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A system for curing a low dielectric constant (low-k) dielectric film on a substrate is described, wherein the dielectric constant of the low-k dielectric film is less than a value of approximately 4. The system comprises one or more process modules configured for exposing the low-k dielectric film

A system for curing a low dielectric constant (low-k) dielectric film on a substrate is described, wherein the dielectric constant of the low-k dielectric film is less than a value of approximately 4. The system comprises one or more process modules configured for exposing the low-k dielectric film to electromagnetic (EM) radiation, such as infrared (IR) radiation and ultraviolet (UV) radiation.

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1. A process module for treating a dielectric film on a substrate, comprising: process chamber;a substrate holder coupled to said process chamber and configured to support a substrate;an infrared (IR) radiation source coupled to said process chamber and configured to expose said dielectric film to I

1. A process module for treating a dielectric film on a substrate, comprising: process chamber;a substrate holder coupled to said process chamber and configured to support a substrate;an infrared (IR) radiation source coupled to said process chamber and configured to expose said dielectric film to IR radiation, wherein said IR radiation source comprises one or more IR lasers configured to produce one or more IR beams;an IR optics system having a beam sizing device configured to enlarge a beam diameter of at least one of said one or more IR beams to produce an enlarged beam spot size on said substrate; anda radiation scanning device coupled to said process chamber, and configured to displace said one or more IR beams from said IR radiation source and to scan said one or more IR beams from said IR radiation source across said substrate,wherein said radiation scanning device is configured to displace and scan said one or more IR beams across said substrate in a first lateral direction and a second lateral direction, said second lateral direction being different than said first lateral direction. 2. The process module of claim 1, wherein said substrate holder is configured to support a plurality of substrates. 3. The process module of claim 1, further comprising: a drive system coupled to said substrate holder, and configured to translate, or rotate, or both translate and rotate said substrate holder; anda motion control system coupled to said drive system, and configured to perform at least one of monitoring a position of said substrate, adjusting said position of said substrate, or controlling said position of said substrate. 4. The process module of claim 1, wherein said IR radiation source comprises an IR wave-band source ranging from approximately 8 microns to approximately 14 microns. 5. The process module of claim 1, wherein said IR radiation source comprises one or more CO2 lasers. 6. The process module of claim 1, further comprising: a scanning motion control system coupled to said radiation scanning device, and configured to perform at least one of monitoring a position of said one or more IR beams, adjusting said position of said one or more IR beams, or controlling said position of said one or more IR beams. 7. The process module of claim 1, wherein said IR radiation source further comprises: a plurality of IR lasers,wherein said IR optics system is further configured to receive a plurality of IR beams from said plurality of IR lasers, combine two or more of said plurality of IR beams from said plurality of IR lasers into a collective IR beam, and illuminate at least a portion of said substrate in said process chamber with said collective IR beam. 8. The process module of claim 1, wherein said IR optics system further comprises: a beam shaping device configured to shape at least one of said one or more IR beams. 9. The process module of claim 8, wherein said IR optics system is configured to size, or shape, or both size and shape said one or more IR beams into an IR sheet, and wherein said radiation scanning device is configured to scan said IR sheet across said substrate. 10. The process module of claim 1, wherein said radiation scanning device comprises one or more rotating mirrors, or one or more translating mirrors, or both one or more rotating mirrors and one or more translating mirrors. 11. The process module of claim 1, wherein said radiation scanning device comprises one or more mirror galvanometers. 12. The process module of claim 1, further comprising: an ultraviolet (UV) radiation source coupled to said process chamber and configured to expose said dielectric film to UV radiation,wherein said UV radiation source comprises a UV wave-band source containing emission ranging from approximately 150 nanometers to approximately 400 nanometers. 13. The process module of claim 12, wherein said UV radiation source comprises one or more UV lamps. 14. The process module of claim 12, further comprising: one or more windows through which said IR radiation, or said UV radiation, or both passes into said process chamber to illuminate said substrate. 15. The process module of claim 14, wherein said one or more windows comprises sapphire, MgF2, BaF2, CaF2, ZnS, Ge, GaAs, ZnSe, KCl, or SiO2, or any combination of two or more thereof. 16. The process module of claim 1, further comprising: a temperature control system coupled to said process chamber and configured to control a temperature of said substrate. 17. The process module of claim 16, wherein said temperature control system comprises a resistive heating element coupled to said substrate holder, and wherein said temperature control system is configured to control said resistive heating element to elevate said temperature of said substrate to a value ranging from approximately 100 degrees C. to approximately 600 degrees C. 18. The process module of claim 1, further comprising: a gas supply system coupled to said process chamber, and configured to introduce a process gas to said process chamber, and wherein said gas supply system is configured to supply a reactive gas, an inert gas, or both to said process chamber; anda vacuum pumping system coupled to said process chamber, and configured to evacuate said process chamber. 19. The process module of claim 18, wherein said gas supply system is configured to supply nitrogen gas to said process chamber. 20. The process module of claim 1, further comprising: an in-situ metrology system coupled to said process chamber, and configured to measure a property of said dielectric film on said substrate. 21. The process module of claim 1, wherein said second lateral direction is orthogonal to said first lateral direction. 22. The process module of claim 1, wherein at least one of said one or more IR beams is polarized to produce a polarized IR beam for irradiation on said substrate. 23. The process module of claim 1, further comprising: a polarizing beam splitter arranged to polarize at least one of said one or more IR beams. 24. The process module of claim 1, further comprising: a polarizing beam splitter arranged to combine two or more of said one or more IR beams into a collective, polarized IR beam for irradiation on said substrate. 25. The process module of claim 1, further comprising: a controller coupled to said substrate holder, said IR radiation source, said IR optics system, and said radiation scanning device, and configured to controllably operate said process module in accordance with a stored process recipe to treat a low-k dielectric film on said substrate with said IR radiation. 26. The process module of claim 25, wherein said controller executes said stored process recipe to control one or more processing elements in said process module to cause breakage of chemical bonds and/or dissociation of molecular side groups in said low-k dielectric film on said substrate. 27. The process module of claim 25, wherein said controller is configured to control one or more process parameters selected from the group consisting of an IR beam intensity, an IR beam size, and a time duration for exposure of at least a portion of said substrate to said IR radiation. 28. The process module of claim 1, further comprising: a controller coupled to said IR radiation source, and configured to generate control voltages sufficient to pulse said IR radiation. 29. The process module of claim 1, wherein said IR radiation source, said IR optics system, and said radiation scanning device are configured to illuminate a first region on said substrate with a first IR beam and illuminate a second region on said substrate with a second IR beam, and wherein said first region does not overlap with said second region, or said first region partially overlaps with said second region. 30. The process module of claim 1, wherein said IR radiation source, said IR optics system, and said radiation scanning device are configured to produce four IR beams to illuminate four regions on said substrate, each of said four IR beams is uniquely dedicated to a quadrant of said substrate.