Integrated gaseous fuel CPOX reformer and fuel cell systems, and methods of producing electricity
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-007/00
C01B-003/36
H01M-008/0612
B01J-012/00
B01J-019/24
B01J-004/00
C01B-003/38
C01B-003/32
C01B-003/48
H01M-008/243
H01M-008/04082(2016.01)
H01M-008/04223(2016.01)
H01M-008/04746(2016.01)
H01M-008/124
출원번호
US-0534409
(2014-11-06)
등록번호
US-9627701
(2017-04-18)
발명자
/ 주소
Finnerty, Caine M.
DeWald, Paul
출원인 / 주소
Watt Fuel Cell Corp.
대리인 / 주소
Dilworth & Barrese, LLP.
인용정보
피인용 횟수 :
0인용 특허 :
119
초록▼
Integrated gaseous fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open g
Integrated gaseous fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The gaseous fuel CPOX reformer also can include one or more igniters, and a source of gaseous reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the gaseous fuel CPOX reformer.
대표청구항▼
1. An integrated gaseous fuel CPOX reformer and fuel cell system, the integrated system comprising: an array of spaced-apart CPOX reactor units, each CPOX reactor unit comprising an elongate tube having a gas-permeable wall with an internal surface and an external surface, the gas-permeable wall enc
1. An integrated gaseous fuel CPOX reformer and fuel cell system, the integrated system comprising: an array of spaced-apart CPOX reactor units, each CPOX reactor unit comprising an elongate tube having a gas-permeable wall with an internal surface and an external surface, the gas-permeable wall enclosing an open gaseous flow passageway and defining an inlet and an outlet of the CPOX reactor unit, the open gaseous flow passageway being a hollow bore extending from the inlet to an outlet of the CPOX reactor unit,wherein a CPOX reactor unit is in thermal communication with at least the adjacent CPOX reactor unit(s) in the array, anda CPOX catalyst disposed within and/or comprising the structure of at least a section of the gas-permeable wall;an igniter in thermal communication with the CPOX catalyst of at least one CPOX reactor unit;a fuel cell unit comprising an anode, a cathode, and an electrolyte disposed therebetween, wherein the anode is in fluid communication with the outlet of the CPOX reactor unit and the cathode is in fluid communication with an oxygen-containing gas; anda current collector electrically coupled to the anode and the cathode of the fuel cell unit. 2. The integrated system of claim 1, wherein a hydrogen barrier is associated with the external surface of at least the CPOX catalyst-containing wall section of a CPOX reactor unit. 3. The integrated system of claim 2, wherein the hydrogen barrier comprises pressurized air. 4. The liquid CPOX reformer of claim 2 wherein the hydrogen barrier is attached or adhered to an outer layer or external surface of the gas-permeable wall for at least that portion of the length of a CPOX reactor unit corresponding to its CPOX reaction zone. 5. The liquid fuel CPOX reformer of claim 4 wherein the material of the hydrogen barrier is selected from the group consisting of aluminum, nickel, molybdenum, tin, chromium, alumina, recrystallized alumina, aluminides, alumino-silicates, titania, titanium carbide, titanium nitride, boron nitride, magnesium oxide, chromium oxide, zirconium phosphate, ceria, zirconia, mulite, admixtures thereof and layered combinations thereof. 6. The integrated system of claim 1, wherein the maximum distance between adjacent CPOX reactor units is that distance beyond which the heat from an operating CPOX reactor unit operating at a predetermined minimum temperature fails to initiate a CPOX reaction in an adjacent CPOX reactor unit and/or during a steady-state mode of operation, the temperature of the array of spaced-apart CPOX reactor units falls below a predetermined minimum array temperature; and the minimum distance between adjacent CPOX reactor units is that distance below which the temperature at an outlet of a CPOX reactor unit is greater than a predetermined maximum temperature. 7. The integrated system of claim 6, wherein the predetermined maximum temperature is a temperature that is tolerable by an inlet of a fuel cell stack in thermal and fluid communication with an outlet of a CPOX reactor unit. 8. The integrated system of claim 6, wherein the predetermined maximum temperature is about 900° C. 9. The integrated system of claim 6, wherein the predetermined minimum array temperature is about 600° C. 10. The integrated system of claim 1, comprising a source of gaseous reformable fuel in fluid communication with an inlet of at least one CPOX reactor unit. 11. The integrated system of claim 1, comprising more than one igniter, wherein each igniter is positioned in thermal communication with a CPOX catalyst of at least one CPOX reactor unit. 12. The integrated system of claim 1, wherein the fuel cell unit is a solid oxide fuel cell or a polymer electrolyte membrane fuel cell. 13. The integrated system of claim 1, wherein the fuel cell unit is a tubular solid oxide fuel cell. 14. The integrated system of claim 1, wherein the fuel cell unit is a multi-tubular solid oxide fuel cell. 15. The integrated system of claim 1, wherein the anode of a fuel cell unit is in fluid communication with the outlet of a CPOX reactor unit via a conduit and the cathode of a fuel cell unit is in fluid communication with the oxygen-containing gas via another conduit. 16. The integrated system of claim 1, wherein the outlet of a CPOX reactor unit is connected directly to an inlet of the fuel cell unit, wherein the inlet of the fuel cell unit is in fluid communication with the anode of the fuel cell unit. 17. The integrated system of claim 1, comprising an afterburner in fluid communication with an outlet of the fuel cell unit. 18. A method of CPOX reforming a gaseous reformable fuel to a hydrogen-rich reformate and converting electrochemically a hydrogen-rich reformate into electricity, the method comprising: introducing a gaseous CPOX reaction mixture comprising a gaseous reformable fuel into inlets of CPOX reactor units, wherein the CPOX reactor units form an array of spaced-apart CPOX reactor units, each CPOX reactor unit comprising an elongate tube having a wall with an internal surface and an external surface, the wall enclosing an open gaseous flow passageway and defining an inlet and an outlet of the CPOX reactor unit, the open gaseous flow passageway being a hollow bore extending from the inlet to the outlet of the CPOX reactor unit,wherein a CPOX reactor unit is in thermal communication with at least the adjacent CPOX reactor unit(s) in the array,a CPOX catalyst disposed within and/or comprising the structure of at least a section of the wall, andthe CPOX catalyst-containing wall section is gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and product hydrogen-rich reformate to diffuse therefrom;initiating catalytic partial oxidation of the gaseous CPOX reaction mixture by an igniter in thermal communication with the CPOX catalyst to begin production of a hydrogen-rich reformate in at least one CPOX reactor unit;maintaining catalytic partial oxidation of the gaseous CPOX reaction mixture in the at least one CPOX reactor unit of the array to produce a hydrogen-rich reformate; andconverting within a fuel cell unit, the fuel cell unit comprising an anode, a cathode, and an electrolyte disposed therebetween, wherein the anode is in fluid communication with the outlet of the CPOX reactor unit and the cathode is in fluid communication with an oxygen-containing gas, the hydrogen-rich reformate to electricity collected by a current collector. 19. The method of claim 18, wherein a hydrogen barrier is associated with the external surface of at least the CPOX catalyst-containing wall section of a CPOX reactor unit. 20. The method of claim 18, wherein the maximum distance between adjacent CPOX reactor units is that distance beyond which the heat from an operating CPOX reactor unit operating at a predetermined minimum temperature fails to initiate a CPOX reaction in an adjacent CPOX reactor unit and/or during a steady-state mode of operation, the temperature of a CPOX reactor unit falls below a predetermined minimum array temperature; and the minimum distance between adjacent CPOX reactor units is that distance below which the temperature at an outlet of a CPOX reactor unit is greater than a predetermined maximum temperature. 21. The method of claim 18, wherein initiating catalytic partial oxidation comprises: initiating a CPOX reaction in one CPOX reactor unit;transferring the heat from the CPOX reaction to an adjacent CPOX reactor unit to initiate a CPOX reaction therein; andrepeating transferring the heat to initiate a CPOX reaction in each of the CPOX reactors of the array. 22. The method of claim 18, wherein initiating catalytic partial oxidation comprises initiating more than a single igniter to initiate catalytic partial oxidation of the gaseous CPOX reaction mixture in each of the CPOX reactor units. 23. The method of claim 18, wherein maintaining catalytic partial oxidation of the gaseous CPOX reaction mixture comprises transferring heat among the CPOX reactor units to maintain a predetermined minimum array temperature. 24. The method of claim 23, wherein the predetermined minimum array temperature is substantially uniform across the array of CPOX reactor units. 25. The method of claim 18, wherein converting within a fuel cell unit the hydrogen-rich reformate to electricity comprises: contacting the hydrogen-rich reformate with an anode of the fuel cell unit; andcontacting an oxygen-containing gas with a cathode of the fuel cell unit. 26. A method of CPOX reforming of gaseous reformable fuel to produce hydrogen-rich reformate and electrochemically converting the reformate within a fuel cell to produce electricity, the method comprising: a) in a start-up mode:(i) introducing gaseous CPOX reaction mixture comprising oxygen-containing gas and gaseous reformable fuel into the inlet of each of a plurality of spaced-apart CPOX reactor units, each reactor unit comprising an elongate tube having an inlet for gaseous CPOX reaction mixture, an outlet for hydrogen-rich reformate, a wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway, the open gaseous flow passageway being a hollow bore extending from the inlet to an outlet of the CPOX reactor unit, with at least a section of the wall having CPOX catalyst disposed therein and/or comprising its structure, such catalyst-containing wall section and open gaseous flow passageway enclosed thereby defining a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and product hydrogen-rich reformate to diffuse therefrom while remaining stable under CPOX reaction conditions,(ii) initiating CPOX of the gaseous CPOX reaction mixture by an igniter in thermal communication with the CPOX catalyst within the CPOX reaction zones of the CPOX reactor units thereby commencing production of gaseous hydrogen-rich reformate, and(iii) conveying hydrogen-rich reformate produced in step (ii) to a fuel cell comprising at least one fuel cell unit, the fuel cell unit comprising an anode component, a cathode component, and an electrolyte disposed therebetween, such that reformate contacts the anode component of the fuel cell unit while at the same time conveying oxygen-containing gas to the fuel cell such that the gas contacts the cathode component of the fuel cell unit, the reformate undergoing conversion within the fuel cell unit to produce electricity collected by a current collector; and,b) in a steady-state mode:(iv) introducing gaseous CPOX reaction mixture into the inlets of the CPOX reactor units,(v) discontinuing CPOX initiating step (ii) prior to, during or following step (iv) while maintaining the CPOX reaction within the CPOX reaction zones of the CPOX reactor units thereby continuing the production of hydrogen-rich reformate, and(vi) conveying hydrogen-rich reformate produced in step (v) to the anode component of the at least one fuel cell unit and at the same time conveying oxygen-containing gas to the cathode component of the at least one fuel cell unit, the reformate continuing to undergo conversion within the fuel cell unit to produce electricity collected by the current collector. 27. A method of CPOX reforming of gaseous reformable fuel to produce hydrogen-rich reformate and electrochemically converting the reformate within a fuel cell to electricity, the method comprising: a) in a start-up mode:(i) introducing oxygen-containing gas into a conduit for routing gas toward the inlet of each of a plurality of CPOX reactor units, the conduit comprising an inlet for oxygen-containing gas, an inlet for gaseous reformable fuel and an outlet for heated gaseous CPOX reaction mixture in gaseous flow communication with the inlets of the CPOX reactor units, each CPOX reactor unit comprising an elongate tube having an inlet for gaseous CPOX reaction mixture, an outlet for hydrogen-rich reformate, a wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway, the open gaseous flow passageway being a hollow bore extending from the inlet to an outlet of the CPOX reactor unit, with at least a section of the wall having CPOX catalyst disposed therein and/or comprising its structure, such catalyst-containing wall section and open gaseous flow passageway enclosed thereby defining a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and product hydrogen-rich reformate to diffuse therefrom while remaining structurally stable under CPOX reaction conditions,(ii) introducing gaseous reformable fuel into the conduit, oxygen-containing gas and gaseous reformable fuel combining to form gaseous CPOX reaction mixture,(iii) introducing gaseous CPOX reaction mixture from step (ii) into the inlets of the CPOX reactor units, and(iv) initiating CPOX of the gaseous CPOX reaction mixture by an igniter in thermal communication with the CPOX catalyst within the CPOX reaction zones of the CPOX reactor units thereby commencing the production of hydrogen-rich reformate, and(v) conveying hydrogen-rich reformate produced in step (iv) to a fuel cell comprising at least one fuel cell unit, the fuel cell unit comprising an anode component, a cathode component, and an electrolyte disposed therebetween, such that reformate contacts the anode component of the fuel cell unit while at the same time conveying oxygen-containing gas to the fuel cell such that the gas contacts the cathode component of the fuel cell unit, the reformate undergoing conversion within the fuel cell unit to produce electricity collected by a current collector; and,b) in a steady-state mode:(vi) introducing oxygen-containing gas into the conduit,(vii) introducing gaseous reformable fuel into the conduit, oxygen-containing gas and gaseous reformable fuel combining to form gaseous CPOX reaction mixture,(viii) introducing gaseous CPOX reaction mixture from step (vii) into the inlets of the CPOX reactor units,(ix) discontinuing initiating step (iv) prior to, during or following step (xi) while maintaining the CPOX reaction within the CPOX reaction zones of the CPOX reactor units thereby continuing the production of hydrogen-rich reformate, and(x) conveying hydrogen-rich reformate produced in step (ix) to the anode component of the at least one fuel cell unit and at the same time conveying oxygen-containing gas to the cathode component of the at least one fuel cell unit, the reformate continuing to undergo conversion within the fuel cell unit to produce electricity collected by the current collector.
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