초록 ▼

A dental adhesive composition is described comprising a photocurable ionomer, radiopaque metal oxide nanoparticles, a phosphorous-containing acidic monomer, other polymerizable resin components, and a polar solvent. In a favored embodiment, the adhesive composition comprises a photocurable ionomer i

A dental adhesive composition is described comprising a photocurable ionomer, radiopaque metal oxide nanoparticles, a phosphorous-containing acidic monomer, other polymerizable resin components, and a polar solvent. In a favored embodiment, the adhesive composition comprises a photocurable ionomer in an amount up to 15 wt-%; 5 wt-% to 30 wt-% of radiopaque metal oxide nanoparticles that comprise a basic surface (such as zirconia) wherein the nanoparticles comprise an organosilane surface treatment; a phosphorous-containing acidic monomer in an amount up to 10 wt-%; and 10 wt-% to 50 wt-% of solvent comprising water and at least one alcohol, ketone, or mixture thereof.

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1. An adhesive composition comprising: a one-part dispersion comprising the following components pre-mixed in a single container;a photocurable ionomer having a molecular weight between 1000 and 100,000 g/mol in an amount up to 15 wt-% wherein the photocurable ionomer has the general formula: B(X)m(

1. An adhesive composition comprising: a one-part dispersion comprising the following components pre-mixed in a single container;a photocurable ionomer having a molecular weight between 1000 and 100,000 g/mol in an amount up to 15 wt-% wherein the photocurable ionomer has the general formula: B(X)m(Y)n whereinB represents an organic polymeric backbone,each X independently is an ionic group,each Y independently is a photocurable group,m is a number having an average value of 2 or more, andn is a number having an average value of 1 or more;5 wt-% to 30 wt-% of radiopaque metal oxide nanoparticles;phosphorous-containing acidic monomer(s);30 wt-% to 50 wt-% of other polymerizable resin components; and10 wt-% to 50 wt-% of solvent comprising waterwherein the adhesive composition is substantially free of acid-reactive filler such that the adhesive composition is stable at 45° C. for at least 90 days. 2. The adhesive composition of claim 1 wherein the radiopaque metal oxide nanoparticles comprise an organosilane surface treatment. 3. The adhesive composition of claim 1 wherein the radiopaque metal oxide nanoparticles comprise zirconia. 4. The adhesive composition of claim 3 wherein the organosilane surface treatment is copolymerizable with the photocurable ionomer. 5. The adhesive composition of claim 1 wherein the photocurable ionomer comprises pendent ionic groups and pendent free-radically polymerizable groups and at least one of the polymerizable groups is linked to the ionomer by means of an amide linkage. 6. The adhesive composition of claim 1 wherein the photocurable ionomer comprises carboxyl groups and (meth)acrylate groups. 7. The adhesive composition of claim 1 wherein the radiopaque metal oxide nanoparticles are present in an amount of 10 wt-% to 30 wt-%. 8. The adhesive composition of claim 1 wherein the phosphorous-containing acidic monomer(s) is present in the adhesive composition in an amount up to 10 wt-%. 9. The adhesive composition of claim 1 wherein the adhesive is suitable for use as a dental adhesive. 10. A method of applying a dental composition comprising: providing a dental adhesive of claim 1;applying the dental adhesive to a hard tissue surface; andhardening the dental composition by curing. 11. The method of claim 10 wherein the hard dental tissue is selected from enamel, dentin, and a combination thereof. 12. The method of claim 10 wherein the adhesive is applied to the hard tissue surface with pretreating the surface with an etchant, primer, or combination thereof. 13. The method of claim 10 wherein the method further comprises contacting the dental adhesive with a curable dental restoration material or preformed dental article prior to hardening. 14. The method of claim 1 wherein the dental composition is hardened by photocuring. 15. The adhesive composition of claim 1 wherein the adhesive comprises at least 10 wt-% of polar solvent selected from alcohol, ketone, or mixture thereof.