[미국특허]
System and method for integrated adsorptive gas separation of combustion gases
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-053/04
B01D-053/62
F23C-009/08
B01D-053/047
F01K-017/04
F01K-023/10
F23J-015/02
B01D-053/06
출원번호
US-0128595
(2012-06-29)
등록번호
US-9146035
(2015-09-29)
국제출원번호
PCT/CA2012/050451
(2012-06-29)
§371/§102 date
20131221
(20131221)
국제공개번호
WO2013/003955
(2013-01-10)
발명자
/ 주소
Boulet, Andre
출원인 / 주소
INVENTYS THERMAL TECHNOLOGIES INC.
대리인 / 주소
Palmer IP
인용정보
피인용 횟수 :
4인용 특허 :
21
초록▼
An integrated fuel combustion system with adsorptive gas separation separates a portion of carbon dioxide from a combustion gas mixture and provides for recycle of separated carbon dioxide to the intake of the fuel combustor for combustion. A process for carbon dioxide separation and recycle include
An integrated fuel combustion system with adsorptive gas separation separates a portion of carbon dioxide from a combustion gas mixture and provides for recycle of separated carbon dioxide to the intake of the fuel combustor for combustion. A process for carbon dioxide separation and recycle includes: admitting combustion gas to an adsorptive gas separation system contactor containing adsorbent material; adsorbing a portion of carbon dioxide; recovering a first product gas depleted in carbon dioxide for release or use; desorbing carbon dioxide from the adsorbent material and recovering a desorbed second product gas enriched in carbon dioxide for sequestration or use; admitting a conditioning fluid into the contactor and desorbing a second portion of carbon dioxide to recover a carbon dioxide enriched conditioning stream; and recycling a portion of the carbon dioxide enriched conditioning stream to an inlet of fuel combustor to pass through the fuel combustor for combustion.
대표청구항▼
1. An integrated adsorptive gas separation process for separating at least a portion of a combustion gas mixture from a fuel combustor, said combustion gas mixture comprising at least carbon dioxide and nitrogen components, the process comprising: admitting said combustion gas mixture into an adsorp
1. An integrated adsorptive gas separation process for separating at least a portion of a combustion gas mixture from a fuel combustor, said combustion gas mixture comprising at least carbon dioxide and nitrogen components, the process comprising: admitting said combustion gas mixture into an adsorptive gas separation system;admitting said combustion gas mixture into an inlet end of at least one adsorbent contactor comprising at least one adsorbent material;adsorbing at least a portion of said carbon dioxide combustion gas component on at least one said adsorbent material;recovering a first product gas depleted in said carbon dioxide component relative to said combustion gas mixture from an outlet end of said adsorbent contactor;desorbing a first portion of said carbon dioxide component adsorbed on at least one said adsorbent material;recovering a desorbed second product gas enriched in said carbon dioxide component from at least one of said inlet and outlet ends of said adsorbent contactor;admitting a conditioning fluid into said adsorbent contactor and desorbing a second portion of said carbon dioxide component adsorbed on at least one said adsorbent material to recover a carbon dioxide enriched conditioning stream; andrecycling at least a portion of said carbon dioxide enriched conditioning stream recovered from said adsorbent contactor to an air inlet of said fuel combustor to pass through said fuel combustor for combustion. 2. The integrated adsorptive gas separation process according to claim 1, wherein said desorbing a first portion of said carbon dioxide component comprises desorbing a first portion of said carbon dioxide component adsorbed on at least one said adsorbent material by at least one of: thermal swing desorption by heating at least one said adsorbent material;pressure swing desorption; andpartial pressure swing desorption. 3. The integrated adsorptive gas separation process according to claim 1, wherein said fuel combustor comprises at least one of a gaseous fuel, liquid fuel and solid fuel fired combustor. 4. The integrated adsorptive gas separation process according to claim 1, wherein said fuel combustor comprises at least one of: a combined cycle gas turbine combustor;a gas turbine combustor;a coal-fired thermal combustor;a steam generator or boiler combustor; anda process heater combustor. 5. The integrated adsorptive gas separation process according to claim 1, wherein said first portion of said carbon dioxide component comprises about one third of said total carbon dioxide component adsorbed on said at least one adsorbent material, and wherein said second portion of said carbon dioxide component comprises about two thirds of said total carbon dioxide component adsorbed on said at least one adsorbent material. 6. The integrated adsorptive gas separation process according to claim 1, wherein said combustion gas mixture comprises about 12% carbon dioxide, and wherein said first portion of said carbon dioxide component comprises about 4% of said combustion gas mixture, and said second portion of said carbon dioxide component recycled to said combustor comprises about 8% of said combustion gas mixture. 7. The integrated adsorptive gas separation process according to claim 1, wherein said first product gas is substantially free of carbon dioxide, and said second desorbed product gas consists substantially of carbon dioxide. 8. The integrated adsorptive gas separation process according to claim 1, wherein said at least one adsorbent contactor comprises a parallel passage adsorbent contactor, said parallel passage adsorbent contactor comprising: a plurality of substantially parallel fluid flow passages oriented in a first axial direction between an inlet and an outlet end thereof; andcell walls situated between said fluid flow passages comprising at least one adsorbent material. 9. The integrated adsorptive gas separation process according to claim 8, wherein said at least one adsorbent contactor additionally comprises a plurality of axially continuous thermally conductive filaments oriented in said first axial direction and in direct contact with said at least one adsorbent material, and said process additionally comprising transferring heat along at least a portion of said thermally conductive filaments in either of said first axial direction or a second axial direction to provide at least a portion of the heat of desorption of said carbon dioxide component during said desorbing step. 10. The integrated adsorptive gas separation process according to claim 1 wherein said process comprises a thermal swing adsorptive gas separation process, and said adsorbing further comprises adsorbing at least a portion of said carbon dioxide component on said at least one adsorbent material at a first adsorbent material temperature, and said desorbing further comprises desorbing at least a portion of said carbon dioxide component adsorbed on said at least one adsorbent material by heating said adsorbent material at a second adsorbent material temperature. 11. The integrated adsorptive gas separation process according to claim 1 wherein said process comprises a thermal swing adsorptive gas separation process and wherein said desorbing additionally comprises heating said at least one adsorbent material using a heated process fluid admitted into said at least one adsorbent contactor, wherein said heated process fluid comprises at least one of: steam, combustion flue gas, and carbon dioxide. 12. The integrated adsorptive gas separation process according to claim 1 wherein said process comprises a pressure swing adsorptive gas separation process, and said adsorbing further comprises adsorbing at least a portion of said carbon dioxide component on said at least one adsorbent material at a first pressure, and said desorbing further comprises desorbing at least a portion of said carbon dioxide component adsorbed on said at least one adsorbent material at a second pressure lower than said first pressure. 13. The integrated adsorptive gas separation process according to claim 1 wherein said process comprises a partial pressure swing adsorptive gas separation process, and said adsorbing further comprises adsorbing at least a portion of said carbon dioxide component on said at least one adsorbent material at a first carbon dioxide partial pressure, and said desorbing further comprises desorbing at least a portion of said carbon dioxide component adsorbed on said at least one adsorbent material at a second carbon dioxide partial pressure lower than said first partial pressure. 14. The integrated adsorptive gas separation process according to claim 1, wherein said fuel combustor comprises a combined cycle gas turbine which additionally comprises a heat recovery steam generator, and wherein desorbing additionally comprises heating said at least one adsorbent material using steam from said heat recovery steam generator admitted into said at least one adsorbent contactor. 15. The integrated adsorptive gas separation process according to claim 9, wherein said process comprises a thermal swing adsorptive gas separation process, and wherein said desorbing additionally comprises directly heating at least one said adsorbent material by supplying thermal energy to said thermally conductive filaments to directly heat said cell walls comprising said at least one adsorbent material. 16. The integrated adsorptive gas separation process according to claim 9, wherein said axially continuous thermally conductive filaments additionally comprise axially continuous electrically conductive filaments, and wherein said desorbing additionally comprises directly heating at least one said adsorbent material by electrically heating said thermally and electrically conductive filaments to directly heat said cell walls comprising said at least one adsorbent material. 17. The integrated adsorptive gas separation process according to claim 1, wherein said at least one adsorbent material is selected from the list consisting of: activated carbon adsorbent, amine impregnated adsorbent supports (comprising silica, activated carbon, alumina, zeolite, polymer and ceramic supports), metal salt, metal hydroxide, metal oxide, zeolite, hydrotalcite, silicalite, metal organic framework and zeolitic imadazolate framework adsorbent materials, and combinations thereof. 18. The integrated adsorptive gas separation process according to claim 1, wherein said admitting, adsorbing, recovering a first product fluid, and desorbing and recovering a desorbed second product fluid steps are substantially isobaric and are conducted at one of substantially atmospheric and elevated supra-atmospheric pressures. 19. The integrated adsorptive gas separation process according to claim 1, wherein said admitting, adsorbing, and recovering a first product fluid are conducted at substantially atmospheric pressure, and wherein said desorbing and recovering a desorbed second product fluid steps are conducted at an elevated supra-atmospheric pressure. 20. The integrated adsorptive gas separation process according to claim 1, wherein said carbon dioxide enriched conditioning stream is heated by contact with said adsorbent contactor during said desorbing of said second portion of said carbon dioxide component adsorbed on said at least one said adsorbent material. 21. The integrated adsorptive gas separation process according to claim 1, wherein said carbon dioxide enriched conditioning stream is cooled by said desorbing of said second portion of said carbon dioxide component adsorbed on said at least one said adsorbent material. 22. The integrated adsorptive gas separation process according to claim 1, wherein said carbon dioxide enriched conditioning stream is enriched in carbon dioxide relative to an ambient carbon dioxide concentration in said air. 23. The integrated adsorptive gas separation process according to claim 1, wherein a carbon dioxide concentration of said first product gas depleted in said carbon dioxide component is less than an ambient carbon dioxide concentration of said air. 24. An integrated adsorptive gas separation system for separating at least a portion of a combustion gas mixture, said combustion gas mixture comprising at least carbon dioxide and nitrogen components, the system comprising: a fuel combustor comprising a combustor air inlet, a combustion chamber and a combustion gas outlet, wherein said combustion gas comprises at least carbon dioxide and nitrogen components;an adsorptive gas separator comprising at least one adsorbent contactor having an inlet and an outlet end, wherein said adsorptive gas separator is fluidly connected to said fuel combustor to receive said combustion gas as a feed gas mixture into said inlet end of said at least one adsorbent contactor and to adsorb at least a portion of said carbon dioxide component onto at least one adsorbent material comprised in said adsorbent contactor; anda combustion gas recycle fluid conduit which is fluidly connected to said adsorptive gas separator and to said combustor air inlet, and adapted to receive a desorbed combustion recycle gas comprising at least a portion of said carbon dioxide component adsorbed on said adsorbent material, and to return said desorbed combustion recycle gas to said combustor air inlet. 25. The integrated adsorptive gas separation system according to claim 24, wherein said adsorptive gas separator additionally comprises: at least one parallel passage adsorbent contactor comprising: a plurality of substantially parallel fluid flow passages oriented in a first axial direction between an inlet and an outlet end thereof; andcell walls situated between said fluid flow passages comprising at least one adsorbent material. 26. The integrated adsorptive gas separation system according to claim 24, wherein said adsorptive gas separator additionally comprises a plurality of axially continuous thermally conductive filaments oriented in said axial direction and in direct contact with said at least one adsorbent material. 27. The integrated adsorptive gas separation system according to claim 24, wherein said fuel combustor comprises at least one of: a combined cycle gas turbine combustor;a gas turbine combustor;a coal-fired thermal combustor;a steam generator or boiler combustor; anda process heater combustor. 28. The integrated adsorptive gas separation system according to claim 24, wherein said fuel combustor comprises a combined cycle gas turbine combustor which additionally comprises a heat recovery steam generator and a steam delivery conduit fluidly connected to said heat recovery steam generator and operable to deliver steam to said adsorptive gas separator for introduction into said at least one adsorptive contactor for desorbing at least a portion of said carbon dioxide component adsorbed on said at least one adsorbent material. 29. The integrated adsorptive gas separation system according to claim 24, wherein said at least one adsorbent material is selected from the list consisting of: activated carbon adsorbent, amine impregnated adsorbent supports (comprising silica, activated carbon, alumina, zeolite, polymer and ceramic supports), metal salt, metal hydroxide, metal oxide, zeolite, hydrotalcite, silicalite, metal organic framework and zeolitic imadazolate framework adsorbent materials, and combinations thereof.
Wijmans, Johannes G.; Merkel, Timothy C; Baker, Richard W., Combustion systems and power plants incorporating parallel carbon dioxide capture and sweep-based membrane separation units to remove carbon dioxide from combustion gases.
Baker, Richard W; Wijmans, Johannes G; Merkel, Timothy C; Lin, Haiqing; Daniels, Ramin; Thompson, Scott, Gas separation process using membranes with permeate sweep to remove CO.
Wijmans, Johannes G.; Merkel, Timothy C.; Baker, Richard W., Process for separating carbon dioxide from flue gas using parallel carbon dioxide capture and sweep-based membrane separation steps.
Mark J. Rood ; Patrick Sullivan ; K. James Hay, Selective sorption and desorption of gases with electrically heated activated carbon fiber cloth element.
Garcia-Crespo, Andres; Davis, Jr., Lewis Berkley; Gilchrist, III, George Martin; Toprani, Amit, System and method of cooling turbine airfoils with sequestered carbon dioxide.
Baker, Richard W; Merkel, Timothy C; Wijmans, Johannes G, Gas separation process using membranes with permeate sweep to remove CO2 from combustion exhaust.
Baker, Richard W; Merkel, Timothy C., Sweep-based membrane separation process for removing carbon dioxide from exhaust gases generated by multiple combustion sources.
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