Solvent-containing clearcoat coating composition, process for preparation thereof and use thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C09D-133/10
C09D-133/06
C09D-007/00
C09D-007/12
출원번호
US-0360133
(2012-11-22)
등록번호
US-9267054
(2016-02-23)
우선권정보
EP-11190752 (2011-11-25)
국제출원번호
PCT/EP2012/073392
(2012-11-22)
국제공개번호
WO2013/076208
(2013-05-30)
발명자
/ 주소
Wegner, Egon
Mayenfels, Peter
출원인 / 주소
BASF Coatings GmbH
대리인 / 주소
Servilla Whitney LLC
인용정보
피인용 횟수 :
0인용 특허 :
22
초록▼
Described is a solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer component composed of (A1) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of 15° C. to 100° C
Described is a solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer component composed of (A1) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of 15° C. to 100° C., and (A2) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of −100° C. to −20° C.; (B) a crosslinker component comprising at least one crosslinking agent having functional groups that are reactive toward OH groups; and also (C) at least one polyamide; and (D) at least one urea compound, which is an adduct of a polyisocyanate and methoxypropylamine. Also described is a process for preparing the solvent-containing clearcoat coating composition, to the use of the solvent-containing clearcoat coating composition and a clearcoat which has been produced using the clearcoat coating composition.
대표청구항▼
1. A solvent-containing clearcoat coating composition comprising: (A) 30% to 80% by weight, based on the nonvolatile fraction of the overall clearcoat coating composition, of an OH-functional (meth)acrylate (co)polymer component composed of (A1) 30%-99% by weight, based on the mass of the nonvolatil
1. A solvent-containing clearcoat coating composition comprising: (A) 30% to 80% by weight, based on the nonvolatile fraction of the overall clearcoat coating composition, of an OH-functional (meth)acrylate (co)polymer component composed of (A1) 30%-99% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of 15° C. to 100° C., and(A2) 1%-70% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of 90° C. to 35° C., wherein the amount of (A1) is more than twice the amount of (A2) by weight;(B) a crosslinker component comprising at least one crosslinking agent having functional groups that are reactive toward OH groups;(C) 0.02%-1.2% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one polyamide;(D) 0.04%-2.9% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one urea compound which is an adduct of a polyisocyanate and methoxypropylamine; and(E) 10% to 50% by weight, based on the mass of the nonvolatile fraction of component (A), of a polyester having an OH number of 8-280 mg KOH/g and a glass transition temperature Tg of −80° C. to 20° C. 2. The solvent-containing clearcoat coating composition of claim 1, wherein the (meth)acrylate (co)polymers (A1) and (A2) have an OH number of 70-180 mg KOH/g. 3. The solvent-containing clearcoat coating composition of claim 1, wherein the crosslinking component (B) comprises as crosslinking agent(s) at least one polyisocyanate and/or at least one amino resin. 4. The solvent-containing clearcoat coating composition of claim 1, wherein the crosslinking agents in the crosslinking component (B) are nonblocked polyisocyanates. 5. The solvent-containing clearcoat coating composition of claim 3, wherein the crosslinking agent is a trimeric hexamethylene diisocyanate. 6. The solvent-containing clearcoat coating composition of claim 1, wherein the solvent-containing clearcoat composition is a two-component clearcoat coating composition. 7. The solvent-containing clearcoat coating composition of claim 1, wherein the polyamides (C) are synthetic polyamide waxes. 8. The solvent-containing clearcoat coating composition of claim 1, wherein the polyamides (C) are reaction products of monomeric polyamines and (hydroxy) fatty acids which comprise 16 to 20 C atoms per molecule. 9. A process for preparing the solvent-containing clearcoat coating composition of claim 1, the process comprising mixing the OH-functional (meth)acrylate (co)polymer component, the crosslinker component, the polyamide, the urea compound, and the polyester together. 10. The process of claim 9, wherein the OH-functional (meth)acrylate (co)polymer component (A) is mixed with the further constituents, apart from the crosslinker component (B), and the crosslinker component (B) with at least one organic solvent added is mixed in only within 30 minutes prior to application to a substrate. 11. The process of claim 9, wherein the urea compound is added in the form of a paste which comprises a mixture of the urea compound with a polyester and/or a (meth)acrylate (co)polymer and at least one organic solvent. 12. The process of claim 9, wherein the polyamides are added in the form of a dispersion which comprises a mixture of the polyamides with a (meth)acrylate (co)polymer and at least one organic solvent. 13. A method of producing a cured clearcoat, the method comprising applying the solvent-containing clearcoat coating composition of claim 1 to a substrate, and subsequently thermal curing at a temperature of 40 to 190° C. 14. A clearcoat on a substrate, comprising the clearcoat coating composition of claim 1 coated onto a substrate.
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