|국가/구분||United States(US) Patent 등록|
|국제특허분류(IPC7판)||C07F-005/02 C07C-211/63 C01B-035/02|
|발명자 / 주소|
|출원인 / 주소|
|대리인 / 주소||
|인용정보||피인용 횟수 : 0 인용 특허 : 9|
The present invention provides methods and devices for producing polyhedral boron compounds. The process is generally an anhydrous, one-pot process that comprises a pyrolytic reaction of a tetraborohydride with a quaternary amine salt to form the polyhedral borane. In another aspect of the present invention, polyhedral boranes are produced, without isolation of the Lewis base-borane complex.
1. A process for the production of a polyhedral borane in an amount greater than one kilogram, wherein the process comprises a solid-phase, anhydrous, one-pot reaction of a tetraborohydride and a quaternary amine salt under anhydrous pyrolytic reaction conditions without solvent, resulting in the formation of the polyhedral borane. 2. The process of claim 1, wherein the tetraborohydride is chosen from sodium borohydride, potassium borohydride, and lithium borohydride. 3. The process of claim 1, wherein the quaternary amine salt of Formula (I), wherein L1...