator actively mixes the activator and polymerization catalyst solution when the second agitator is in operation; anda second heating system coupled to the precontactor and configured to maintain a temperature of the catalyst complex within the precontactor above a second threshold. 3. The system of claim 1, comprising the reactor configured to polymerize monomer into polymer solids in the presence of the catalyst complex and including the polymer solids therein. 4. The system of claim 3, comprising a plurality of reactors configured to polymerize monomer into polymer solids in the presence of the catalyst complex. 5. The system of claim 4, wherein the plurality of reactors are operated in a series configuration or in a parallel configuration. 6. The system of claim 1, wherein the polymerization catalyst comprises a metallocene catalyst. 7. The system of claim 1, wherein the solvent comprises a comonomer. 8. The system of claim 7, wherein the comonomer comprises 1-hexene. 9. The system of claim 1, wherein the precontactor comprises a cocatalyst. 10. The system of claim 9, wherein the cocatalyst comprises triisobutylaluminum, triethylaluminum, or any combination thereof. 11. The system of claim 1, wherein the activator comprises a solid super acid. 12. The system of claim 1, wherein the heating system is configured to heat a second transfer line including the polymerization catalyst solution, wherein the second transfer line transfers the polymerization catalyst solution from the polymerization catalyst tank to the precontactor when the second transfer line is in operation. 13. The system of claim 1, comprising a sensor configured to provide an indication of a concentration of the polymerization catalyst in the polymerization catalyst solution. 14. A system, comprising: one or more automation controllers configured to: receive a first input indicative of a demand for a metallocene catalyst in a metallocene catalyst tank;activate a first output to supply the metallocene catalyst to the metallocene catalyst tank, such that the metallocene catalyst and a solvent mix in the metallocene catalyst tank to form a metallocene catalyst solution;receive a second input indicative of a demand for the metallocene catalyst solution in a precontactor; andactivate a second output to supply the metallocene catalyst solution to the precontactor; such that the metallocene catalyst solution and an activator mix in the precontactor to form a metallocene catalyst complex. 15. The system of claim 14, wherein the one or more automation controllers are configured to: receive a third input indicative of a demand for the metallocene catalyst complex in a reactor; andactivate a third output to supply the metallocene catalyst complex to the reactor. 16. The system of claim 14, wherein the first and second outputs comprise a control valve actuator, a pump actuator, or any combination thereof. 17. The system of claim 14, wherein the second input comprises a concentration of the metallocene catalyst in the metallocene catalyst tank. 18. The system of claim 17, comprising a sensor configured to generate the second input, wherein the sensor comprises an ultraviolet-visible photometric analyzer. 19. The system of claim 14, wherein the one or more automation controllers are configured to: receive a fourth input indicative of a temperature of the metallocene catalyst solution in the metallocene catalyst tank; andactivate a fourth output to supply heat to the metallocene catalyst tank. 20. A system, comprising: a first polymerization catalyst tank comprising a polymerization catalyst and a solvent;a first agitator disposed inside the first polymerization catalyst tank and configured to mix the polymerization catalyst and the solvent to generate a polymerization catalyst solution;a first heating system coupled to the first polymerization catalyst tank and configured to maintain a temperature within the first polymerization catalyst tank above a threshold;a precontactor comprising an activator and the polymerization catalyst solution received from the polymerization catalyst tank, wherein the precontactor generates a catalyst complex from the polymerization catalyst solution and the activator when in use; anda transfer line comprising the catalyst complex when in use to transfer the catalyst complex from an outlet of the precontactor to a reactor. 21. The system of claim 20, comprising: a first catalyst storage tank comprising a first polymerization catalyst when in use, wherein the first catalyst storage tank is configured to supply the first polymerization catalyst to the polymerization catalyst tank; anda second catalyst storage tank comprising a second polymerization catalyst when in use, wherein the second catalyst storage tank is configured to supply the second polymerization catalyst to the polymerization catalyst tank, wherein the polymerization catalyst comprises the first and second polymerization catalyst. 22. The system of claim 20, comprising: a second polymerization catalyst tank comprising the polymerization catalyst and the solvent when in use;a second agitator disposed inside the second polymerization catalyst tank and configured to mix the polymerization catalyst and the solvent to generate the polymerization catalyst solution; anda second heating system coupled to the second polymerization catalyst tank and configured to maintain a second temperature within the second polymerization catalyst tank above the threshold, wherein the precontactor comprises the activator and the polymerization catalyst solution from the second polymerization catalyst tank when in use to generate the catalyst complex. 23. The system of claim 20, comprising: a second polymerization catalyst tank comprising the polymerization catalyst solution from the first polymerization catalyst tank when in use;a second agitator disposed inside the second polymerization catalyst tank and configured to mix the polymerization catalyst solution; anda second heating system coupled to the second polymerization catalyst tank and configured to maintain a second temperature of the polymerization catalyst solution within the second polymerization catalyst tank above the threshold.
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