Rigid renewable polyester compositions having a high impact strength and tensile elongation
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08J-009/00
C08L-067/04
C08J-009/28
출원번호
US-0370869
(2012-02-10)
등록번호
US-8975305
(2015-03-10)
발명자
/ 주소
Topolkaraev, Vasily A.
Scholl, Neil T.
McEneany, Ryan J.
Eby, Thomas A.
출원인 / 주소
Kimberly-Clark Worldwide, Inc.
대리인 / 주소
Dority & Manning, P.A.
인용정보
피인용 횟수 :
0인용 특허 :
82
초록▼
A thermoplastic composition that contains a rigid renewable polyester and a polymeric toughening additive is provided. The toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. An increase in the deformation force and elongational st
A thermoplastic composition that contains a rigid renewable polyester and a polymeric toughening additive is provided. The toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. An increase in the deformation force and elongational strain causes debonding to occur in the renewable polyester matrix at those areas located adjacent to the discrete domains. This can result in the formation of a plurality of voids adjacent to the discrete domains that can help to dissipate energy under load and increase impact strength. To even further increase the ability of the composition to dissipate energy in this manner, an interphase modifier may be employed that reduces the degree of friction between the toughening additive and renewable polyester and thus enhances the degree and uniformity of debonding.
대표청구항▼
1. A melt blended, thermoplastic composition comprising: at least one rigid renewable polyester having a glass transition temperature of about 0° C. or more;from about 1 wt. % to about 30 wt. % of at least one polymeric toughening additive based on the weight of the renewable polyester;from about 0.
1. A melt blended, thermoplastic composition comprising: at least one rigid renewable polyester having a glass transition temperature of about 0° C. or more;from about 1 wt. % to about 30 wt. % of at least one polymeric toughening additive based on the weight of the renewable polyester;from about 0.5 wt. % to about 15 wt. % of at least one interphase modifier based on the weight of the renewable polyester, wherein the interphase modifier facilitates debonding from the renewable polyester; anda polyepoxide modifier having a number average molecular weight of from about 7,500 grams per mole to about 250,000 grams per mole;wherein the thermoplastic composition has a morphology in which a plurality of discrete primary domains are dispersed within a continuous phase, the discrete primary domains containing the polymeric toughening additive and the continuous phase containing the renewable polyester, wherein a plurality of substantially homogeneously distributed voids are located adjacent to the discrete primary domains, further wherein the composition exhibits an Izod impact strength of about 0.3 Joules per centimeter or more, measured at 23° C. according to ASTM D256-10 (Method A), and a tensile elongation at break of about 10% or more, measured at 23° C. according to ASTM D638-10, and wherein the ratio of the glass transition temperature of the thermoplastic composition to the glass transition temperature of the renewable polyester is from about 0.7 to about 1.3. 2. The thermoplastic composition of claim 1, wherein the renewable polyester is a polylactic acid. 3. The thermoplastic composition of claim 1, wherein the renewable polyester and the thermoplastic composition have a glass transition temperature of from about 50° C. to about 75° C. 4. The thermoplastic composition of claim 1, wherein the ratio of the solubility parameter for the renewable polyester to the solubility parameter of the polymeric toughening additive is from about 0.5 to about 1.5. 5. The thermoplastic composition of claim 4, wherein the polymeric toughening additive has a solubility parameter of from about 15 to about 30 MJoules1/2/m3/2. 6. The thermoplastic composition of claim 1, wherein the ratio of the melt flow rate for the renewable polyester to the melt flow rate of the polymeric toughening additive is from about 0.2 to about 8. 7. The thermoplastic composition of claim 1, wherein the ratio of the Young's modulus elasticity of the renewable polyester to the Young's modulus of elasticity of the polymeric toughening additive is from about 2 to about 500. 8. The thermoplastic composition of claim 1, wherein the polymeric toughening additive includes a polyolefin. 9. The thermoplastic composition of claim 8, wherein the polyolefin is a propylene homopolymer, propylene/α-olefin copolymer, ethylene/α-olefin copolymer, or a combination thereof. 10. The thermoplastic composition of claim 1, wherein the interphase modifier has a kinematic viscosity of from about 0.7 to about 200 centistokes, determined at a temperature of 40° C. 11. The thermoplastic composition of claim 1, wherein the interphase modifier is hydrophobic. 12. The thermoplastic composition of claim 1, wherein the interphase modifier is a silicone, silicone-polyether copolymer, aliphatic polyester, aromatic polyester, alkylene glycol, alkane diol, amine oxide, fatty acid ester, or a combination thereof. 13. The thermoplastic composition of claim 1, wherein the discrete primary domains have a length of from about 0.05 micrometers to about 30 micrometers. 14. The thermoplastic composition of claim 1, further comprising a compatibilizer. 15. The thermoplastic composition of claim 1, wherein the polyepoxide modifier includes an epoxy-functional (meth)acrylic monomeric component. 16. The thermoplastic composition of claim 15, wherein the polyepoxide modifier is poly(ethylene-co-methacrylate-co-glycidyl methacrylate). 17. The thermoplastic composition of claim 1, wherein the renewable polyester constitutes about 70 wt. % or more of the thermoplastic composition. 18. The thermoplastic composition of claim 1, wherein the composition exhibits an Izod notched impact strength of from about 0.8 J/cm to about 2.5 J/cm, measured at 23° C. according to ASTM D256-10 (Method A). 19. The thermoplastic composition of claim 1, wherein the composition exhibits a tensile elongation at break of from about 100% to about 300%, measured at 23° C. according to ASTM D638-10. 20. An injection molded article comprising the thermoplastic composition of claim 1. 21. An injection molded article that is formed from a thermoplastic composition, wherein the thermoplastic composition comprises about 70 wt. % or more of at least one polylactic acid having a glass transition temperature of about 0° C. or more, from about 0.1 wt. % to about 30 wt. % of at least one polymeric toughening additive, from about 0.1 wt. % to about 20 wt. % of at least one interphase modifier, and a polyepoxide modifier having a number average molecular weight of from about 7,500 grams per mole to about 250,000 grams per mole; wherein the molded article exhibits an Izod impact strength of about 0.3 Joules per centimeter or more, measured at 23° C. according to ASTM D256-10 (Method A), and a tensile elongation at break of about 10% or more, measured at 23° C. according to ASTM D638-10. 22. The injection molded article of claim 21, wherein the polymeric toughening additive includes a propylene homopolymer, propylene/α-olefin copolymer, ethylene/α-olefin copolymer, or a combination thereof. 23. The injection molded article of claim 21, wherein the ratio of the glass transition temperature of the thermoplastic composition to the glass transition temperature of the polylactic acid is from about 0.9 to about 1.1. 24. The injection molded article of claim 21, wherein the interphase modifier is a silicone, silicone-polyether copolymer, aliphatic polyester, aromatic polyester, alkylene glycol, alkane diol, amine oxide, fatty acid ester, or a combination thereof. 25. The injection molded article of claim 21, further comprising a compatibilizer, polyepoxide modifier, or both. 26. The injection molded article of claim 21, wherein the article exhibits an Izod notched impact strength of from about 0.8 J/cm to about 2.5 J/cm, measured at 23° C. according to ASTM D256-10 (Method A). 27. The injection molded article of claim 21, wherein the article exhibits a tensile elongation at break of from about 100% to about 300%, measured at 23° C. according to ASTM D638-10. 28. The thermoplastic composition of claim 1, wherein the renewable polyester is polyethylene terephthalate. 29. The thermoplastic composition of claim 1, wherein the interphase modifier is an alkylene glycol, a fatty acid ester, or a combination thereof. 30. The thermoplastic composition of claim 1, wherein the renewable polyester constitutes from 85.3 wt. % or more of the thermoplastic composition. 31. The thermoplastic composition of claim 15, wherein the polyepoxide modifier includes an α-olefin monomer, wherein the epoxy-functional (meth)acrylic monomer constitutes from about 1 wt. % to about 25 wt. % of the polyepoxide modifier, and wherein the α-olefin monomer constitutes from about 55 wt. % to about 95 wt. % of the polyepoxide modifier. 32. The thermoplastic composition of claim 1, wherein the thermoplastic composition excludes a filler.
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