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A method for treating engine exhaust. The method includes contacting an NOx exhaust with an upstream catalyst material coated onto a substrate and including copper or iron loaded in a first zeolite at an upstream loading of 0 to 3.5 g/l to convert the NOx exhaust in a first temperature range of 150°

A method for treating engine exhaust. The method includes contacting an NOx exhaust with an upstream catalyst material coated onto a substrate and including copper or iron loaded in a first zeolite at an upstream loading of 0 to 3.5 g/l to convert the NOx exhaust in a first temperature range of 150° C. to 500° C. to a first NOx converted exhaust. The method further includes contacting the first NOx converted exhaust with a downstream catalyst material coated onto the substrate downstream of the upstream catalyst material and including copper or iron loaded in a second zeolite at a downstream loading of 1.5 to 9.5 g/l to convert the first NOx converted exhaust in a second temperature range of 450° C. to 700° C.

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1. A method comprising: contacting an NOx exhaust with an upstream catalyst material coated onto a substrate and including copper or iron loaded in a first zeolite at an upstream loading of 0 to 3.5 g/l to convert the NOx exhaust in a first temperature range of 150° C. to 500° C. to a first NOx conv

1. A method comprising: contacting an NOx exhaust with an upstream catalyst material coated onto a substrate and including copper or iron loaded in a first zeolite at an upstream loading of 0 to 3.5 g/l to convert the NOx exhaust in a first temperature range of 150° C. to 500° C. to a first NOx converted exhaust; andcontacting the first NOx converted exhaust with a downstream catalyst material coated onto the substrate downstream of the upstream catalyst material and including copper or iron loaded in a second zeolite at a downstream loading of 1.5 to 9.5 g/l to convert the first NOx converted exhaust in a second temperature range of 450° C. to 700° C. 2. The method of claim 1, further comprising contacting the NOx exhaust with an oxidation catalyst prior to the first contacting step. 3. The method of claim 1, wherein the substrate includes a plurality of flow channels. 4. The method of claim 1, wherein each of the upstream and downstream catalyst materials is copper. 5. The method of claim 1, wherein the first and second base metals are iron. 6. The method of claim 1, wherein each of the first and second zeolites is an alkaline earth metal exchanged zeolite. 7. The method of claim 1, wherein each of the first and second zeolites is a precious metal exchanged zeolite. 8. A method comprising: coating an upstream substrate with an upstream catalyst material including copper at an upstream loading; andcoating a downstream substrate with a downstream catalyst material including copper at a downstream loading, the upstream and downstream copper loadings are substantially uniform and the upstream and downstream catalyst materials have an increasing coating thickness in an exhaust flow direction. 9. The method of claim 8, wherein the upstream catalyst material has a NOx conversion activity at a first temperature and the downstream catalyst material has a NOx conversion activity at a second temperature less than the first temperature. 10. The method of claim 8, further comprising forming the upstream and downstream substrates as a monolith. 11. The method of claim 10, wherein the monolith is a ceramic material. 12. The method of claim 10, wherein the monolith is a metallic material. 13. The method of claim 10, wherein the monolith includes a plurality of flow channels. 14. A method comprising: coating an upstream substrate with an upstream catalyst material including copper at an upstream loading; andcoating a downstream substrate with a downstream catalyst material including copper at a downstream loading, the upstream and downstream copper loadings are substantially uniform and the upstream and downstream catalyst materials have an increasing coating thickness in an exhaust flow direction, and one of the upstream and the downstream substrates is a wall flow ceramic substrate. 15. The method of claim 14, wherein both of the upstream and downstream substrates are wall flow ceramic substrates. 16. The method of claim 15, further comprising forming the upstream and downstream substrates as a monolith. 17. The method of claim 16, wherein the monolith includes a plurality of flow channels. 18. The method of claim 14, wherein the upstream catalyst material has a NOx conversion activity at a first temperature and the downstream catalyst material has a NOx conversion activity at a second temperature less than the first temperature. 19. The method of claim 14, wherein the wall flow ceramic substrate includes cordierite. 20. The method of claim 14, wherein the wall flow ceramic substrate includes mullite.