Process for the production of chlorinated and/or fluorinated propenes
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07C-017/26
C07C-017/38
C07C-021/073
C07C-017/269
출원번호
US-0575266
(2012-05-30)
등록번호
US-8927792
(2015-01-06)
국제출원번호
PCT/US2012/039906
(2012-05-30)
§371/§102 date
20120725
(20120725)
국제공개번호
WO2012/170239
(2012-12-13)
발명자
/ 주소
Tirtowidjojo, Max M.
Kruper, Jr., William J.
Hirsekorn, Kurt F.
Chakraborty, Debashis
출원인 / 주소
Dow AgroSciences, LLC
대리인 / 주소
Corvin, Carl D
인용정보
피인용 횟수 :
0인용 특허 :
72
초록▼
Processes for the production of chlorinated and/or fluonnated propenes provide good product yield with advantageous impurity profiles in the crude product. Advantageously, the processes may be conducted at lower temperatures than 600° C., or less than 500° C., so that energy savings are provided, an
Processes for the production of chlorinated and/or fluonnated propenes provide good product yield with advantageous impurity profiles in the crude product. Advantageously, the processes may be conducted at lower temperatures than 600° C., or less than 500° C., so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.
대표청구항▼
1. A one-step process for the production of chlorinated and/or fluorinated propenes comprising: reacting i) a dichloroethylene or a chlorofluoroethylene having the formula CHCl═CHX wherein X is Cl or F; and ii) a methane, chloromethane, fluoromethane or chlorofluoromethane having the formula CH(4-a)
1. A one-step process for the production of chlorinated and/or fluorinated propenes comprising: reacting i) a dichloroethylene or a chlorofluoroethylene having the formula CHCl═CHX wherein X is Cl or F; and ii) a methane, chloromethane, fluoromethane or chlorofluoromethane having the formula CH(4-a)Xa, wherein a is 0-3, to provide at least one chlorinated and/or fluorinated propene. 2. The process of claim 1, wherein the chlorinated and/or fluorinated propene has the formula CHX═CH—CH(3-a)Xa wherein a is 0-3. 3. The process of claim 1, wherein the process carried out at a temperature of less than 600° C. 4. The process of claim 3, wherein the process is carried out at a temperature of less than 500° C. 5. The process of claim 1, wherein the process is carried out at ambient pressure or greater. 6. The process of claim 5, wherein the process is carried out at a pressure of greater than 200 psig. 7. The process of claim 1, wherein the reaction is carried out in the presence of one or more catalyst(s) and/or initiator(s). 8. The process of claim 7, wherein the initiator comprises carbon tetrachloride, chlorine, hexachloroethane, benzotrichloride, hexachloroacetone or combinations of these. 9. The process of claim 1, wherein the methane, chloromethane, fluoromethane or chlorofluoromethane and the chloroethylene or chlorofluoroethylene are provided in a ratio of CH(4-a)Xa/CHCl═CHX of greater than or equal to 1.0. 10. The process of claim 9, wherein the reactor further makes use of a diluent to reduce the temperature within the reactor, wherein the diluent comprises an inert diluent, CH(4-a)Xa, HCl, or combinations of these. 11. The process of claim 1, wherein the chlorinated and/or fluorinated propene comprises cis/trans 1,3-dichloropropene. 12. The process of claim 11, wherein the dichloroethylene or chlorofluoroethylene comprises cis/trans 1,2-dichloroethylene and the methane, chloromethane, fluoromethane or chlorofluoromethane comprises methyl chloride. 13. The process of claim 12; wherein the methyl chloride and/or 1,2-dichloroethylene are generated for use in the process. 14. The process of claim 4, wherein the pressure is greater than 15 psia and the process is carried out in the presence of a catalyst/initiator, and the molar ratio of CH(4-a)Xa/CHCl═CHX is greater than 1.0. 15. The process of claim 1, wherein the CHCl═CHX and/or CH(4-a)Xa are recycled within the process. 16. The process of claim 15, where byproducts with boiling points in between CH(4-a)Xa, and CHCl═CHX are removed from the process by purging or distillation prior to recycling of CH(4-a)Xa and CHCl═CHX. 17. A one-step process for the production of chlorinated propenes comprising: reacting i) a dichloroethylene having the formula CHCl═CHCl; and ii) a methane or chloromethane having the formula CH(4-a)Cla, wherein a is 0-3, to provide at least one chlorinated propene. 18. The process of claim 17, wherein the chlorinated propene has the formula CHCl═CH—CH(3-a)Cla wherein a is 0-3. 19. The process of claim 17, wherein the process carried out at a temperature of less than 600° C. 20. The process of claim 17, wherein the process is carried out at a pressure of greater than 200 psig. 21. The process of claim 17, wherein the reaction is carried out in the presence of one or more catalyst(s) and/or initiator(s). 22. A one-step process for the production of 1,3-dichloropropenes comprising reacting 1,2-dichloroethylene and methyl chloride at a ratio of at least 1:1, a temperature of less than 600° C., and ambient pressure or higher to provide a mixture of 1,3-dichloropropenes.
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