Systems and methods for preventing chromium contamination of solid oxide fuel cells
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
H01M-008/02
H01M-008/10
H01M-008/12
H01M-008/06
H01M-004/86
H01M-004/88
H01M-008/04
B01D-053/02
B01J-020/32
H01M-004/90
출원번호
US-0220867
(2014-03-20)
등록번호
US-9559366
(2017-01-31)
발명자
/ 주소
He, Hongpeng
Wood, Anthony
출원인 / 주소
VERSA POWER SYSTEMS LTD.
대리인 / 주소
Foley & Lardner, LLP
인용정보
피인용 횟수 :
0인용 특허 :
8
초록▼
In some embodiments, a solid oxide fuel system is provided. The solid oxide fuel cell system may include a chromium-getter material. The chromium-getter material may react with chromium to remove chromium species from chromium vapor. The solid oxide fuel cell system may also include an inert substra
In some embodiments, a solid oxide fuel system is provided. The solid oxide fuel cell system may include a chromium-getter material. The chromium-getter material may react with chromium to remove chromium species from chromium vapor. The solid oxide fuel cell system may also include an inert substrate. The chromium-getter material may be coated onto the inert substrate. The coated substrate may remove chromium species from chromium vapor before the chromium species can react with a cathode in the solid oxide fuel cell system.
대표청구항▼
1. A solid oxide fuel cell system comprising: a chromium-getter material, wherein the chromium-getter material comprises a material that reacts with chromium to remove chromium species from chromium vapor; andan inert substrate comprising alumina,wherein the chromium-getter material is covalently bo
1. A solid oxide fuel cell system comprising: a chromium-getter material, wherein the chromium-getter material comprises a material that reacts with chromium to remove chromium species from chromium vapor; andan inert substrate comprising alumina,wherein the chromium-getter material is covalently bonded to the inert substrate to form a coated substrate that removes chromium species from chromium vapor in the solid oxide fuel cell system before the chromium species can react with a cathode in the solid oxide fuel cell system. 2. The solid oxide fuel cell system of claim 1, wherein: the chromium-getter material comprises a compound selected from the group consisting of: lanthanum oxide,lanthanum carbonate, andcalcium carbonate. 3. The solid oxide fuel cell system of claim 1, wherein: the chromium-getter material comprises an inorganic carbonate, nitrate, hydroxide, or acetate that reacts with chromium vapor in a range of 300 to 850° C. 4. The solid oxide fuel cell system of claim 3, wherein: the chromium-getter material further comprises lanthanum, barium, calcium, lithium, or sodium. 5. The solid oxide fuel cell system of claim 1, wherein: the coated substrate is disposed in a solid oxide fuel cell stack of the solid oxide fuel cell system. 6. The solid oxide fuel cell system of claim 1, wherein: the chromium-getter material comprises a compound selected from the group consisting of: barium oxide,lithium oxide, andsodium oxide. 7. The solid oxide fuel cell system of claim 1, wherein: the coated substrate is disposed in a stack manifold or a stack hot box of the solid oxide fuel cell system. 8. The solid oxide fuel cell system of claim 1, wherein: the coated substrate is disposed in a hot system piping of the solid oxide fuel cell system. 9. The solid oxide fuel cell system of claim 1, wherein: the coated substrate is disposed in an air flow stream of a solid oxide fuel cell interconnect of the solid oxide fuel cell system. 10. The solid oxide fuel cell system of claim 1, wherein: the coated substrate is disposed in an area of the solid oxide fuel cell system,wherein the area reaches a temperature above about 300° C. 11. The solid oxide fuel cell system of claim 1, wherein: the chromium-getter material comprises pellets. 12. The solid oxide fuel cell system of claim 1, wherein the inert substrate consists essentially of alumina. 13. The solid oxide fuel cell system of claim 1, wherein the inert substrate consists of alumina. 14. A solid oxide fuel cell system comprising: a chromium-getter material, wherein the chromium-getter material comprises a material that reacts with chromium to remove chromium species from chromium vapor; andan inert substrate comprising alumina;wherein the chromium-getter material is ionically bonded to the inert substrate to form a coated substrate that removes chromium species from chromium vapor in the solid oxide fuel cell system before the chromium species can react with a cathode in the solid oxide fuel cell system. 15. The solid oxide fuel cell system of claim 14, wherein: the chromium-getter material comprises a compound selected from the group consisting of: lanthanum oxide,lanthanum carbonate, andcalcium carbonate. 16. The solid oxide fuel cell system of claim 14, wherein: the chromium-getter material comprises an inorganic carbonate, nitrate, hydroxide, or acetate that reacts with chromium vapor in a range of 300 to 850° C. 17. The solid oxide fuel cell system of claim 16, wherein: the chromium-getter material further comprises lanthanum, barium, calcium, lithium, or sodium. 18. The solid oxide fuel cell system of claim 14, wherein: the coated substrate is disposed in a solid oxide fuel cell stack of the solid oxide fuel cell system. 19. The solid oxide fuel cell system of claim 14, wherein: the chromium-getter material comprises a compound selected from the group consisting of: barium oxide,lithium oxide, andsodium oxide. 20. The solid oxide fuel cell system of claim 14, wherein: the coated substrate is disposed in a stack manifold or a stack hot box of the solid oxide fuel cell system. 21. The solid oxide fuel cell system of claim 14, wherein: the coated substrate is disposed in a hot system piping of the solid oxide fuel cell system. 22. The solid oxide fuel cell system of claim 14, wherein: the coated substrate is disposed in an air flow stream of a solid oxide fuel cell interconnect of the solid oxide fuel cell system. 23. The solid oxide fuel cell system of claim 14, wherein: the coated substrate is disposed in an area of the solid oxide fuel cell system,wherein the area reaches a temperature above about 300° C. 24. The solid oxide fuel cell system of claim 14, wherein: the chromium-getter material comprises pellets. 25. The solid oxide fuel cell system of claim 14, wherein the inert substrate consists essentially of alumina. 26. The solid oxide fuel cell system of claim 14, wherein the inert substrate consists of alumina.
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