Dental composition, method of producing and use thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
A61K-006/00
A61K-006/083
A61K-006/09
출원번호
US-0237210
(2012-08-10)
등록번호
US-9173820
(2015-11-03)
우선권정보
EP-11177273 (2011-08-11)
국제출원번호
PCT/US2012/050331
(2012-08-10)
§371/§102 date
20140205
(20140205)
국제공개번호
WO2013/023138
(2013-02-14)
발명자
/ 주소
Eckert, Adrian S.
Thalacker, Christoph
Dede, Karsten
출원인 / 주소
3M Innovative Properties Company
인용정보
피인용 횟수 :
0인용 특허 :
24
초록▼
The invention is directed to a composition comprising a) compound (A) being characterized by at least the following features: comprising a backbone unit (U) comprising a tricylclic hydrocarbon moiety, two spacer units (S) each comprising a hydrocarbon chain (G) being directly connected to the backbo
The invention is directed to a composition comprising a) compound (A) being characterized by at least the following features: comprising a backbone unit (U) comprising a tricylclic hydrocarbon moiety, two spacer units (S) each comprising a hydrocarbon chain (G) being directly connected to the backbone unit (U) via an urethane moiety, and at least two reactive groups (M) being connected to the hydrocarbon chain (G) via an ester linkage, with (G) being a non-branched hydrocarbon chain having a length of at least 3 carbon atoms, (G) not comprising ether moieties, and (M) being selected from acroyl and methacroyl, b) initiator (B) and c) optionally filler (C), the composition being a dental composition.
대표청구항▼
1. A composition comprising a) compound (A) being characterized by at least the following features: comprising a backbone unit (U) comprising a tricyclodecane moiety,two spacer units (S) each comprising a hydrocarbon chain (G) being directly connected to the backbone unit (U) via an urethane moiety,
1. A composition comprising a) compound (A) being characterized by at least the following features: comprising a backbone unit (U) comprising a tricyclodecane moiety,two spacer units (S) each comprising a hydrocarbon chain (G) being directly connected to the backbone unit (U) via an urethane moiety, wherein the urethane moiety is connected to the backbone unit (U) through the oxygen, andat least two reactive groups (M) being connected to the hydrocarbon chain (G) via an ester linkage, with (G) being a non-branched hydrocarbon chain selected from C3 to C8 alkylene moieties, (G) not comprising ether moieties and (M) being selected from acroyl and methacroyl,b) initiator (B) andc) filler (C), the composition being a dental composition, and being characterized by a Shrinkage Stress of below 1350 μstrain, and a Compressive Strength of at least 320 MPa. 2. The composition according to claim 1, compound (A) being characterized by at least one of the following features: Molecular weight (Mw): from about 500 to about 600,Functionality: 2 reactive groups per molecule,Number of urethane moieties: 2;Number of ester moieties: 2Viscosity: below about 200 Pa*s (measured at 23° C.). 3. The composition according to claim 1 not comprising moieties selected from epoxy, bisphenol, halogen and combinations thereof. 4. The composition according to claim 1, compound (A) being selected from and mixtures thereof. 5. The composition according to claim 1, initiator (B) being a redox initiator, a photo initiator or a combinations or mixture of both. 6. The composition according to claim 1, comprising in addition one or more of the following components: polymerizable compound (D) being different from compound (A)softener (E) not comprising polymerizable group(s),adjuvents (F). 7. The composition according to claim 6, the polymerizable compound (D) being selected from ethylenically unsaturated monomers, oligomers or polymers, combinations and mixtures thereof. 8. The composition according to claim 1 comprising the components in the following amounts: Compound (A): from about 5 to about 70 wt.-%,Initiator (B): from about 0.1 to about 3 wt.-%,Filler (C): from about 0 to about 90 wt.-%,Polymerizable compound (D): from about 0 to about 65 wt.-%,Softener (E): from about 0 to about 20 wt.-%,Adjuvant (F): from about 0 to about 25 wt.-%, wt.-% with respect to the weight of the whole composition. 9. The composition according to claim 1 being hardenable within about 30 min at a temperature below about 50° C. 10. The composition according to claim 1 being characterized by at least one of the following parameters after hardening: Flexural strength: at least 120 MPa,E-Modulus: at least 10 GPa but not higher than 14 GPa,Depth of Cure: at least 4.2 mm. 11. The composition according to claim 1 being contained in a container. 12. A kit of parts comprising at least 2 compositions as described in claim 1, the compositions differing from each other at least with respect to their colour. 13. A method of using the composition as described in claim 1 for producing a dental cement, a crown and bridge material, a dental filling material, a casting material, a cavity liner, a coating composition, a mill blank, an orthodontic device, a sealant or combinations thereof. 14. A process of producing a composition as described in claim 1 wherein compound (A) is obtained either by reacting a component comprising a tricyclic hydrocarbon moiety bearing at least two OH moieties witha component represented by the formula (MA)-(SU)-NCO, with (MA) being methacrylate or acrylate, (SU) being a non-branched spacer unit comprising at least about 3 carbon atoms, and NCO being an isocyanate moiety or by reacting a component comprising a tricyclo decane moiety bearing at least two OH moieties withan urethane moiety forming activating agent,followed by reaction with (MA)-(SU)-Y+X− with (MA) being methacrylate or acrylate, (SU) being a non-branched spacer unit comprising C3 to C8 alkylene moieties, X being selected from tosylate, mesylate, trifluoroacetate and Y being selected from ammonium. 15. A composition comprising a) compound (A) being characterized by at least the following features: comprising a backbone unit (U) comprising a tricyclodecane moiety,two spacer units (S) each comprising a hydrocarbon chain (G) being directly connected to the backbone unit (U) via an urethane moiety, wherein the urethane moiety is connected to the backbone unit (U) through the oxygen, andat least two reactive groups (M) being connected to the hydrocarbon chain (G) via an ester linkage, with(G) being a non-branched hydrocarbon chain selected from C3 to C8 alkylene moieties, (G) not comprising ether moieties and(M) being selected from acroyl and methacroyl,b) initiator (B) andc) filler (C), the composition being a dental composition.
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이 특허에 인용된 특허 (24)
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Shanklin Michael S. (Dayton OH) Gottschalk Peter (Centerville OH) Adair Paul C. (Springboro OH), Photohardenable composition containing borate salts and ketone initiators.
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Gottschalk Peter (Centerville OH) Neckers Douglas C. (Perrysburg OH) Schuster Gary B. (Champaign IL), Photosensitive materials containing ionic dye compounds as initiators.
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