Three-way catalyst systems including Fe-activated Rh and Ba-Pd material compositions
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-027/25
B01J-023/00
B01J-023/02
B01J-023/10
B01J-023/40
B01J-023/42
B01J-023/44
B01J-023/56
B01J-023/58
B01J-023/70
B01J-023/74
B01J-021/04
B01D-053/94
B01J-023/89
B01J-035/04
B01J-023/20
B01J-023/63
B01J-027/232
B01J-035/00
출원번호
US-0732473
(2015-06-05)
등록번호
US-9475005
(2016-10-25)
발명자
/ 주소
Hatfield, Randal L.
Lee, Edward J.
Ngo, Johnny T.
Golden, Stephen J.
출원인 / 주소
Clean Diesel Technologies, Inc.
대리인 / 주소
Alston & Bird LLP
인용정보
피인용 횟수 :
0인용 특허 :
60
초록▼
Three way catalysts (TWCs) for catalyst systems are disclosed. The disclosed TWC systems include Iron (Fe)-activated Rhodium (Rh) and Barium (Ba)-Palladium (Pd) layers capable of interacting with conventional and/or non-conventional catalyst supports and additives. Variations of TWC system samples a
Three way catalysts (TWCs) for catalyst systems are disclosed. The disclosed TWC systems include Iron (Fe)-activated Rhodium (Rh) and Barium (Ba)-Palladium (Pd) layers capable of interacting with conventional and/or non-conventional catalyst supports and additives. Variations of TWC system samples are produced including Fe-activated Rh layers deposited onto a washcoat (WC) layer having one or more of an oxygen storage material (OSM). Other TWC system samples are produced including an impregnation (IMPG) layer having loading variations of Ba within a Pd, Ce, and Nd applied onto an OSM WC layer, and a further overcoat layer including Fe-activated Rh is applied onto the IMPG layer. The catalytic performance of disclosed TWC catalysts is evaluated by performing a series of light-off tests, wide pulse perturbation tests, and standard isothermal oxygen storage capacity oscillating tests. Disclosed TWC catalysts exhibit high catalytic performance and significant oxygen storage capacity.
대표청구항▼
1. A catalyst system, comprising: a substrate;a washcoat deposited on the substrate;at least one impregnation layer; andan overcoat;wherein the washcoat comprises at least one of the group consisting of about 10 (w/w) to about 75 (w/w) cerium oxide, about 25 (w/w) to about 90 (w/w) zirconium-hafnium
1. A catalyst system, comprising: a substrate;a washcoat deposited on the substrate;at least one impregnation layer; andan overcoat;wherein the washcoat comprises at least one of the group consisting of about 10 (w/w) to about 75 (w/w) cerium oxide, about 25 (w/w) to about 90 (w/w) zirconium-hafnium oxide, about 0 (w/w) to about 15 (w/w) lanthanum oxide, about 0 (w/w) to about 15 (w/w) neodymium oxide, about 0 (w/w) to about 15 (w/w) yttrium oxide, and about 0 (w/w) to about 15 (w/w) praseodymium oxide;wherein the at least one impregnation layer comprises rhodium at about 1 g/ft3 to about g/ft3 and iron at about 60 g/ft3 to about 630 g/ft3 ; andwherein the overcoat comprises at least one of the group consisting of an oxygen storage material, support oxides, barium carbonate, doped alumina, strontium carbonate, and combinations thereof. 2. The catalyst system of claim 1, wherein the overcoat is platinum group metal free. 3. The catalyst system of claim 1, wherein the washcoat comprises a first oxygen storage material including about 31 (w/w) cerium, about 58 (w/w) zirconium-hafnium, about 5.5 (w/w) neodymium, and about 5 (w/w) yttrium oxide. 4. The catalyst system of claim 1, wherein the at least one impregnation layer comprises about 3 g/ft3 rhodium. 5. The catalyst system of claim 1, wherein the at least one impregnation layer comprises about 140 g/ft3 iron. 6. The catalyst system of claim 1, wherein the overcoat comprises the oxygen storage material and wherein the oxygen storage material includes about 30 (w/w) Ce, about 60 (w/w) Zr—Hf, about 5 (w/w) Nd, and about 5 (w/w) Pr oxides. 7. The catalyst system of claim 1, wherein the overcoat comprises the oxygen storage material and wherein the oxygen storage material includes about 30 (w/w) Ce, about 58 (w/w) Zr—Hf, about 5.5 (w/w) Nd, and about 5 (w/w) yttrium oxides and wherein the oxygen storage material is loaded at about 42 g/L. 8. The catalyst system of claim 1, wherein the overcoat comprises high surface area alumina stabilized with La2O3 . 9. The catalyst system of claim 8, wherein the overcoat is loaded with 40 g/L of the high surface area alumina stabilized with La2O3. 10. A catalyst system, comprising: a substrate;a washcoat deposited on the substrate;at least one impregnation layer impregnated in the washcoat; andan overcoat;wherein the at least one impregnation layer comprises Pd nitrate, Ce nitrate, Nd nitrate,and a Ba salt;wherein the Ba salt is loaded from about 50 g/ft3 to about 700 g/ft3. 11. The catalyst system of claim 10, wherein the overcoat comprises an oxygen storage material including Ce, Zr, Nd, and Y; wherein the oxygen storage material is impregnated with Fe nitrate; and wherein the overcoat is further impregnated with Rh nitrate. 12. The catalyst system of claim 11, wherein the overcoat is loaded with about 9 g/ft3 Rh. 13. The catalyst system of claim 12, wherein the overcoat is loaded with about 210 g/ft3 . 14. The catalyst system of claim 11, wherein the at least one impregnation layer is loaded with about 22 g/ft3 Pd, about 115 g/ft3 Ba, about 105 g/ft3 Ce, and about 12 g/ft3 Nd. 15. The catalyst system of claim 10, wherein the at least one impregnation layer is loaded with about 92 g/ft3 Pd, about 105 g/ft3 Ce, and about 12 g/ft3 Nd. 16. The catalyst system of claim 15, wherein the at least one impregnation layer is loaded with about 140 g/ft3 iron. 17. The catalyst system of claim 10, wherein the at least one impregnation layer is loaded with about 22 g/ft3 Pd, about 115 g/ft3 Ba, about 105 g/ft3 Ce, and about 12 g/ft3 Nd. 18. The catalyst of claim 10, wherein the at least one impregnation layer is loaded with about 50 g/ft3 to about 230 g/ft3 of the Ba salt.
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