Catalyzed SCR filter and emission treatment system
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-050/00
B01J-029/76
B01D-005/00
B01D-019/00
B01D-053/94
B01J-037/02
F01N-003/023
F01N-003/10
F01N-003/20
F01N-013/00
F01N-003/28
B01J-035/04
B01J-035/10
출원번호
US-0054753
(2016-02-26)
등록번호
US-9517456
(2016-12-13)
발명자
/ 주소
Patchett, Joseph A.
Dettling, Joseph C.
Przybylski, Elizabeth A.
출원인 / 주소
BASF Corporation
대리인 / 주소
Womble Carlyle Sandridge & Rice, LLP
인용정보
피인용 횟수 :
1인용 특허 :
74
초록▼
Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by
Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.
대표청구항▼
1. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the system comprising: an oxidation catalyst upstream of a soot filter comprising a wall flow monolith and an SCR catalyst composition;wherein the wall flow monolith has a plurality of longitudi
1. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the system comprising: an oxidation catalyst upstream of a soot filter comprising a wall flow monolith and an SCR catalyst composition;wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end,wherein the SCR catalyst composition comprises a zeolite and a base metal component, andwherein the SCR catalyst composition permeates the walls at a concentration of at least 1.3 g/in3. 2. The emission treatment system according to claim 1, further comprising an injector in fluid communication with and downstream of the oxidation catalyst, wherein the injector is capable of periodically metering reductant to the system. 3. The emission treatment system according to claim 1, wherein the soot filter is capable of converting at least 50% of the NOx component to N2. 4. The emission treatment system according to claim 1, wherein the SCR catalyst composition permeates the walls at a concentration of 1.6 to 2.4 g/in3. 5. The emission treatment system according to claim 1, wherein the walls have a porosity of from 55 to 75% and an average pore size of from 10 to 30 microns. 6. The emission treatment system according to claim 1, wherein the wall flow monolith has from about 100 to 400 cells per square inch and a wall thickness between 0.002 and 0.015 inches. 7. The emission treatment system according to claim 1, wherein the wall flow monolith comprises silicon carbide. 8. The emission treatment system according to claim 1, wherein the base metal component comprises copper. 9. The emission treatment system according to claim 1, wherein the zeolite has a silica to alumina ratio of at least 10. 10. The emission treatment system according to claim 1, wherein the oxidation catalyst is effective to convert at least 20% of NO of the NOx component to NO2. 11. The emission treatment system according to claim 1, wherein the oxidation catalyst is effective to convert between 30 and 60% of NO of the NOx component to NO2. 12. The emission treatment system according to claim 1, wherein the oxidation catalyst comprises a platinum group metal component. 13. The emission treatment system according to claim 12, wherein the oxidation catalyst further comprises a zeolite. 14. The emission treatment system according to claim 1, wherein the SCR composition is present on the inlet sides of the walls, on the outlet sides of the walls, and also permeates the walls. 15. The emission treatment system according to claim 1, wherein the wall flow monolith comprises a washcoat of the SCR catalyst composition. 16. The emission treatment system according to claim 1, wherein the SCR catalyst composition has thermal resistance to temperatures greater than 650° C. 17. The emission treatment system according to claim 1, wherein the SCR catalyst composition is effective to catalyze conversion of the NOx component to N2 in the presence of a reductant. 18. The emission treatment system according to claim 1, wherein the pressure drop of flowing air under ambient conditions across the soot filter is not more than 25% higher than the same soot filter containing no catalyst composition. 19. The emission treatment system according to claim 1, wherein the pressure drop of flowing air under ambient conditions across the soot filter is less than 20 kPa at an air flow of 300 cfm or less. 20. The emission treatment system according to claim 1, wherein the soot filter is effective for removing greater than 80% of the particulate matter in the exhaust stream. 21. A catalyst article in the form of a soot filter comprising a wall flow monolith and an SCR catalyst composition, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, wherein the wall flow monolith comprises an SCR catalyst composition that permeates the walls at a concentration of at least 1.3 g/in3, wherein the SCR catalyst composition comprises a zeolite and a base metal component. 22. The catalyst article according to claim 21, wherein the SCR catalyst composition permeates the walls at a concentration of 1.6 to 2.4 g/in3. 23. The catalyst article according to claim 21, wherein the walls have a porosity of from 55 to 75% and an average pore size of from 10 to 30 microns. 24. The catalyst article according to claim 21, wherein the wall flow monolith has from about 100 to 400 cells per square inch and a wall thickness between 0.002 and 0.015 inches. 25. The catalyst article according to claim 21, wherein the wall flow monolith comprises silicon carbide. 26. The catalyst article according to claim 21, wherein the base metal component comprises copper. 27. The catalyst article according to claim 21, wherein the zeolite has a silica to alumina ratio of at least 10. 28. The catalyst article according to claim 21, wherein the SCR catalyst composition is present on the inlet sides of the walls, on the outlet sides of the walls, and also permeates the walls. 29. The catalyst article according to claim 21, wherein the wall flow monolith comprises a washcoat of the SCR catalyst composition. 30. The catalyst article according to claim 21, wherein the pressure drop of flowing air under ambient conditions across the soot filter is not more than 25% higher than the same soot filter containing no catalyst composition. 31. The catalyst article according to claim 21, wherein the pressure drop of flowing air under ambient conditions across the soot filter is less than 20 kPa at an air flow of 300 cfm or less. 32. The catalyst article according to claim 21, wherein the soot filter is effective for removing greater than 80% of particulate matter in an exhaust stream. 33. The catalyst article according to claim 21, where the SCR catalyst composition has thermal resistance to temperatures greater than 650° C. 34. The catalyst article according to claim 21, wherein the SCR catalyst composition permeates the walls at a concentration of 1.6 to 2.4 g/in3, which walls have a porosity of from 55 to 75% and an average pore size of from 10 to 30 microns, wherein the wall flow monolith comprises silicon carbide and has from about 100 to 400 cells per square inch and a wall thickness between 0.002 and 0.015 inches, and wherein the SCR catalyst composition comprises a zeolite having a silica to alumina ratio of at least 10 and copper. 35. The catalyst article according to claim 21, wherein the soot filter is capable of converting at least 50% of a NOx component in an exhaust stream to N2.
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