[미국특허]
Imino carbene compounds and derivatives, and catalyst compositions made therefrom
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08F-004/76
C08F-004/64
출원번호
US-0442903
(2012-04-10)
등록번호
US-8907031
(2014-12-09)
발명자
/ 주소
Murray, Rex E.
Slaughter, LeGrande Mancel
Prema, Dipesh
Chen, Jinhui
출원인 / 주소
Chevron Phillips Chemical Company LP
대리인 / 주소
Merchant & Gould
인용정보
피인용 횟수 :
0인용 특허 :
45
초록
The present invention provides imino carbene compounds and their derivatives, catalyst compositions containing these compounds in combination with an activator, and polymerization processes using these catalyst compositions to polymerize one or more olefins.
대표청구항▼
1. A compound having the formula: or a partially saturated or saturated version thereof; wherein: MD is Ti, Zr, or Hf;R11, R11′, R11″, R12, and R13 are independently H or a hydrocarbyl, hydrocarbyloxide, hydrocarbylamino, hydrocarbylsilyl, or halogenated hydrocarbyl group, any of which having up to
1. A compound having the formula: or a partially saturated or saturated version thereof; wherein: MD is Ti, Zr, or Hf;R11, R11′, R11″, R12, and R13 are independently H or a hydrocarbyl, hydrocarbyloxide, hydrocarbylamino, hydrocarbylsilyl, or halogenated hydrocarbyl group, any of which having up to 18 carbon atoms; andR14D and R14E are phenyl groups. 2. The compound of claim 1, wherein: R11′ and R11″ are H; andR11, R12, and R13 are independently H, Me, t-Bu, Ph, CH2-Ph, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl, trifluoromethyl, pentafluorophenyl, or 4-trifluoromethylphenyl. 3. The compound of claim 1, wherein: MD is Zr or Hf; andR11, R11′, R11″, R12, and R13 are independently H, Me, t-Bu, Ph, CH2-Ph, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl, trifluoromethyl, pentafluorophenyl, or 4-trifluoromethylphenyl. 4. The compound of claim 3, wherein R11′ and R11″ are H. 5. The compound of claim 1, wherein the compound is: 6. A catalyst composition comprising at least one activator and a compound having the formula: or a partially saturated or saturated version thereof; wherein: MD is Ti, Zr, or Hf;R11, R11′, R11″, R12, and R13 are independently H or a hydrocarbyl, hydrocarbyloxide, hydrocarbylamino, hydrocarbylsilyl, or halogenated hydrocarbyl group, any of which having up to 18 carbon atoms; andR14D and R14E are phenyl groups. 7. The catalyst composition of claim 6, wherein the at least one activator comprises at least one aluminoxane compound, at least one organoboron or organoborate compound, at least one ionizing ionic compound, at least one activator-support, or any combination thereof. 8. The catalyst composition of claim 6, wherein the catalyst composition further comprises at least one organoaluminum compound. 9. The catalyst composition of claim 8, wherein the catalyst composition comprises at least one activator-support comprising a solid oxide treated with an electron-withdrawing anion. 10. The catalyst composition of claim 9, wherein the at least one activator-support comprises a fluorided solid oxide and/or a sulfated solid oxide. 11. The catalyst composition of claim 6, wherein: R11′ and R11″ are H; andR11, R12, and R13 are independently H, Me, t-Bu, Ph, CH2-Ph, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl, trifluoromethyl, pentafluorophenyl, or 4-trifluoromethylphenyl. 12. A method for preparing an article of manufacture comprising an olefin polymer, the method comprising: (i) contacting the catalyst composition of claim 6 with an olefin monomer and optionally at least one olefin comonomer under polymerization conditions to produce the olefin polymer; and(ii) forming the article of manufacture comprising the olefin polymer. 13. An olefin polymerization process, the process comprising: contacting a catalyst composition with an olefin monomer and optionally at least one olefin comonomer under polymerization conditions to produce an olefin polymer, wherein the catalyst composition comprises at least one activator and a compound having the formula: or a partially saturated or saturated version thereof; wherein: MD is Ti, Zr, or Hf;R11, R11′, R11″, R12, and R13 are independently H or a hydrocarbyl, hydrocarbyloxide, hydrocarbylamino, hydrocarbylsilyl, or halogenated hydrocarbyl group, any of which having up to 18 carbon atoms; andR14D and R14E are phenyl groups. 14. The process of claim 13, wherein the olefin monomer is ethylene, propylene, 1-butene, 2-butene, 3-methyl-1-butene, isobutylene, 1-pentene, 2-pentene, 3-methyl-1-pentene, 4-methyl-1-pentene, 1-hexene, 2-hexene, 3-ethyl-1-hexene, 1-heptene, 2-heptene, 3-heptene, 1-octene, 1-decene, or styrene. 15. The process of claim 13, wherein the process is conducted in a slurry reactor, a solution reactor, a gas phase reaction, or combinations thereof. 16. The process of claim 13, wherein the at least one activator comprises at least one aluminoxane compound. 17. The process of claim 13, wherein the catalyst composition comprises at least one activator-support comprising a solid oxide treated with an electron-withdrawing anion. 18. The process of claim 17, wherein the at least one activator-support comprises a fluorided solid oxide and/or a sulfated solid oxide. 19. The process of claim 13, wherein the catalyst composition is contacted with ethylene and at least one olefin comonomer comprising 1-butene, 1-hexene, 1-octene, or a mixture thereof. 20. The process of claim 19, wherein: R11′ and R11″ are H; andR11, R12, and R13 are independently H, Me, t-Bu, Ph, CH2-Ph, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 2,6-diisopropylphenyl, trifluoromethyl, pentafluorophenyl, or 4-trifluoromethylphenyl.
Hottovy John D. (Bartlesville OK) Lawrence Frederick C. (Bartlesville OK) Lowe Barry W. (Bartlesville OK) Fangmeier James S. (Bartlesville OK), Apparatus and method for producing ethylene polymer.
McDaniel Max P. ; Benham Elizabeth A. ; Martin Shirley J. ; Collins Kathy S. ; Smith James L. ; Hawley Gil R. ; Wittner Christopher E. ; Jensen Michael D., Compositions that can produce polymers.
McDaniel Max P. ; Collins Kathy S. ; Johnson Marvin M. ; Smith James L. ; Benham Elizabeth A. ; Hawley Gil R. ; Wittner Christopher E. ; Jensen Michael D., Compositions that can produce polymers.
Diamond,Gary M.; LaPointe,Anne M.; Leclerc,Margarete K.; Longmire,James; Nava Salgado,Victor; Shoemaker,James A. W.; Sun,Pu, Heterocycle-amine ligands, compositions, complexes, and catalysts.
Hottovy John D. ; Hensley Harvey D. ; Przelomski David J. ; Cymbaluk Teddy H. ; Franklin ; III Robert K. ; Perez Ethelwoldo P., High solids slurry polymerization.
Reed Marion G. (Hacienda Heights CA) Jaffe Joseph (Berkeley CA), Hydrocarbon hydroconversion process employing hydroxy-aluminum stabilized catalysts supports.
Jenkins ; III John M. (So. Charleston WV) Jones Russell L. (Chapel Hill NC) Jones Thomas M. (So. Charleston WV) Beret Samil (Danville CA), Method for fluidized bed polymerization.
Shamshoum Edwar S. ; Rauscher David J., Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation.
Diamond,Gary M.; LaPointe,Anne M.; Leclerc,Margarete K.; Longmire,James; Nava Salgado,Victor; Shoemaker,James A. W.; Sun,Pu, Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts.
McDaniel, Max P.; Johnson, Marvin M.; Randolph, Bruce B.; Collins, Kathy S.; Benham, Elizabeth A.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst composition.
Collins, Kathy S.; Palackal, Syriac J.; McDaniel, Max P.; Jensen, Michael D.; Hawley, Gil R.; Farmer, Kenneth R.; Wittner, Christopher E.; Benham, Elizabeth A.; Eaton, Anthony P.; Martin, Joel L., Organometal catalyst compositions.
Max P. McDaniel ; James B. Kimble ; Kathy S. Collins ; Elizabeth A. Benham ; Michael D. Jensen ; Gil R. Hawley ; Joel L. Martin, Organometal catalyst compositions.
Max P. McDaniel ; Kathy S. Collins ; Anthony P. Eaton ; Elizabeth A. Benham ; Michael D. Jensen ; Joel L. Martin ; Gil R. Hawley, Organometal catalyst compositions.
Max P. McDaniel ; Kathy S. Collins ; James L. Smith ; Elizabeth A. Benham ; Marvin M. Johnson ; Anthony P. Eaton ; Michael D. Jensen ; Joel L. Martin ; Gil R. Hawley, Organometal catalyst compositions.
McDaniel, Max P.; Collins, Kathy S.; Benham, Elizabeth A.; Eaton, Anthony P.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R.; Hsieh, Eric T., Organometal catalyst compositions.
McDaniel, Max P.; Collins, Kathy S.; Eaton, Anthony P.; Benham, Elizabeth A.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst compositions.
McDaniel, Max P.; Shveima, Joseph S.; Smith, James L.; Collins, Kathy S.; Benham, Elizabeth A.; Eaton, Anthony P.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst compositions.
McDaniel, Max P.; Collins, Kathy S.; Benham, Elizabeth A.; Eaton, Anthony P.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst compositions with solid oxide supports treated with fluorine and boron.
Max P. McDaniel ; Kathy S. Collins ; Anthony P. Eaton ; Elizabeth A. Benham ; Joel L. Martin ; Michael D. Jensen ; Gil R. Hawley, Organometal compound catalyst.
McDaniel, Max P.; Collins, Kathy S.; Hawley, Gil R.; Jensen, Michael D.; Benham, Elizabeth A.; Eaton, Anthony P.; Martin, Joel L.; Wittner, Christopher E., Organometal compound catalyst.
Hawley, Gil R.; McDaniel, Max P.; Wittner, Christopher E.; Jensen, Michael D.; Martin, Joel L.; Benham, Elizabeth A.; Eaton, Anthony P.; Collins, Kathy S., Polymerization catalysts.
Hanson Donald O. (Bartlesville OK), Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator.
Hasegawa Saiki (Mie-ken JPX) Yasuda Hisami (Mie-ken JPX) Yano Akihiro (Mie-ken JPX), Process for producing a
상세보기
Max P. McDaniel ; Anthony P. Eaton ; Elizabeth A. Benham ; Shawn R. Kennedy ; Ashish M. Sukhadia ; Rajendra K. Krishnaswamy ; Kathy S. Collins, Process for producing a polymer composition.
McDaniel Max P. ; Collins Kathy S. ; Johnson Marvin M. ; Smith James L. ; Benham Elizabeth A. ; Hawley Gil R. ; Wittner Christopher E. ; Jensen Michael D., Process for producing polymers using a composition comprising an organometal compound, a treated solid oxide compound, and an organoaluminum compound.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.