Process using microchannel technology for conducting alkylation or acylation reaction
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07C-002/56
C07C-209/68
B01F-005/04
B01F-013/00
B01J-019/00
C07C-002/66
C07C-002/70
C07C-037/14
B01J-029/40
B01J-037/02
B01J-038/10
출원번호
US-0271154
(2005-11-11)
등록번호
US-9150494
(2015-10-06)
발명자
/ 주소
Tonkovich, Anna Lee
Perry, Steven T.
LaPlante, Timothy J.
Jarosch, Kai Tod Paul
Hickey, Thomas P.
Fitzgerald, Sean Patrick
Qiu, Dongming
Arora, Ravi
Sullivan, Timothy J.
Neagle, Paul
출원인 / 주소
Velocys, Inc.
대리인 / 주소
Renner, Otto, Boisselle & Sklar, LLP
인용정보
피인용 횟수 :
1인용 특허 :
76
초록▼
The disclosed invention relates to a process, comprising: flowing a first reactant feed stream comprising a reactant substrate and a second reactant feed stream comprising an alkylating agent, an acylating agent or a mixture thereof, in a process microchannel in contact with each other to form a pro
The disclosed invention relates to a process, comprising: flowing a first reactant feed stream comprising a reactant substrate and a second reactant feed stream comprising an alkylating agent, an acylating agent or a mixture thereof, in a process microchannel in contact with each other to form a product comprising at least one alkylation product, at least one acylation product, or a mixture thereof; transferring heat from the process microchannel to a heat sink; and removing the product from the process microchannel.
대표청구항▼
1. A process for conducting an alkylation or acylation reaction in a microchannel reactor, the microchannel reactor comprising a microchannel reactor core comprising a plurality of process microchannels and a feed stream header for distributing a reactant mixture to the process microchannels, the fe
1. A process for conducting an alkylation or acylation reaction in a microchannel reactor, the microchannel reactor comprising a microchannel reactor core comprising a plurality of process microchannels and a feed stream header for distributing a reactant mixture to the process microchannels, the feed stream header comprising a first reactant zone, a second reactant zone, and an apertured section positioned between the first reactant zone and the second reactant zone, the process comprising: flowing a first reactant feed stream into the first reactant zone, flowing a second reactant feed stream through the second reactant zone and the apertured section into the first reactant zone where it is mixed with the first reactant feed stream to form a reactant mixture, the reactant mixture comprising a dispersed phase of the second reactant feed stream and a continuous phase of the first reactant feed stream,the dispersed phase being in the form of gas bubbles and/or liquid droplets dispersed in the continuous phase, the reactant mixture comprising a reactant substrate, and an alkylating agent, an acylating agent or a mixture thereof, andflowing the reactant mixture from the feed stream header into the process microchannels, and reacting the reactant substrate with the alkylating agent, acylating agent, or mixture thereof in the presence of a catalyst in the process microchannels at a temperature in the range from about 100° C. to about 500° C. to form a product comprising at least one alkylation product, at least one acylation product, or a mixture thereof, the weight hourly space velocity for the flow of reactants in the microchannel reactor core being at least about 100 milliliters of feed per gram of catalyst per hour;transferring heat from the process microchannels to a heat sink; andremoving the product from the process microchannels. 2. The process of claim 1 wherein the catalyst is in the form of a liquid. 3. The process of claim 2 wherein the catalyst is mixed with the first reactant feed stream. 4. The process of claim 2 wherein the catalyst is mixed with the second reactant feed stream. 5. The process of claim 2 wherein the first reactant feed stream and the second reactant feed stream are mixed with the catalyst prior to entering the process microchannels. 6. The process of claim 1 wherein the process microchannels have internal dimensions of width or height of up to about 10 mm. 7. The process of claim 1 wherein the process microchannels have internal dimensions of width or height of up to about 2 mm. 8. The process of claim 1 wherein the process microchannels are made of a material comprising: steel; monel; inconel; aluminum; titanium; nickel; copper; brass; an alloy of any of the foregoing metals; a polymer;ceramics; glass; a composite comprising a polymer and fiberglass; quartz; silicon; or a combination of two or more thereof. 9. The process of claim 1 wherein the heat sink is adjacent to the process microchannels. 10. The process of claim 1 wherein the heat sink is remote from the process microchannels. 11. The process of claim 1 wherein the heat sink comprises at least one heat exchange channel. 12. The process of claim 11 wherein the heat exchange channel comprises a microchannel. 13. The process of claim 11 wherein the heat exchange channel has an internal dimension of width or height of up to about 10 mm. 14. The process of claim 11 wherein the heat exchange channel has an internal dimension of width or height of up to about 2 mm. 15. The process of claim 11 wherein the heat exchange channel is made of a material comprising: steel; monel; inconel; aluminum; titanium; nickel; copper; brass; an alloy of any of the foregoing metals; a polymer; ceramics; glass; a composite comprising polymer and fiberglass; quartz; silicon; or a combination of two or more thereof. 16. The process of claim 1 wherein the heat sink comprises one or more non-fluid cooling elements. 17. The process of claim 16 wherein the non-fluid cooling element is adjacent to the process microchannels. 18. The process of claim 16 wherein each process microchannel comprises one or more walls and the non-fluid cooling element is built into at least one of the walls of the process microchannels. 19. The process of claim 16 wherein each process microchannel comprises one or more walls and at least one of the walls of the process microchannel is formed from the non-fluid cooling element. 20. The process of claim 1 wherein the first reactant feed stream comprises one or more of an aliphatic compound, an aromatic compound, an aliphatic-substituted aromatic compound, an aromatic-substituted aliphatic compound, a hydrocarbon compound containing non-hydrocarbon groups, a hetero substituted hydrocarbon compound, or a mixture of two or more thereof. 21. The process of claim 1 wherein the first reactant feed stream comprises at least one aliphatic compound. 22. The process of claim 1 wherein the first reactant feed stream comprises at least one aromatic compound. 23. The process of claim 1 wherein the first reactant feed stream comprises at least one alkane and/or isoalkane. 24. The process of claim 1 wherein the first reactant feed stream comprises one or more polymers. 25. The process of claim 24 wherein the polymer is derived from one or more monomers containing 2 to about 12 carbon atoms. 26. The process of claim 1 wherein the first reactant feed stream comprises one or more of isobutane, isopentane, isohexane, 2-methyl butane, 2-methyl pentane and 3-methyl pentane. 27. The process of claim 1 wherein the first reactant feed stream comprises one or more of benzene, toluene, ethylbenzene, propylbenzene, xylene, mesitylene, methylethylbenzene, naphthalene, anthracene, phenanthrene, methylnaphthalene, dimethylnaphthalene and tetralin. 28. The process of claim 1 wherein the first reactant feed stream comprises one or more of phenol, benzene diol, naphthol and naphthalene diol. 29. The process of claim 1 wherein the first reactant feed stream comprises at least one aromatic amine, at least one pyridine, or a mixture thereof. 30. The process of claim 1 wherein the first reactant feed stream comprises one or more of aniline, toluidine, phenylene diamine and toluene diamine. 31. The process of claim 1 wherein the first reactant feed stream comprises one or more of o-xylene, m-xylene, p-xylene, toluene, tolyl aldehyde, amino toluene, o-cresol, m-cresol, p-cresol and phenyl aldehyde. 32. The process of claim 1 wherein the second reactant feed stream comprises an olefin containing from 2 to about 30 carbon atoms. 33. The process of claim 1 wherein the second reactant feed stream comprises an olefin containing from about 10 to about 18 carbon atoms. 34. The process of claim 1 wherein the second reactant feed stream comprises one or more of ethylene, propylene, butene-1, cis-butene-2, trans-butene-2, isobutylene, 1,3-butadiene, amylene, isoamylene, 2-pentene, 2-methyl-butene-2,1-pentene, 3-methyl-butene-1, 2-methyl-butene-1, isoprene, piperylene, cyclopentene, 1-hexene, 2-methyl-1-pentene, 2-methyl-2-pentene, 1-octene, diisobutylene, 1-decene, 1-dodecene, 2-dodecene, 1-tetradecene, 2-tetradecene, 1-hexadecene, 1-eicosene, α-pinene, camphene, limonene, and styrene. 35. The process of claim 1 wherein the second reactant feed stream comprises one or more of ethylene, propylene, butylene, isobutylene, and amylene. 36. The process of claim 1 wherein the product comprises one or more of ethylbenzene, C10-C18 alkyl benzene, cumene, cymene, refinery alkylate, detergent alkylate, and xylene. 37. The process of claim 1 wherein the product comprises an alkylated phenol, alkylated phenol derivative, or a mixture thereof. 38. The process of claim 1 wherein the product comprises an alkylated aromatic amine, an alkylated pyridene, or a mixture thereof. 39. The process of claim 1 wherein the product comprises one or more of dimethyl pentane, trimethyl pentane, 2,6-xylenol, o-cresol, and 5-tert-butyl-2,4-toluene diamine. 40. The process of claim 1 wherein the product comprises bisphenol A. 41. The process of claim 1 wherein the product comprises hydrocarbyl substituted carboxylic acid or anhydride. 42. The process of claim 11 wherein the process microchannels exchange heat with a heat exchange fluid flowing through the heat exchange channel. 43. The process of claim 42 wherein the heat exchange fluid undergoes a phase change as it flows through the heat exchange channel. 44. The process of claim 42 wherein the heat flux between the heat exchange channel and the process microchannels is in the range from about 0.01 to about 250 watts per square centimeter of surface area of the process microchannels. 45. The process of claim 11 wherein an endothermic process is conducted in the heat exchange channel. 46. The process of claim 45 wherein the endothermic process comprises a steam reforming reaction or a dehydrogenation reaction. 47. The process of claim 11 wherein the first reactant feed stream flows through the process microchannels in a first direction, and a heat exchange fluid flows through the heat exchange channel in a second direction, the second direction being cross current relative to the first direction. 48. The process of claim 11 wherein the first reactant feed stream flows through the process microchannels in a first direction, and a heat exchange fluid flows through the heat exchange channel in a second direction, the second direction being concurrent or counter current relative to the first direction. 49. The process of claim 11 wherein a heat exchange fluid flows through the heat exchange channel, the heat exchange fluid comprising the first reactant feed stream, the second reactant feed stream, or a mixture thereof. 50. The process of claim 11 wherein a heat exchange fluid flows through the heat exchange channel, the heat exchange fluid comprising one or more of air, steam, liquid water, carbon monoxide, carbon dioxide, gaseous nitrogen, liquid nitrogen, inert gas, gaseous hydrocarbon, oil, and liquid hydrocarbon. 51. The process of claim 1 wherein the apertured section comprises a relatively thin sheet overlying a relatively thick sheet or plate, the relatively thin sheet containing an array of relatively small apertures, and the relatively thick sheet or plate containing an array of relatively large apertures, at least some of the relatively small apertures being aligned with the relatively large apertures. 52. The process of claim 1 wherein the apertured section comprises apertures that are partially filled with a coating material. 53. The process of claim 1 wherein the apertured section is heat treated. 54. The process of claim 1 wherein the apertured section is made from a porous material. 55. The process of claim 54 wherein the porous material is metallic. 56. The process of claim 54 wherein the porous material is nonmetallic. 57. The process of claim 54 wherein the porous material is oxidized. 58. The process of claim 54 wherein the porous material is coated with alumina or nickel. 59. The process of claim 1 wherein the apertured section is made from a porous material, the surface of the porous material being treated by filling the pores on the surface with a liquid filler, solidifying the filler, grinding or polishing the surface, and removing the filler. 60. The process of claim 1 wherein the catalyst comprises a liquid catalyst. 61. The process of claim 1 wherein the catalyst comprises a solid catalyst. 62. The process of claim 1 wherein the catalyst comprises an acid catalyst. 63. The process of claim 1 wherein the catalyst comprises is a Friedel-Crafts catalyst. 64. The process of claim 1 wherein the catalyst comprises alumino-silicate, clay, ion-exchange resin, mixed oxide or supported acid. 65. The process of claim 1 wherein the catalyst comprises a zeolite. 66. The process of claim 1 wherein the catalyst comprises a hydrogenating metal component and a solid acid constituent. 67. The process of claim 1 wherein the catalyst comprises particulate solids. 68. The process of claim 1 wherein the catalyst is washcoated on interior walls of the process microchannel, grown on interior walls of the process microchannel from solution, or coated in situ on a fin structure. 69. The process of claim 1 wherein the catalyst comprises a support, an optional buffer layer overlying the support, an interfacial layer overlying the optional buffer layer or the support, and a catalyst material dispersed or deposited on the interfacial layer. 70. The process of claim 1 wherein the catalyst is supported by a support, the support being made of a material comprising one or more of silica gel, foamed copper, sintered stainless steel fiber, steel wool, alumina, poly(methyl methacrylate), polysulfonate, poly(tetrafluoroethylene), iron, nickel sponge, nylon, polyvinylidene difluoride, polypropylene, polyethylene, polyethylene ethylketone, polyvinyl alcohol, polyvinyl acetate, polyacrylate, polymethylmethacrylate, polystyrene, polyphenylene sulfide, polysulfone, polybutylene, or a combination of two or more thereof. 71. The process of claim 1 wherein the catalyst is supported on a support, the support comprising a heat conducting material. 72. The process of claim 1 wherein the catalyst is supported on a support, the support comprising an alloy comprising Ni, Cr and Fe, or an alloy comprising Fe, Cr, Al and Y. 73. The process of claim 1 wherein the catalyst is supported on a support having a flow-by configuration, a flow-through configuration, a honeycomb structure or a serpentine configuration. 74. The process of claim 1 wherein the catalyst is supported on a support having the configuration of a foam, felt, wad, fin, or a combination of two or more thereof. 75. The process of claim 1 wherein the catalyst is supported on a support having a flow-by configuration with an adjacent gap, a foam configuration with an adjacent gap, a fin structure with gaps, a washcoat on a substrate, or a gauze configuration with a gap for flow. 76. The process of claim 1 wherein the catalyst is supported on a support, the support comprising a fin assembly comprising at least one fin. 77. The process of claim 76 wherein the fin assembly comprises a plurality of parallel spaced fins. 78. The process of claim 76 wherein the fin has an exterior surface and a porous material overlies at least part of the exterior surface of the fin, the catalyst being supported by the porous material. 79. The process of claim 78 wherein the porous material comprises a coating, fibers, foam or felt. 80. The process of claim 76 wherein the fin has an exterior surface and a plurality fibers or protrusions extend from at least part of the exterior surface of the fin, the catalyst being supported by the protrusions. 81. The process of claim 76 wherein the fin has an exterior surface and the catalyst is: washcoated on at least part of the exterior surface of the fin; grown on at least part of the exterior surface of the fin from solution; or deposited on at least part of the exterior surface of the fin using vapor deposition. 82. The process of claim 76 wherein the fin assembly comprises a plurality of parallel spaced fins, at least one of the fins having a length that is different than the length of the other fins. 83. The process of claim 76 wherein the fin assembly comprises a plurality of parallel spaced fins, at least one of the fins having a height that is different than the height of the other fins. 84. The process of claim 76 wherein the fin has a cross section having the shape of a square, a rectangle, or a trapezoid. 85. The process of claim 76 wherein the fin is made of a material comprising: steel; aluminum; titanium; iron; nickel; platinum; rhodium; copper; chromium; brass; an alloy of any of the foregoing metals; a polymer; ceramics; glass; a composite comprising polymer and fiberglass; quartz; silicon; or a combination of two or more thereof. 86. The process of claim 76 wherein the fin is made of an alloy comprising Ni, Cr and Fe, or an alloy comprising Fe, Cr, Al and Y. 87. The process of claim 76 wherein the fin is made of an Al2O3 forming material or a Cr2O3 forming material. 88. The process of claim 1 wherein the catalyst is in the form of a layer of ZSM-5 zeolite having a thickness of up to about 1 micron. 89. The process of claim 1 wherein the catalyst is positioned within a reaction zone in each process microchannel, the reaction zone having a bulk flow path comprising about 5% to about 95% of the cross section of the process microchannel. 90. The process of claim 1 wherein the contact time for the first reactant feed stream, second reactant feed stream and product with the catalyst is in the range up to about 10 minutes. 91. The process of claim 1 wherein the temperature within each process microchannel is in the range from about 100° C. to about 400° C. 92. The process of claim 1 wherein the gage pressure within each process microchannel is in the range up to about 50 atmospheres. 93. The process of claim 1 wherein the weight hourly space velocity for the flow of reactants through the microchannel reactor core is in the range from about 100 to about 1,000,000 milliliters of feed per gram of catalyst per hour. 94. The process of claim 1 wherein the pressure drop for the flow of reactants and product through the process microchannels is up to about 0.5 atmosphere per meter of length of the process microchannels. 95. The process of claim 11 wherein a heat exchange fluid flows through the heat exchange channel, the pressure drop for the heat exchange fluid flowing through the heat exchange channel being up to about 0.5 atmosphere per meter of length of the heat exchange channel. 96. The process of claim 1 wherein the conversion of the reactant substrate is about 30% or higher per cycle. 97. The process of claim 1 wherein the conversion of the alkylating and/or acylating agent is about 80% or higher per cycle. 98. The process of claim 1 wherein the yield of product is about 60% or higher per cycle. 99. The process of claim 1 wherein subsequent to removing the product from the process microchannels, the process further comprises flowing a regenerating fluid through the process microchannels in contact with the catalyst, the residence time for the regenerating fluid in the process microchannels being from about 0.001 to about 10 seconds. 100. The process of claim 1 wherein each process microchannel comprises surface features formed in and/or on one or more interior walls for modifying flow and/or enhancing mixing within the process microchannel. 101. The process of claim 11 wherein the heat exchange channel comprises surface features formed in and/or on one or more interior walls for modifying flow and/or enhancing mixing within the heat exchange channel. 102. The process of claim 100 wherein the surface features are in the form of depressions in and/or projections from one or more of the microchannel interior walls and are oriented at angles relative to the direction of flow of fluid through the process microchannel. 103. The process of claim 100 wherein the surface features comprise two or more layers stacked on top of each other and/or intertwined in a three-dimensional pattern. 104. The process of claim 100 wherein the surface features are in the form of circles, oblongs, squares, rectangles, checks, chevrons, wavy shapes, or combinations thereof. 105. The process of claim 100 wherein the surface features comprise sub-features where the major walls of the surface features further contain smaller surface features in the form of notches, waves, indents, holes, burrs, checks, scallops, or combinations thereof.
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