[미국특허]
Catalyst compositions for the polymerization of olefins
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08F-004/76
C08F-004/64
C08F-004/52
B01J-031/22
C07F-007/00
C07F-007/28
C08F-002/01
C08F-004/02
C08F-004/16
C08F-110/02
C08F-004/659
출원번호
US-0306449
(2014-06-17)
등록번호
US-8987394
(2015-03-24)
발명자
/ 주소
Hlavinka, Mark L.
Yang, Qing
Yu, Youlu
출원인 / 주소
Chevron Phillips Chemical Company LP
대리인 / 주소
Merchant & Gould
인용정보
피인용 횟수 :
5인용 특허 :
45
초록
Catalyst compositions containing N,N-bis2-hydroxidebenzylamine transition metal compounds are disclosed. Methods for making these transition metal compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
대표청구항▼
1. An olefin polymerization process, the process comprising: contacting a catalyst composition with an olefin monomer and optionally an olefin comonomer under polymerization conditions to produce an olefin polymer, wherein the catalyst composition comprises: (i) an N,N-bis[2-hydroxidebenzyl]amine co
1. An olefin polymerization process, the process comprising: contacting a catalyst composition with an olefin monomer and optionally an olefin comonomer under polymerization conditions to produce an olefin polymer, wherein the catalyst composition comprises: (i) an N,N-bis[2-hydroxidebenzyl]amine compound having formula (Ia): wherein: M is Ti, Zr, or Hf;X1 and X2 independently are a monoanionic ligand;each RB and Rc independently is a halide, a C1 to C36 hydrocarbyl group, a C1 to C36 halogenated hydrocarbyl group, a C1 to C36 hydrocarboxy group, or a C1 to C36 hydrocarbylsilyl group, wherein p and q independently are 0, 1, 2, 3, or 4; andRA is a C1 to C36 hydrocarbyl group or C1 to C36 halogenated hydrocarbyl group;(ii) an activator-support comprising a solid oxide treated with an electron-withdrawing anion; and(iii) optionally, a co-catalyst. 2. The process of claim 1, wherein the process is conducted in a batch reactor, slurry reactor, gas-phase reactor, solution reactor, high pressure reactor, tubular reactor, autoclave reactor, or a combination thereof. 3. The process of claim 1, wherein the olefin monomer comprises ethylene or propylene. 4. The process of claim 1, wherein the olefin monomer comprises ethylene, and the olefin comonomer comprises 1-butene, 1-hexene, 1-octene, or a mixture thereof. 5. The process of claim 1, wherein the olefin polymer has a Mw greater than about 1,000,000 g/mol. 6. The process of claim 1, wherein: X1 and X2 independently are a halide or a C1 to C18 hydrocarbyl group;each RB and RC independently is a halide, a C1 to C 18 hydrocarbyl group, or a C1 to C18 hydrocarbylsilyl group, wherein p and q independently are 0, 1, or 2;RA is a C1 to C18 hydrocarbyl group;the activator-support comprises a fluorided solid oxide, a sulfated solid oxide, or a combination thereof; andthe olefin monomer comprises ethylene or propylene. 7. The process of claim 6, wherein: the catalyst composition comprises a co-catalyst; andthe olefin polymer has a Mw in a range from about 2,000,000 to about 7,000,000 g/mol. 8. The process of claim 6, wherein: M is Zr or Hf;X1 and X2 independently are a halide, methyl, benzyl, or phenyl;each RB and RC independently is a C1 to C5 alkyl group;the process is conducted in a slurry reactor, gas-phase reactor, solution reactor, or a combination thereof; andthe catalyst composition is contacted with ethylene and an olefin comonomer comprising 1-butene, 1-hexene, 1-octene, or a mixture thereof 9. The process of claim 8, wherein: RA is a C3 to C8 terminal alkenyl group; andthe catalyst composition comprises an organoaluminum co-catalyst. 10. An olefin polymerization process, the process comprising: contacting a catalyst composition with an olefin monomer and optionally an olefin comonomer under polymerization conditions to produce an olefin polymer, wherein the catalyst composition comprises: (i) an N,N-bis[2-hydroxidebenzyl]amine compound having formula (Ib): wherein: M is Ti, Zr, or Hf;X1 and X2 independently are a monoanionic ligand;RB1, RB2, RC1, and RC2 independently are a halide, a C1 to C36 hydrocarbyl group, a C1 to C36 halogenated hydrocarbyl group, a C1 to C36 hydrocarboxy group, or a C1 to C36 hydrocarbylsilyl group; andRA is a C1 to C36 hydrocarbyl group or C1 to C36 halogenated hydrocarbyl group;(ii) an activator-support comprising a solid oxide treated with an electron- withdrawing anion; and(iii) optionally, a co-catalyst. 11. The process of claim 10, wherein: the process is conducted in a slurry reactor, gas-phase reactor, solution reactor, or a combination thereof; andthe catalyst composition is contacted with ethylene and an olefin comonomer comprising 1-butene, 1-hexene, 1-octene, or a mixture thereof 12. The process of claim 11, wherein: the catalyst composition comprises a co-catalyst;M is Zr or Hf;X1 and X2 independently are a halide or a C1 to C18 hydrocarbyl group;RB1, RB2, RC1, and RC2 independently are a halide, a C1 to C18 hydrocarbyl group, or a C1 to C18 hydrocarbylsilyl group; andRA is a C1 to C18 hydrocarbyl group. 13. The process of claim 12, wherein the olefin polymer has a Mw in a range from about 2,000,000 to about 7,000,000 g/mol. 14. The process of claim 12, wherein: the activator-support comprises a fluorided solid oxide, a sulfated solid oxide, or a combination thereof;the catalyst composition comprises an organoaluminum co-catalyst; andRA is a C3 to C8 terminal alkenyl group. 15. The process of claim 12, wherein: the activator-support comprises fluorided alumina, sulfated alumina, fluorided silica-alumina, sulfated silica-alumina, fluorided silica-coated alumina, sulfated silica-coated alumina, or any combination thereof; andRB1, RB2, RC1, and RC2 independently are a C1 to C5 alkyl group. 16. The process of claim 10, wherein: the olefin monomer comprises ethylene or propylene; andthe process is conducted in a batch reactor, slurry reactor, gas-phase reactor, solution reactor, high pressure reactor, tubular reactor, autoclave reactor, or a combination thereof. 17. The process of claim 16, wherein: the catalyst composition comprises a co-catalyst;M is Zr or Hf;X1 and X2 independently are a halide or a C1 to C18 hydrocarbyl group;RB1, RB2, RC1, and RC2 independently are a halide, a C1 to C18 hydrocarbyl group, or a C1 to C18 hydrocarbylsilyl group; andRA is a C1 to C18 hydrocarbyl group. 18. The process of claim 17, wherein: the activator-support comprises a fluorided solid oxide, a sulfated solid oxide, or a combination thereof; andthe olefin polymer has a Mw in a range from about 2,000,000 to about 7,000,000 g/mol. 19. The process of claim 17, wherein: X1 and X2 independently are a halide, methyl, benzyl, or phenyl; andRB1, RB2, RC1, and RC2 independently are a C1 to C5 alkyl group. 20. The process of claim 19, wherein: RA is a C3 to C8 terminal alkenyl group;the activator-support comprises a fluorided solid oxide, a sulfated solid oxide, or a combination thereof;the catalyst composition comprises an organoaluminum co-catalyst; andthe catalyst composition is contacted with ethylene and a comonomer comprising 1-butene, 1-hexene, 1-octene, or a mixture thereof.
Hottovy John D. (Bartlesville OK) Lawrence Frederick C. (Bartlesville OK) Lowe Barry W. (Bartlesville OK) Fangmeier James S. (Bartlesville OK), Apparatus and method for producing ethylene polymer.
McDaniel Max P. ; Benham Elizabeth A. ; Martin Shirley J. ; Collins Kathy S. ; Smith James L. ; Hawley Gil R. ; Wittner Christopher E. ; Jensen Michael D., Compositions that can produce polymers.
McDaniel Max P. ; Collins Kathy S. ; Johnson Marvin M. ; Smith James L. ; Benham Elizabeth A. ; Hawley Gil R. ; Wittner Christopher E. ; Jensen Michael D., Compositions that can produce polymers.
Hottovy John D. ; Hensley Harvey D. ; Przelomski David J. ; Cymbaluk Teddy H. ; Franklin ; III Robert K. ; Perez Ethelwoldo P., High solids slurry polymerization.
Reed Marion G. (Hacienda Heights CA) Jaffe Joseph (Berkeley CA), Hydrocarbon hydroconversion process employing hydroxy-aluminum stabilized catalysts supports.
Kol, Moshe; Tshuva, Edit Y.; Goldschmidt, Zeev, Method for catalytic polymerization of alpha-olefin monomers using an ultra-high activity non-metallocene pre-catalyst.
Jenkins ; III John M. (So. Charleston WV) Jones Russell L. (Chapel Hill NC) Jones Thomas M. (So. Charleston WV) Beret Samil (Danville CA), Method for fluidized bed polymerization.
Shamshoum Edwar S. ; Rauscher David J., Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation.
Eaton Gerald B. ; Monahan Michael J. ; Tipton Robert J., Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents.
Eaton, Gerald B.; Monahan, Michael J.; Ebert, Alan K.; Tipton, Robert J.; Baralt, Eduardo, Methods for forming amorphous ultra-high molecular weight polyolefins for use as drag reducing agents.
McDaniel, Max P.; Johnson, Marvin M.; Randolph, Bruce B.; Collins, Kathy S.; Benham, Elizabeth A.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst composition.
Collins, Kathy S.; Palackal, Syriac J.; McDaniel, Max P.; Jensen, Michael D.; Hawley, Gil R.; Farmer, Kenneth R.; Wittner, Christopher E.; Benham, Elizabeth A.; Eaton, Anthony P.; Martin, Joel L., Organometal catalyst compositions.
Max P. McDaniel ; James B. Kimble ; Kathy S. Collins ; Elizabeth A. Benham ; Michael D. Jensen ; Gil R. Hawley ; Joel L. Martin, Organometal catalyst compositions.
Max P. McDaniel ; Kathy S. Collins ; Anthony P. Eaton ; Elizabeth A. Benham ; Michael D. Jensen ; Joel L. Martin ; Gil R. Hawley, Organometal catalyst compositions.
Max P. McDaniel ; Kathy S. Collins ; James L. Smith ; Elizabeth A. Benham ; Marvin M. Johnson ; Anthony P. Eaton ; Michael D. Jensen ; Joel L. Martin ; Gil R. Hawley, Organometal catalyst compositions.
McDaniel, Max P.; Collins, Kathy S.; Benham, Elizabeth A.; Eaton, Anthony P.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R.; Hsieh, Eric T., Organometal catalyst compositions.
McDaniel, Max P.; Collins, Kathy S.; Eaton, Anthony P.; Benham, Elizabeth A.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst compositions.
McDaniel, Max P.; Shveima, Joseph S.; Smith, James L.; Collins, Kathy S.; Benham, Elizabeth A.; Eaton, Anthony P.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst compositions.
McDaniel, Max P.; Collins, Kathy S.; Benham, Elizabeth A.; Eaton, Anthony P.; Jensen, Michael D.; Martin, Joel L.; Hawley, Gil R., Organometal catalyst compositions with solid oxide supports treated with fluorine and boron.
Max P. McDaniel ; Kathy S. Collins ; Anthony P. Eaton ; Elizabeth A. Benham ; Joel L. Martin ; Michael D. Jensen ; Gil R. Hawley, Organometal compound catalyst.
McDaniel, Max P.; Collins, Kathy S.; Hawley, Gil R.; Jensen, Michael D.; Benham, Elizabeth A.; Eaton, Anthony P.; Martin, Joel L.; Wittner, Christopher E., Organometal compound catalyst.
Hawley, Gil R.; McDaniel, Max P.; Wittner, Christopher E.; Jensen, Michael D.; Martin, Joel L.; Benham, Elizabeth A.; Eaton, Anthony P.; Collins, Kathy S., Polymerization catalysts.
Hanson Donald O. (Bartlesville OK), Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator.
Hasegawa Saiki (Mie-ken JPX) Yasuda Hisami (Mie-ken JPX) Yano Akihiro (Mie-ken JPX), Process for producing a
상세보기
Max P. McDaniel ; Anthony P. Eaton ; Elizabeth A. Benham ; Shawn R. Kennedy ; Ashish M. Sukhadia ; Rajendra K. Krishnaswamy ; Kathy S. Collins, Process for producing a polymer composition.
McDaniel Max P. ; Collins Kathy S. ; Johnson Marvin M. ; Smith James L. ; Benham Elizabeth A. ; Hawley Gil R. ; Wittner Christopher E. ; Jensen Michael D., Process for producing polymers using a composition comprising an organometal compound, a treated solid oxide compound, and an organoaluminum compound.
Kol Moshe,ILX ; Tshuva Edit,ILX ; Goldschmidt Zeev,ILX, Ultra-high activity non-metallocene pre-catalyst and method for catalytic polymerization of alpha-olefin monomers.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.