Process for producing a ceramic matrix composite article and article formed thereby
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C04B-035/573
C04B-035/634
F01D-005/12
C04B-035/626
C04B-035/80
C04B-035/632
출원번호
US-0827821
(2010-06-30)
등록번호
US-8899939
(2014-12-02)
발명자
/ 주소
Manicke, Paul Stephen
Walker, Bryant Edward
Ronk, Warren Rosal
출원인 / 주소
General Electric Company
대리인 / 주소
General Electric Company
인용정보
피인용 횟수 :
0인용 특허 :
14
초록▼
Process for producing a ceramic composite structure includes impregnating a reinforcing material with a suitable precursor slurry composition including thermosetting resin, a suitable curing agent, a ceramic component, a carbonaceous solids component, and optionally, a suitable solvent. Exemplary th
Process for producing a ceramic composite structure includes impregnating a reinforcing material with a suitable precursor slurry composition including thermosetting resin, a suitable curing agent, a ceramic component, a carbonaceous solids component, and optionally, a suitable solvent. Exemplary thermosetting resins include polyesters, vinyl esters, epoxy resins, bismaleimide resins, and polyimide resins. The carbonaceous solids component provides a suitable amount of carbon char upon pyrolization. The preform may be dried prior to curing to remove solvents and thereby provide a working material comprising up to 70 volume % solids. The preform is cured, pyrolized, and infiltrated with molten silicon to form a composite article. The thermosetting resin is selected for processibility, green strength, and relatively fast cure cycle.
대표청구항▼
1. A process comprising: providing a reinforcing material;providing a precursor slurry composition including a thermosetting resin, a curing agent, a ceramic component, a carbonaceous solids component that includes at least a carbon-containing filler, and optionally a solvent, wherein the thermosett
1. A process comprising: providing a reinforcing material;providing a precursor slurry composition including a thermosetting resin, a curing agent, a ceramic component, a carbonaceous solids component that includes at least a carbon-containing filler, and optionally a solvent, wherein the thermosetting resin is at least one member selected from a polyester, a vinyl ester, and a bismaleimide resin, wherein the thermosetting resin and the curing agent are present in the precursor slurry composition to yield a cure time of less than fifteen minutes, wherein the thermosetting resin forms carbon char upon pyrolization, and wherein the carbon char and the filler of the carbonaceous solids component provide a final carbon yield;impregnating the reinforcing material with the precursor slurry composition to form a working material;drying the working material to remove substantially all the solvent, if present, wherein the dried working material comprises greater than 30 volume % to about 70 volume % solids attributable to the carbonaceous solids component. 2. The process according to claim 1 further comprising: shaping the working material into a near net shape preform subsequent to or prior to drying the working material. 3. The process according to claim 2 further comprising: curing the thermosetting resin in the near net shape preform to provide a cured preform. 4. The process according to claim 3 further comprising: pyrolozing the cured preform to produce the carbon char and form a porous preform; andinfiltrating the porous preform with molten silicon to form a ceramic composite structure. 5. The process according to claim 1 wherein providing the precursor slurry composition includes providing about 48 volume % acetone as the solvent, about 16 volume % of the carbonaceous solids component; about 9 volume % of the ceramic component, a remainder being the thermosetting resin and the curing agent. 6. The process according to claim 1 wherein the working material comprises a unidirectional tape. 7. The process according to claim 1 wherein providing the precursor slurry composition includes providing an amount of one or more additives selected from dispersants, thickening agents, crosslinking monomers, low profile additives and pigments. 8. The process according to claim 1 wherein flow of the precursor slurry composition is obtained with the thermosetting resin. 9. The process according to claim 1 wherein the carbonaceous solids component includes at least one member of the group consisting of graphite particles, graphite flakes, graphite whiskers, amorphous , single crystal or poly-crystalline carbon, carbonized plant fibers, lamp black, finely divided coal, charcoal, carbonized polymer fibers or felt. 10. The process according to claim 2 wherein shaping the working material includes forming a plurality of prepreg plies. 11. The process according to claim 10 wherein the working material is dried prior to forming the prepreg plies. 12. The process according to claim 11 further comprising: stacking the prepreg plies to provide an uncured ply stack;covering each of the outer plies of the stack with a covering ply formed of a matrix material including the thermosetting resin and the curing agent; andpress curing the stack for a total cure time of less than 15 minutes;pyrolozing the cured stack to produce the carbon char and form a porous preform; andinfiltrating the porous preform with molten silicon to form a ceramic composite structure. 13. An article comprising: a ceramic composite structure derived from the process according to claim 1. 14. The article according to claim 13 comprising a blade for a gas turbine engine assembly. 15. The process according to claim 1, wherein the thermosetting resin is polyester. 16. The process according to claim 1, wherein the thermosetting resin is vinyl ester. 17. The process according to claim 1, wherein the precursor slurry composition does not contain a solvent.
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이 특허에 인용된 특허 (14)
Yang Junsheng ; Wu Liangwei ; Liu Junhai ; Jang Bor Z., Apparatus and process for freeform fabrication of composite reinforcement preforms.
Steibel James D. ; Corman Gregory S. ; Schikner Robert C. ; Szweda Andrew, Article and method for making complex shaped preform and silicon carbide composite by melt infiltration.
Steibel James D. ; Corman Gregory S. ; Schikner Robert C. ; Szweda Andrew, Article and method for making complex shaped preform and silicon carbide composite by melt infiltration.
Borom Marcus P. (Schenectady NY) Hillig William B. (Ballston Lake NY) Singh Raj N. (Schenectady NY) Morrison William A. (Albany NY) Interrante Leonard V. (Schenectady NY), Fiber-containing composite.
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