Carbon dioxide separation method and apparatus
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-053/04
B01J-020/34
B01D-053/02
B01J-020/32
B01D-053/14
출원번호
US-0386219
(2010-07-22)
등록번호
US-8840704
(2014-09-23)
우선권정보
JP-2009-174513 (2009-07-27)
국제출원번호
PCT/JP2010/004691
(2010-07-22)
§371/§102 date
20120308
(20120308)
국제공개번호
WO2011/013332
(2011-02-03)
발명자
/ 주소
Shoji, Takatoshi
Kimura, Akira
Kishimoto, Teruo
출원인 / 주소
Kawasaki Jukogyo Kabushiki Kaisha
대리인 / 주소
Oliff PLC
인용정보
피인용 횟수 :
4인용 특허 :
6
초록▼
A carbon dioxide separation method and a carbon dioxide separation apparatus capable of maintaining a carbon dioxide adsorption capacity for a long term by collecting an amine compound that evaporates during an operation of the apparatus and reloading the amine compound onto a carbon dioxide adsorbe
A carbon dioxide separation method and a carbon dioxide separation apparatus capable of maintaining a carbon dioxide adsorption capacity for a long term by collecting an amine compound that evaporates during an operation of the apparatus and reloading the amine compound onto a carbon dioxide adsorbent. An amine collector and an amine aqueous solution preparation device are connected to an adsorbent-packed tank packed with a carbon dioxide adsorbent. An amine compound that evaporates from the carbon dioxide adsorbent during an operation of the apparatus is collected by the amine collector into the amine aqueous solution preparation device. The collected amine compound is reloaded onto the carbon dioxide adsorbent via a supply line.
대표청구항▼
1. A carbon dioxide separation method using a first and a second carbon dioxide adsorbent which are porous materials loaded with an amine compound, the method comprising: adsorbing carbon dioxide by causing a gas, which is to be treated, to come into contact with the first carbon dioxide adsorbent;d
1. A carbon dioxide separation method using a first and a second carbon dioxide adsorbent which are porous materials loaded with an amine compound, the method comprising: adsorbing carbon dioxide by causing a gas, which is to be treated, to come into contact with the first carbon dioxide adsorbent;desorbing, from the first carbon dioxide adsorbent by using a heated gas stream, carbon dioxide that has been adsorbed to the first carbon dioxide adsorbent; andreloading the amine compound onto the porous material of the first carbon dioxide adsorbent;cooling, by using a gas stream, the first carbon dioxide adsorbent that has been heated by the heated gas stream in the desorbing step; andintroducing the gas stream that has cooled the first carbon dioxide adsorbent to the second carbon dioxide adsorbent, and capturing, with the second carbon dioxide adsorbent, the amine compound contained in the gas stream. 2. The carbon dioxide separation method according to claim 1, further comprising collecting the amine compound that has been desorbed from the first carbon dioxide adsorbent, wherein the amine compound used in the amine reloading step includes the amine compound that has been collected in the amine collecting step. 3. The carbon dioxide separation method according to claim 2, wherein the amine collecting step comprises collecting the amine compound from the gas stream that has desorbed carbon dioxide from the first carbon dioxide adsorbent in the desorbing step. 4. The carbon dioxide separation method according to claim 1, wherein the amine compound is monoethanolamine, diethanolamine, or a mixture of monoethanolamine and diethanolamine. 5. The carbon dioxide separation method according to claim 1, wherein the heated gas stream is a mixture gas of air and steam. 6. A carbon dioxide separation apparatus using a first and a second carbon dioxide adsorbent which are porous materials loaded with an amine compound, the apparatus comprising: a first adsorbent-packed tank packed with the first carbon dioxide adsorbent;an air supplier configured to supply a gas to be treated, the gas containing carbon dioxide, to the first adsorbent-packed tank;a heated gas stream supplier configured to supply a heated gas stream for use in desorbing, from the first carbon dioxide adsorbent, carbon dioxide that has been adsorbed to the first carbon dioxide adsorbent; andan amine re-loading device configured to supply the amine compound to the porous material of the first carbon dioxide adsorbent;a second adsorbent-packed tank packed with the second carbon dioxide adsorbent;a cooling gas stream supplier configured to supply a cooling gas stream to the first carbon dioxide adsorbent from which carbon dioxide has been desorbed; andan amine collector configured to introduce the gas stream that has cooled the first carbon dioxide adsorbent to the second adsorbent-packed tank, and to capture, with the second carbon dioxide adsorbent in the second adsorbent-packed tank, the amine compound that is contained in the gas stream. 7. The carbon dioxide separation apparatus according to claim 6, further comprising: an amine collector configured to collect the amine compound that has been desorbed from the first carbon dioxide adsorbent, whereinthe amine compound used in the reloading by the amine re-loading device includes the amine compound that has been collected by the amine collector. 8. The carbon dioxide separation apparatus according to claim 7, wherein the amine collector collects the amine compound from the gas stream that has desorbed carbon dioxide from the first carbon dioxide adsorbent. 9. The carbon dioxide separation apparatus according to claim 6, wherein the amine compound is monoethanolamine, diethanolamine, or a mixture of monoethanolamine and diethanolamine. 10. The carbon dioxide separation apparatus according to claim 6, wherein the heated gas stream supplied from the heated gas stream supplier is a mixture gas of air and steam. 11. The carbon dioxide separation method according to claim 2, wherein the amine compound is monoethanolamine, diethanolamine, or a mixture of monoethanolamine and diethanolamine. 12. The carbon dioxide separation method according to claim 3, wherein the amine compound is monoethanolamine, diethanolamine, or a mixture of monoethanolamine and diethanolamine. 13. The carbon dioxide separation method according to claim 2, wherein the heated gas stream is a mixture gas of air and steam. 14. The carbon dioxide separation method according to claim 3, wherein the heated gas stream is a mixture gas of air and steam. 15. The carbon dioxide separation method according to claim 4, wherein the heated gas stream is a mixture gas of air and steam. 16. The carbon dioxide separation apparatus according to claim 7, wherein the amine compound is monoethanolamine, diethanolamine, or a mixture of monoethanolamine and diethanolamine. 17. The carbon dioxide separation apparatus according to claim 8, wherein the amine compound is monoethanolamine, diethanolamine, or a mixture of monoethanolamine and diethanolamine. 18. The carbon dioxide separation apparatus according to claim 7, wherein the heated gas stream supplied from the heated gas stream supplier is a mixture gas of air and steam. 19. The carbon dioxide separation apparatus according to claim 8, wherein the heated gas stream supplied from the heated gas stream supplier is a mixture gas of air and steam. 20. The carbon dioxide separation apparatus according to claim 9, wherein the heated gas stream supplied from the heated gas stream supplier is a mixture gas of air and steam.
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이 특허에 인용된 특허 (6)
Chuang, Steven, Amine absorber for carbon dioxide capture and processes for making and using the same.
Zinnen Hermann A. (Evanston IL) Oroskar Anil R. (Downers Grove IL) Chang Chin-Hsiung (Palatine IL), Carbon dioxide removal using aminated carbon molecular sieves.
Pennline, Henry W.; Hoffman, James S.; Gray, McMahan L.; Fauth, Daniel J.; Resnik, Kevin P., Regenerable sorbent technique for capturing CO2 using immobilized amine sorbents.
Li, Xiaobing; Thompson, Jesse G.; Liu, Kunlei, Reduction of amine emissions from an aqueous amine carbon dioxide capture system using charged colloidal gas aphrons.
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