Carbon dioxide adsorbent including zeolite and methods for preparing the same
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-053/02
B01J-029/70
B01J-020/18
B01J-020/30
B01J-020/34
출원번호
US-0181818
(2014-02-17)
등록번호
US-9358530
(2016-06-07)
우선권정보
KR-10-2013-0025847 (2013-03-11)
발명자
/ 주소
Kwon, Hyuk Jae
Kwon, Soon Chul
Lee, Hyun Chul
Ahn, Wha Seung
Hong, Seung Hwan
출원인 / 주소
SAMSUNG ELECTRONICS CO., LTD.
대리인 / 주소
Harness, Dickey & Pierce, P.L.C.
인용정보
피인용 횟수 :
0인용 특허 :
3
초록▼
A carbon dioxide adsorbent may include a chabazite zeolite containing an alkali metal ion or an alkaline earth metal ion. The chabazite zeolite may have a Si/Al mole ratio of about 1 to about 9.9. The carbon dioxide adsorbent may be included in a carbon dioxide capture module. The carbon dioxide ads
A carbon dioxide adsorbent may include a chabazite zeolite containing an alkali metal ion or an alkaline earth metal ion. The chabazite zeolite may have a Si/Al mole ratio of about 1 to about 9.9. The carbon dioxide adsorbent may be included in a carbon dioxide capture module. The carbon dioxide adsorbent may also be used in a method of separating carbon dioxide.
대표청구항▼
1. A carbon dioxide adsorbent comprising: a chabazite zeolite containing an alkali metal ion or an alkaline earth metal ion, the chabazite zeolite having a Si/Al mole ratio of about 1 to about 9.9, the chabazite zeolite being a reaction product of a non-chabazite structure zeolite, the chabazite zeo
1. A carbon dioxide adsorbent comprising: a chabazite zeolite containing an alkali metal ion or an alkaline earth metal ion, the chabazite zeolite having a Si/Al mole ratio of about 1 to about 9.9, the chabazite zeolite being a reaction product of a non-chabazite structure zeolite, the chabazite zeolite having a chabazite structure obtained by structural transformation using a strong base, the carbon dioxide adsorbent having a CO2 adsorption capacity of greater than or equal to about 5 wt % at a temperature of 120° C. 2. The carbon dioxide adsorbent of claim 1, wherein the Si/Al mole ratio is about 1 to about 3. 3. The carbon dioxide adsorbent of claim 1, wherein the alkali metal ion or the alkaline earth metal ion includes a lithium ion, a sodium ion, a potassium ion, a magnesium ion, or a calcium ion. 4. The carbon dioxide adsorbent of claim 1, wherein the non-chabazite structure zeolite has a faujasite structure or a mordenite structure. 5. The carbon dioxide adsorbent of claim 1, wherein the chabazite zeolite has a specific surface area of 600 m2/g or less. 6. A process for preparing a carbon dioxide adsorbent, comprising: obtaining a zeolite having a non-chabazite structure and a Si/Al mole ratio of about 1 to 9.9;adding the zeolite to an aqueous solution of a strong base having an alkali metal ion or an alkaline earth metal ion;subjecting the zeolite and the aqueous solution to a hydrothermal treatment to obtain a chabazite zeolite including the alkali metal ion or the alkaline earth metal ion; andseparating the chabazite zeolite, the Si/Al mole ratio of the chabazite zeolite being about 1 to about 9.9, the chabazite zeolite being a reaction product of the non-chabazite structure zeolite, the chabazite zeolite having a chabazite structure obtained by structural transformation using the strong base, the carbon dioxide adsorbent having a CO2 adsorption capacity of greater than or equal to about 5 wt % at a temperature of 120° C. 7. The process of claim 6, further comprising: exchanging the alkali metal ion or the alkaline earth metal ion contained in the chabazite zeolite with another alkali metal ion or another alkaline earth metal ion. 8. The process of claim 6, wherein the subjecting the zeolite and the aqueous solution to a hydrothermal treatment includes the chabazite structure being formed without using a structure directing agent. 9. The process of claim 6, wherein the obtaining a zeolite having a non-chabazite structure includes obtaining faujasite, mordenite, or a combination thereof. 10. The process of claim 6, wherein the obtaining a zeolite having a non-chabazite structure includes the Si/Al mole ratio ranging from about 1 to about 3. 11. The process of claim 6, wherein the adding the zeolite to an aqueous solution includes the strong base including KOH, NaOH, or LiOH. 12. The process of claim 6, wherein the subjecting the zeolite and the aqueous solution to a hydrothermal treatment is conducted at a temperature of higher than or equal to about 80° C. for a period of time of about 40 hours or longer. 13. A method of separating carbon dioxide, comprising: contacting a carbon dioxide adsorbent with an input gas stream containing carbon dioxide, the carbon dioxide adsorbent including a chabazite zeolite containing an alkali metal ion or an alkaline earth metal ion, the chabazite zeolite having a Si/Al mole ratio of about 1 to about 9.9, the chabazite zeolite being a reaction product of a non-chabazite structure zeolite, the chabazite zeolite having a chabazite structure obtained by structural transformation using a strong base, the carbon dioxide adsorbent having a CO2 adsorption capacity of greater than or equal to about 5 wt % at a temperature of 120° C. 14. The method of claim 13, wherein the contacting a carbon dioxide adsorbent includes the alkali metal ion or the alkaline earth metal ion including a lithium ion, a sodium ion, a potassium ion, a magnesium ion, or a calcium ion. 15. The method of claim 13, wherein the contacting a carbon dioxide adsorbent includes the Si/Al mole ratio ranging from about 1 to about 3. 16. The method of claim 13, further comprising: heat-treating the carbon dioxide adsorbent at a temperature of about 200° C. to about 500° C. to desorb the carbon dioxide. 17. The method of claim 16, wherein the heat-treating is performed under a reduced pressure. 18. The method of claim 13, wherein the contacting a carbon dioxide adsorbent includes the input gas stream further including at least one gas selected from hydrogen, nitrogen, and methane. 19. The method of claim 13, wherein the contacting a carbon dioxide adsorbent includes the input gas stream contacting the carbon dioxide adsorbent at a temperature of about 30° C. to about 500° C.
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이 특허에 인용된 특허 (3)
White,Mark G.; Iretski,Alexei V; Weigel,Scott Jeffrey; Chiang,Robert Ling; Brzozowski,Jeffrey Richard, Adsorbents, methods of preparation, and methods of use thereof.
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