[미국특허]
Systems and methods for converting carbonaceous fuels
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-008/26
B01J-008/08
B01J-008/12
C10J-003/72
B01J-008/18
B01J-008/00
출원번호
US-0774730
(2014-03-14)
등록번호
US-9616403
(2017-04-11)
국제출원번호
PCT/US2014/028217
(2014-03-14)
국제공개번호
WO2014/152914
(2014-09-25)
발명자
/ 주소
Fan, Liang-Shih
Wang, Dawei
출원인 / 주소
Ohio State Innovation Foundation
대리인 / 주소
Michael Best & Friedrich LLP
인용정보
피인용 횟수 :
6인용 특허 :
67
초록▼
A system for converting carbonaceous fuels is provided. The system includes a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor. The fuel pretreatm
A system for converting carbonaceous fuels is provided. The system includes a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor. The fuel pretreatment fluidized bed reactor devolatilizes a solid fuel using heat to produce an off-gas and a devolatilized solid fuel. The gaseous fuel conversion reactor converts the off-gas from the fuel pretreatment fluidized bed reactor to a product gas stream comprising carbon dioxide and water. The solid fuel conversion reactor receives a mixture of oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge and reduces the devolatilized solid fuel with the oxygen carrier solids to convert the devolatilized solid fuel to an intermediate gas.
대표청구항▼
1. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor; the gaseous fuel conversion reactor c
1. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor; the gaseous fuel conversion reactor comprising: a gaseous fuel reactor oxygen carrier solid inlet,a gaseous fuel reactor off-gas inlet configured to receive off-gas from the fuel pretreatment fluidized bed reactor, anda gaseous fuel reactor oxygen carrier solid outlet,wherein the gaseous fuel conversion reactor is configured to convert the off-gas and oxygen carrier solids to a product gas stream comprising carbon dioxide and water, thereby reducing at least a portion of the oxygen carrier solids to reduced oxygen carrier solids;the fuel pretreatment fluidized bed reactor comprising: a pretreatment reactor solid fuel inlet disposed in a fuel introduction section of the fuel pretreatment reactor,a pretreatment reactor oxygen carrier inlet configured to receive a mixture of oxygen carrier solids and reduced oxygen carrier solids from the gaseous fuel reactor oxygen carrier solid outlet,a pretreatment reactor intermediate gas inlet configured to receive intermediate gas from the solid fuel conversion reactor, the intermediate gas being used for fluidization, anda pretreatment reactor discharge in communication with the gaseous fuel conversion reactor off-gas inlet,wherein the fuel pretreatment fluidized bed reactor is configured to volatilize solid fuel using heat from the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce a devolatilized solid fuel and off-gas, and subsequently discharge the off-gas, the devolatilized solid fuel, and the mixture of oxygen carrier solids and reduced oxygen carrier solids via the pretreatment reactor discharge;the solid fuel conversion reactor comprising: a solid fuel conversion reactor inlet configured to receive the mixture of oxygen carrier solids and reduced oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge anda solid fuel conversion reactor intermediate gas outlet in communication with the pretreatment reactor intermediate gas inlet, anda solid fuel conversion reactor oxygen carrier solid outlet,wherein the solid fuel conversion reactor is configured to react the devolatilized solid fuel with the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce the intermediate gas comprising carbon dioxide and water, thereby further reducing oxygen carrier solids to reduced oxygen carrier solids. 2. The system of claim 1, further comprising an oxidation reactor configured to react the reduced oxygen carrier solids from the solid fuel conversion reactor oxygen carrier solid outlet with an oxidation gas stream to convert the reduced oxygen carrier solid back to the oxygen carrier solid, the oxidation reactor comprising a reduced oxygen carrier solid inlet configured to receive the reduced oxygen carrier solid, andan oxidation reactor discharge configured to discharge the oxygen carrier solid and an oxygen depleted oxidation gas stream. 3. The system of claim 1, further comprising a pretreatment gas-solids separation unit in communication with the pretreatment reactor discharge and configured to separate the off-gas from the devolatilized solid fuel and the oxygen carrier solid exiting the fuel pretreatment fluidized bed reactor. 4. The system of claim 1, wherein the gaseous fuel conversion reactor is divided into two or more staged reactors in series. 5. The system of claim 1, wherein the solid fuel conversion reactor is divided into two or more staged reactors in series. 6. The system of claim 1, wherein the gas velocity of the off-gas through the gaseous fuel conversion reactor is less than the minimum fluidization velocity of the oxygen carrier solid. 7. The system of claim 1, further comprising a conversion enhancement gas inlet configured to introduce a conversion enhancement gas into the solid fuel conversion reactor to enhance conversion of the devolatilized solid fuel. 8. The system of claim 7, wherein the conversion enhancement gas is the product gas stream from the gaseous fuel conversion reactor. 9. The system of claim 7, wherein the gas velocity of the conversion enhancement gas through the solid fuel conversion reactor is less than the minimum fluidization velocity of the oxygen carrier solid. 10. The system of claim 2, further comprising an oxidizer gas-solids separation unit in communication with the oxidation reactor discharge and configured to separate the oxygen depleted oxidation gas stream from the oxygen carrier solid exiting the oxidation reactor. 11. The system of claim 2, further comprising a non-mechanical seal separating the solid fuel conversion reactor and the oxidation reactor, the non-mechanical seal configured to prevent gases generated in the solid fuel conversion reactor and the oxidation gas stream in the oxidation reactor from transferring between the solid fuel conversion reactor and the oxidation reactor while allowing the reduced oxygen carrier solid to pass through. 12. The system of claim 10, further comprising a non-mechanical seal separating the gaseous fuel conversion reactor and oxidizer gas-solids separation unit, the non-mechanical seal configured to prevent the product gas stream of the gaseous fuel conversion reactor and the oxygen depleted oxidation gas stream in the oxidizer gas-solids separation unit from transferring between the gaseous fuel conversion reactor and the oxidizer gas-solids separation unit or oxygen carrier solid storage vessel while allowing the oxygen carrier solid to pass through. 13. The system of claim 1, wherein the fuel pretreatment reactor further comprises a substantially cone shaped bottom in communication with a gas-solids jet configured to provide a uniform distribution of the intermediate gas and the oxygen carrier solid into the fuel pretreatment fluidized bed reactor; wherein the gas-solids jet comprises the pretreatment reactor intermediate gas inlet and the pretreatment reactor oxygen carrier inlet. 14. The system of claim 1, wherein the fuel pretreatment reactor further comprises a supply chamber and a mixing chamber with a crossflow slit disposed between the supply chamber and the mixing chamber configured to allow passage of the oxygen carrier solid through the crossflow slit; wherein an aeration inlet provides an aeration gas from the bottom or from the side of the supply chamber to propel the oxygen carrier solid through the crossflow slit into the mixing chamber. 15. The system of claim 1, wherein the fuel pretreatment reactor further comprises a gas introduction zone and a solids mixing zone separated by a meshed gas distributor configured to distribute the intermediate gas uniformly across the fuel pretreatment fluidized bed reactor. 16. The system of claim 15, further comprising an ash separator disposed between the solid fuel conversion intermediate gas outlet and the pretreatment reactor intermediate gas inlet and is configured to separate ash and/or unconverted carbon from the intermediate gas before the intermediate gas is provided to the fuel pretreatment fluidized bed reactor. 17. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor, an oxidation reactor disposed downstream of the solid fuel conversion reactor, and a pretreatment gas-solids separation unit; the gaseous fuel conversion reactor comprising: a gaseous fuel reactor oxygen carrier solid inlet,a gaseous fuel reactor off-gas inlet configured to receive off-gas from the fuel pretreatment fluidized bed reactor, anda gaseous fuel reactor oxygen carrier solid outlet,wherein the gaseous fuel conversion reactor is configured to convert the off-gas and oxygen carrier solids to a product gas stream comprising carbon dioxide and water, thereby reducing at least a portion of the oxygen carrier solids to reduced oxygen carrier solids;the fuel pretreatment fluidized bed reactor comprising a pretreatment reactor solid fuel inlet disposed in a fuel introduction section of the fuel pretreatment reactor,a pretreatment reactor oxygen carrier inlet configured to receive a mixture of oxygen carrier solids and reduced oxygen carrier solids from the gaseous fuel reactor oxygen carrier solid outlet,a pretreatment reactor intermediate gas inlet configured to receive intermediate gas from the solid fuel conversion reactor, the intermediate gas being used for fluidization, anda pretreatment reactor discharge in communication with the gaseous fuel conversion reactor off-gas inlet,wherein the fuel pretreatment fluidized bed reactor is configured to volatilize solid fuel using heat from the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce a devolatilized solid fuel and off-gas, and subsequently discharge the off-gas, the devolatilized solid fuel, and the mixture of oxygen carrier solids and reduced oxygen carrier solids via the pretreatment reactor discharge;the solid fuel conversion reactor comprising: a solid fuel conversion reactor inlet configured to receive the mixture of oxygen carrier solids and reduced oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge,a solid fuel conversion reactor intermediate gas outlet in communication with the pretreatment reactor intermediate gas inlet, anda solid fuel conversion reactor oxygen carrier solid outlet,wherein the solid fuel conversion reactor is configured to react the devolatilized solid fuel with the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce the intermediate gas comprising carbon dioxide and water, thereby further reducing oxygen carrier solids to reduced oxygen carrier solids;the oxidation reactor comprising: a reduced oxygen carrier solid inlet configured to receive the reduced oxygen carrier solid andan oxidation reactor discharge configured to discharge the oxygen carrier solid and an oxygen depleted oxidation gas stream,wherein the oxidation reactor is configured to react the reduced oxygen carrier solids from the solid fuel conversion reactor oxygen carrier solid outlet with an oxidation gas stream to convert the reduced oxygen carrier solid back to the oxygen carrier solid; andwherein the pretreatment gas-solids separation unit is in communication with the pretreatment reactor discharge and configured to separate the off-gas from the devolatilized solid fuel and the oxygen carrier solid exiting the fuel pretreatment reactor. 18. The system of claim 17, further comprising an oxidizer gas-solids separation unit in communication with the oxidation reactor discharge and configured to separate the oxygen depleted oxidation gas stream from the oxygen carrier solid exiting the oxidation reactor. 19. The system of claim 17, wherein the fuel pretreatment reactor further comprises a supply chamber and a mixing chamber with a crossflow slit disposed between the supply chamber and the mixing chamber configured to allow passage of the oxygen carrier solid through the crossflow slit; wherein an aeration inlet provides an aeration gas from the bottom or from the side of the supply chamber to propel the oxygen carrier solid through the crossflow slit into the mixing chamber. 20. The system of claim 17, wherein the fuel pretreatment reactor further comprises a gas introduction zone and a solids mixing zone separated by a meshed gas distributor configured to distribute the intermediate gas uniformly across the fuel pretreatment fluidized bed reactor.
Ouwerkerk Johannes H. W. (Driehuis NLX) Lucieer Wouter B. (Schagen NLX) Cramer Rudolph E. (Oudkarspel NLX), Arrangement for mixing a gas into a main flow of a second gas.
Funk Erwin D. (Glens Falls NY) Sherman Michael I. (Glens Falls NY), Coal gasification process with improved procedures for continuously feeding lump coal under pressure.
Davis George D. (Creve Coeur MO) Hill James C. (Seabrook TX) McMinn Talmage D. (Des Peres MO) Rooks Charles W. (St. Louis MO), Conversion of carbon-containing materials to synthesis gas.
Iyer, Mahesh V.; Fan, Liang-Shih; Ramkumar, Shwetha, High purity, high pressure hydrogen production with in-situ COand sulfur capture in a single stage reactor.
Vinegar, Harold J.; Wellington, Scott Lee; Berchenko, Ilya Emil; Van Hardeveld, Robert Martijn, In situ production of synthesis gas from a coal formation, the synthesis gas having a selected H2 to CO ratio.
Hoteit, Ali; Guillou, Florent; Lambert, Arnold; Roesler, John, Integrated energy and/or synthesis gas production method by in-situ oxygen production, chemical looping combustion and gasification.
Grochowski, Horst, Method and device for purifying the flue gases of a sintering process of ores and/or other material-containing materials in metal production.
Bruno Joseph A. (Blue Bell PA) Doty Brian D. (Phoenixville PA) Gustow Evan (Ardmore PA) Illig Kathleen J. (Phoenixville PA) Rajagopalan Nats (Phoenixville PA) Sarpotdar Pramod (Malvern PA), Method of grinding pharmaceutical substances.
Shapiro, Edward G.; Seppi, Edward J.; Pavkovich, John M.; Munro, Peter; Johnsen, Stanley W.; Colbeth, Richard E., Multi-mode cone beam CT radiotherapy simulator and treatment machine with a flat panel imager.
Kainer Hartmut (Wiesbaden DEX) Bhler Eugen (Knigstein DEX) Grimm Daniel (Bad Schwalbach DEX) Schenelle Wilfried (Wiesbaden DEX) Flockenhaus Claus (Essen DEX) Laue Karl-Heinrich (Hattingen DEX) Merkel, Process for the manufacture of catalytic elements and catalytic elements so produced.
David Charles Griffiths GB; Barry Martin Maunders GB; William Terence Woodfin GB, Process for the preparation of mono-olefins from paraffinic hydrocarbons.
Sanfilippo,Domenico; Mizia,Franco; Malandrino,Alberto; Rossini,Stefano, Process for the production of hydrogen and the co-production of carbon dioxide.
Mori Kenji (Kobe JPX) Narita Kiichi (Kobe JPX) Ijiri Ryuzo (Kobe JPX) Morimitsu Tsuneo (Kobe JPX) Kaneko Dentaro (Kobe JPX) Uemura Nobuo (Nishinomiya JPX) Kameoka Yoshifumi (Kobe JPX) Taniuchi Mamoru, Process for the production of reduced iron and thermal cracking of heavy oils.
Goldstein Stuart S. (Kinnelon NJ) Calvin William J. (Convent Station NJ) Marshall Harry A. (Madison NJ), Production of methanol via catalytic coal gasification.
Fan, Liang-Shih; Li, Fanxing; Wang, Fei; Tong, Andrew S.; Karri, Surya B. R.; Findlay, John G.; Knowlton, Ted M.; Cocco, Raymond A., Circulating fluidized bed with moving bed downcomers and gas sealing between reactors.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.