Hydrocarbon-decomposing porous catalyst body and process for producing the same, process for producing hydrogen-containing mixed reformed gas from hydrocarbons, and fuel cell system
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C01B-003/02
C01B-003/24
C01B-003/26
H01M-008/00
B01J-023/00
B01J-023/02
B01J-023/06
B01J-023/08
B01J-023/40
B01J-023/42
B01J-023/56
B01J-023/58
B01J-020/00
B01J-021/04
B01J-037/03
B01J-023/89
B01J-035/00
B01J-035/10
B01J-037/00
C01B-003/40
B01J-037/18
B01J-037/08
H01M-010/0569
B01J-023/78
H01M-008/06
출원번호
US-0926091
(2013-06-25)
등록번호
US-8883118
(2014-11-11)
우선권정보
JP-2008-057050 (2008-03-06)
발명자
/ 주소
Takahashi, Shinji
Kobayashi, Naoya
출원인 / 주소
Toda Kogyo Corporation
대리인 / 주소
Nixon & Vanderhye P.C.
인용정보
피인용 횟수 :
6인용 특허 :
14
초록▼
A process for producing the porous catalyst body for decomposing hydrocarbons, the body containing at least magnesium, aluminum and nickel, and has a pore volume of 0.01 to 0.5 cm3/g, an average pore diameter of not more than 3006 Å and an average crushing strength of not less than 3 kgf. The proces
A process for producing the porous catalyst body for decomposing hydrocarbons, the body containing at least magnesium, aluminum and nickel, and has a pore volume of 0.01 to 0.5 cm3/g, an average pore diameter of not more than 3006 Å and an average crushing strength of not less than 3 kgf. The process includes molding hydrotalcite containing at least magnesium, aluminum and nickel, and calcining the resulting molded product at a temperature of 700 to 1500° C.
대표청구항▼
1. A process for producing a porous catalyst body for decomposing hydrocarbons which porous catalyst body comprises at least magnesium, aluminum and nickel in such a manner that the magnesium and aluminum are present in the form of a composite oxide of magnesium and aluminum, and the nickel is prese
1. A process for producing a porous catalyst body for decomposing hydrocarbons which porous catalyst body comprises at least magnesium, aluminum and nickel in such a manner that the magnesium and aluminum are present in the form of a composite oxide of magnesium and aluminum, and the nickel is present in the form of metallic nickel; and which porous catalyst body has a magnesium element content of 10 to 50% by weight, an aluminum element content of 5 to 35% by weight and a nickel element content of 0.1 to 30% by weight, a pore volume of 0.01 to 0.5 cm3/g, an average pore diameter of not more than 300 Å and an average crushing strength of not less than 3 kgf, the process comprising the steps of:mixing a hydrotalcite comprising at least magnesium, aluminum and nickel, a molding assistant, a binder and a dispersing medium to form a mixture,kneading the mixture to form a clay-like mass,molding the clay-like mass to form a molded product,calcining the molded product at a temperature of 700 to 1500° C., andsubjecting the calcined hydrotalcite molded product to a reduction treatment at a temperature of 700 to 1000° C. 2. The process according to claim 1, wherein the molding assistant is cellulose, polyvinyl alcohol, starches, methyl cellulose, maltose, carboxymethyl cellulose or mixtures thereof. 3. The process according to claim 1, wherein the binder is α-alumina, an aluminum salt, silica, clay, talc, bentonite, zeolite, cordierite, a titania alkali metal salt, an alkali earth metal salt, a rare earth metal salt, zirconia, mullite, sepiolite, montmorillonite, halloysite, saponite, stevensite, hectorite, silica alumina or mixtures thereof. 4. The process according to claim 1, wherein the dispersing medium is water, an alcohol or mixtures thereof. 5. A process for producing a mixed reformed gas comprising hydrogen from hydrocarbons, the process comprising the step of reacting the hydrocarbons with steam at a temperature of 250 to 850° C., at a molar ratio of steam to carbon (S/C) of 1.0 to 6.0 and at a space velocity (GHSV) of 100 to 100000 h−1 in the presence of the porous catalyst body for decomposing hydrocarbons as defined in claim 1. 6. A process for producing a mixed reformed gas comprising hydrogen from hydrocarbons, comprising the step of reacting the hydrocarbons with steam at a temperature of 250 to 850° C., at a molar ratio of steam to carbon (S/C) of 1.0 to 6.0 and at a space velocity (GHSV) of 100 to 100000 h−1 in the presence of the porous catalyst body for decomposing hydrocarbons which is defined in claim 1 and supports one or more active metal species selected from the group consisting of gold, silver, platinum, palladium, ruthenium, cobalt, rhodium, iridium, rhenium, copper, manganese, chromium, vanadium and titanium which have an average particle diameter of not more than 50 nm. 7. A fuel cell system comprising the porous catalyst body for decomposing hydrocarbons as defined in claim 1.
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이 특허에 인용된 특허 (14)
Antos George J. (Bartlett IL), Acidic multimetallic catalytic composite.
Cronauer ; Donald C. ; Kehl ; William L., Process for hydrogenating a solid carbonaceous material with Ni/Ti/Mo on a mangesium-deficient magnesium aluminate spin.
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