Emissions treatment system with ammonia-generating and SCR catalysts
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-050/00
B01D-053/94
F01N-003/035
F01N-003/08
F01N-003/20
F01N-003/10
F01N-013/02
출원번호
US-0274300
(2014-05-09)
등록번호
US-9358503
(2016-06-07)
발명자
/ 주소
Wan, Chung-Zong
Zheng, Xiaolai
Stiebels, Susanne
Wendt, Claudia
Neubauer, Torsten
Boorse, R. Samuel
출원인 / 주소
BASF Corporation
대리인 / 주소
Womble Carlyle Sandridge & Rice, LLP
인용정보
피인용 횟수 :
0인용 특허 :
45
초록▼
Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sie
Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
대표청구항▼
1. An emissions treatment system for an exhaust stream of a diesel engine or a lean burn gasoline engine comprising: a lean NOx trap (LNT) catalytic material disposed on a carrier, wherein the lean NOx trap catalytic material is capable of adsorbing NOx during lean engine operation and reducing NOx
1. An emissions treatment system for an exhaust stream of a diesel engine or a lean burn gasoline engine comprising: a lean NOx trap (LNT) catalytic material disposed on a carrier, wherein the lean NOx trap catalytic material is capable of adsorbing NOx during lean engine operation and reducing NOx to N2, desorbing NOx, and generating NH3 during rich engine operation, the catalytic material comprising an undercoat washcoat layer comprising at least one NOx sorbent including an element selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof, wherein the undercoat washcoat layer is on the carrier; and a top washcoat layer comprising a support material, and at least one platinum group metal, the top washcoat layer being substantially free of alkaline earth components; andan SCR catalyst disposed downstream of the lean NOx trap catalytic material, wherein the SCR catalyst comprises a molecular sieve having the CHA crystal structure. 2. The emissions treatment system of claim 1, wherein the SCR catalyst is present in an amount in the range of 0.5 to 2.5 g/in3. 3. The emissions treatment system of claim 1, wherein the molecular sieve comprises a copper chabazite (CuCHA), and the CuCHA is disposed on a downstream carrier. 4. The emissions treatment system of claim 3, wherein the molecular sieve is a copper chabazite SSZ-13. 5. The emissions treatment system of claim 3, wherein the lean NOx trap (LNT) catalytic material comprises platinum, palladium and rhodium. 6. The emissions treatment system of claim 5, wherein the platinum, palladium and rhodium are present in an amount in the range of 50 to 200 g/ft3. 7. The emissions treatment system of claim 1, wherein the molecular sieve comprises a copper SAPO (CuSAPO), and the CuSAPO is disposed on a downstream carrier. 8. The emissions treatment system of claim 7, wherein the molecular sieve is copper SAPO-34. 9. The emissions treatment system of claim 1, wherein the downstream carrier comprises a wall flow filter having a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end. 10. The emissions treatment system of claim 9, wherein the filter is coated by the SCR catalyst in the range of about 10% to 100% of the axial length. 11. The emissions treatment system of claim 1, wherein the lean NOx trap (LNT) catalytic material is disposed on an upstream carrier that is a flow through monolith. 12. The emissions treatment system of claim 1, wherein the SCR catalyst is effective to reduce a spike in ammonia by at least about 50% or greater. 13. The emissions treatment system of claim 1, wherein the lean NOx trap (LNT) catalytic material comprises platinum, palladium and rhodium. 14. The emissions treatment system of claim 13, wherein the platinum, palladium and rhodium are present in an amount in the range of 50 to 200 g/ft3. 15. A method of converting NOx in an exhaust gas stream from a diesel engine or lean burn gasoline engine to N2 comprising: routing the exhaust gas stream through the emissions treatment system of claim 14. 16. A method of converting NOx in an exhaust gas stream from a diesel engine or lean burn gasoline engine to N2 comprising: routing the exhaust gas stream through the emissions treatment system of claim 13. 17. A method of converting NOx in an exhaust gas stream from a diesel engine or lean burn gasoline engine to N2 comprising: routing the exhaust gas stream through the emissions treatment system of claim 1. 18. The method of claim 17, comprising: (a) contacting the exhaust gas stream comprising NOx in a lean period with the lean NOx trap (LNT) catalytic material to sorb NOx from the exhaust gas stream;(b) periodically altering the air/fuel ratio of the exhaust stream to provide a rich gaseous stream during a rich period;(c) contacting the rich gaseous stream with the LNT to reduce a portion of the sorbed NOx to ammonia and sorbing ammonia on the SCR catalyst;(d) subsequently reacting ammonia sorbed on the SCR catalyst with NOx in the exhaust gas with the SCR catalyst; and(e) wherein the SCR catalyst is effective to reduce a spike in ammonia. 19. The method of claim 18, wherein step (d) occurs during a lean period of operation. 20. The emissions treatment system of claim 1, further comprising an oxidation catalyst upstream of the lean NOx trap (LNT) catalytic material. 21. The emissions treatment system of claim 1, wherein the undercoat washcoat layer comprises one or more refractory metal oxides supporting at least one alkaline earth element and at least one platinum group metal. 22. The emissions treatment system of claim 21, wherein the one or more refractory metal oxides are selected from the group consisting of alumina, ceria, zirconia, and combinations thereof. 23. The emissions treatment system of claim 1, wherein the top washcoat layer comprises one or more refractory metal oxides supporting at least one platinum group metal. 24. The emissions treatment system of claim 23, wherein the one or more refractory metal oxides are selected from the group consisting of alumina, ceria, zirconia, and combinations thereof. 25. The emissions treatment system of claim 1, wherein the undercoat washcoat layer comprises alumina, ceria, at least one platinum group metal, and at least one of barium oxide and magnesium oxide. 26. The emissions treatment system of claim 1, wherein the top washcoat layer comprises alumina, ceria, and at least one platinum group metal. 27. The emissions treatment system of claim 1, wherein the undercoat washcoat layer comprises one or more refractory metal oxides supporting at least one alkaline earth element and at least one platinum group metal; and the top washcoat layer comprises one or more refractory metal oxides supporting at least one platinum group metal. 28. The emissions treatment system of claim 27, wherein the undercoat washcoat layer comprises alumina, ceria, at least one platinum group metal, and at least one of barium oxide and magnesium oxide; and the top washcoat layer comprises alumina, ceria, and at least one platinum group metal. 29. The emissions treatment system of claim 27, wherein the molecular sieve comprises copper chabazite (CuCHA) or copper SAPO (CuSAPO).
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