Vegetable oil derivatives as extender oils for elastomer compositions
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IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08K-005/09
C08K-005/10
C08L-009/00
C08K-005/103
C08K-005/11
C08K-005/092
출원번호
US-0995775
(2011-12-20)
등록번호
US-8969454
(2015-03-03)
우선권정보
IT-MI2010A2325 (2010-12-20)
국제출원번호
PCT/EP2011/073494
(2011-12-20)
§371/§102 date
20130619
(20130619)
국제공개번호
WO2012/085014
(2012-06-28)
발명자
/ 주소
Bastioli, Catia
Capuzzi, Luigi
Magistrali, Paolo
Gesti′ Garcia, Sebastià
Viola, Gian Tommaso
Savini, Giuseppe
Bacchelli, Fabio
출원인 / 주소
Novamont S.p.A.
대리인 / 주소
Novak Druce Connolly Bove + Quigg LLP
인용정보
피인용 횟수 :
1인용 특허 :
1
초록▼
Elastomer composition comprising at least one elastomer and at least one vegetable oil derivative selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4OC(O)R1C(O)OCH2CH(OR2)CH2nOR3 and said mixture of triglycerides having a Numeri
Elastomer composition comprising at least one elastomer and at least one vegetable oil derivative selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4OC(O)R1C(O)OCH2CH(OR2)CH2nOR3 and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000, b. triglycerides of one or more long chain carboxylic acids including at least one carboxylic acid containing adjacent hydroxyl groups, c. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides.
대표청구항▼
1. Elastomer composition comprising at least one elastomer and at least one vegetable oil derivative selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4—[O—C(O)—R1—C(O)—O—CH2—CH(OR2)—CH2]n—O—R3 whereinR1 is selected from C2-C22
1. Elastomer composition comprising at least one elastomer and at least one vegetable oil derivative selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4—[O—C(O)—R1—C(O)—O—CH2—CH(OR2)—CH2]n—O—R3 whereinR1 is selected from C2-C22 alkylenes,R2 is selected from one or more of the following groups consisting of C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R3 is selected from one or more of the following groups consisting of H, C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R4 is an alkyl group,n is an integer greater than or equal to 2,said C6-C24 dicarboxylic acid residues of R2 and R3 being esterified with monoalcohols and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000;b. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides. 2. Elastomer composition according to claim 1, in which said at least one elastomer is a natural rubber or a synthetic rubber. 3. Elastomer composition according to claim 2, in which said at least one elastomer is a synthetic rubber selected from the group consisting of diene-based rubbers, thermoplastic elastomers, nitrile rubbers, acrylonitrile-butadiene copolymers (NBR) and styrene-isoprene-styrene (SIS) polar rubbers. 4. Elastomer composition according to claim 3, in which said at least one elastomer is a diene-based rubber. 5. Elastomer composition according to claim 4, in which said diene-based rubber is a vinylarene-conjugated diene copolymer. 6. Elastomer composition according to claim 5, in which said vinylarene-conjugated diene copolymer is a styrene-1,3-butadiene random copolymer. 7. Elastomer composition according to claim 6, in which said styrene-1,3-butadiene random copolymer has a styrene content from 15 to 50% by weight. 8. Elastomer composition according to claim 6, in which said styrene-1,3-butadiene random copolymer has a vinyl unit content from 10 to 80% with respect to the diene content. 9. Elastomer composition according to claim 6, in which said styrene-1,3-butadiene random copolymer is obtained from solution or as emulsion. 10. Elastomer composition according to claim 1, wherein the R1 group of the vegetable oil derivatives of type (a) is C6-C11 alkylene. 11. Elastomer composition according to claim 1, wherein the C6-C24 dicarboxylic acid residues of R2 and R3 are suberic acid, azelaic acid and brassylic acid and their mixtures. 12. Elastomer composition according to claim 1, wherein the R4 group of the vegetable oil derivatives of type (a) is a C1-C12 alkyl group. 13. Elastomer composition according to claim 1, in which the vegetable oil derivatives of type (a) comprise dimer and/or trimer esters of triglycerides containing C6-C24 dicarboxylic acids residues. 14. Elastomer composition according to claim 1, in which the vegetable oil derivative is of type (a). 15. Elastomer composition according to claim 1, in which the vegetable oil derivative is used in a mixture with mineral and/or natural oils. 16. Elastomer composition according to claim 15, wherein said mixtures contain 15-45% by weight of vegetable oil derivatives. 17. Elastomer composition according to claim 1 comprising one or more of the following ingredients: vulcanisation agents, vulcanisation accelerators, activators, retardants, organic acids, antioxidants, fillers, reinforcing materials, process coadjuvants. 18. Elastomer composition according to claim 17 in which the reinforcing materials belong to the group comprising carbon black, silicas and biofillers from renewable sources. 19. Raw elastomeric composition comprising: (A1) from 30 to 100% by weight of a vinylarene-conjugated diene random elastomeric copolymer,(A2) from 0 to 70% by weight of one or more diene rubbers,the total amount of elastomers (A1)+(A2) being equal to 100, and(B) from 10 to 150 phr of silica or carbon black or mixtures thereof;(C) from 10 to 100 phr, of at least one vegetable oil derivative selected from one or more of:a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4—[O—C(O)—R1—C(O)—O—CH2—CH(OR2)—CH2]n—O—R3 whereinR1 is selected from C2-C22 alkylenes,R2 is selected from one or more of the following groups consisting of C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R3 is selected from one or more of the following groups consisting of H, C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R4 is an alkyl group,n is an integer greater than or equal to 2,said C6-C24 dicarboxylic acid residues of R2 and R3 being esterified with monoalcohols and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000,b. triglycerides of one or more long chain carboxylic acids including at least one carboxylic acid containing adjacent hydroxyl groups,c. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides,(D) from 0.1 to 20 phr of a coupling agent based on silane;(E) from 0.1 to 10 phr of a vulcanizing agent. 20. Rubber compounds prepared from the elastomeric composition according to claim 1. 21. Tyre tread comprising the rubber compound according to claim 20. 22. A mixture of elastomers of natural and/or synthetic origin with one or more derivatives of vegetable oils as an extender oil being selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4—[O—C(O)—R1—C(O)—O—CH2—CH(OR2)—CH2]n—O—R3 whereinR1 is selected from C2-C22 alkylenes,R2 is selected from one or more of the following groups consisting of C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R3 is selected from one or more of the following groups consisting of H, C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R4 is an alkyl group,n is an integer greater than or equal to 2,said C6-C24 dicarboxylic acid residues of R2 and R3 being esterified with monoalcohols and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000;b. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides. 23. A tyre comprising an elastomer composition which comprises at least one elastomer and at least one vegetable oil derivative selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R4—[O—C(O)—R1—C(O)—O—CH2—CH(OR2)—CH2]n—O—R3 whereinR1 is selected from C2-C22 alkylenes,R2 is selected from one or more of the following groups consisting of C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R3 is selected from one or more of the following groups consisting of H, C6-C24 dicarboxylic acid residues and C6-C24 monocarboxylic acid residues,R4 is an alkyl group,n is an integer greater than or equal to 2,said C6-C24 dicarboxylic acid residues of R2 and R3 being esterified with monoalcohols and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000;b. triglycerides of one or more long chain carboxylic acids including at least one carboxylic acid containing adjacent hydroxyl groups,c. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides. 24. Elastomer compositions containing silicas and esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being derived from vegetable oils other than triglycerides, as compatibilising agents.
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