Method for disposing SCR composition on a wall flow monolith
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-037/02
B01J-029/76
B01D-005/00
B01D-019/00
B01D-053/94
F01N-003/023
F01N-003/10
F01N-003/20
F01N-013/00
F01N-003/28
B01J-035/04
B01J-035/10
B01J-037/08
출원번호
US-0355130
(2016-11-18)
등록번호
US-9757717
(2017-09-12)
발명자
/ 주소
Patchett, Joseph A.
Dettling, Joseph C.
Przybylski, Elizabeth A.
출원인 / 주소
BASF Corporation
대리인 / 주소
Womble Carlyle Sandridge & Rice, LLP
인용정보
피인용 횟수 :
0인용 특허 :
76
초록▼
Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by
Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.
대표청구항▼
1. A method for disposing a selective catalytic reduction (SCR) catalyst composition on a wall flow monolith, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages compris
1. A method for disposing a selective catalytic reduction (SCR) catalyst composition on a wall flow monolith, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the method comprising: receiving an aqueous slurry comprising the SCR catalyst composition, the SCR catalyst composition comprising a zeolite and a base metal component;immersing the wall flow monolith in the aqueous slurry from a first direction to deposit the SCR catalyst composition on the inlet passages;removing excess aqueous slurry from the inlet passages;immersing the wall flow monolith in the aqueous slurry from a second direction, opposite the first direction, to deposit the SCR catalyst composition on the outlet passages and form a coated wall flow monolith;removing excess aqueous slurry from the outlet passages; anddrying and calcining the coated wall flow monolith to form an integrated soot filter and SCR catalyst, wherein the SCR catalyst composition is present on the coated wall flow monolith at a concentration of at least 1.3 g/in3. 2. The method of claim 1, wherein the SCR catalyst composition permeates the walls. 3. The method of claim 1, wherein the SCR catalyst composition is present on the coated wall flow monolith at a concentration of 1.6 to 2.4 g/in3. 4. The method of claim 1, wherein the calcining step comprises calcining at a temperature in the range from about 300° C. to about 450° C. 5. The method of claim 1, wherein each of the steps of removing excess aqueous slurry from the inlet passages and removing excess aqueous slurry from the outlet passages comprise one or more of: (i) allowing excess aqueous slurry to drain from the passages; (ii) forcing a compressed gas stream through the passages against the direction of slurry penetration; and (iii) applying a vacuum to the passages. 6. The method of claim 5, wherein the step of forcing a compressed gas stream through the passages is accomplished using an air knife. 7. The method of claim 1, wherein the steps of removing excess aqueous slurry from the inlet passages comprises forcing a compressed gas stream through the outlet passages and applying a vacuum to the inlet passages. 8. The method of claim 1, wherein the steps of removing excess aqueous slurry from the outlet passages comprises forcing a compressed gas stream through the inlet passages and applying a vacuum to the outlet passages. 9. The method of claim 1, wherein the steps of immersing the wall flow monolith in the aqueous slurry from a first direction comprises dipping the wall flow monolith into the aqueous slurry to a depth sufficient to coat the inlet passages of the substrate along the entire axial length of the wall flow monolith from the first direction. 10. The method of claim 1, wherein the steps of immersing the wall flow monolith in the aqueous slurry from a second direction comprises dipping the wall flow monolith into the aqueous slurry to a depth sufficient to coat the outlet passages of the substrate along the entire axial length of the wall flow monolith from the second direction. 11. The method of claim 1, wherein the steps of immersing the wall flow monolith in the aqueous slurry from a first direction to deposit the SCR catalyst composition on the inlet passages and removing excess aqueous slurry from the inlet passages are repeated. 12. The method of claim 1, wherein the steps of immersing the wall flow monolith in the aqueous slurry from a second direction, opposite the first direction, to deposit the SCR catalyst composition on the outlet passages and form a coated wall flow monolith and removing excess aqueous slurry from the outlet passages are repeated. 13. The method of claim 1, further comprising immersing the wall flow monolith in the aqueous slurry from the first direction to deposit a second layer of the SCR catalyst composition on the inlet passages; and immersing the wall flow monolith in the aqueous slurry from the second direction, opposite the first direction, to deposit a second layer of the SCR catalyst composition on the outlet passages. 14. The method of claim 1, wherein the walls have a porosity of from 55 to 75% and an average pore size of from 10 to 30 microns. 15. The method of claim 1, wherein the wall flow monolith has from about 100 to 400 cells per square inch and a wall thickness between 0.002 and 0.015 inches. 16. The method of claim 1, wherein the wall flow monolith comprises silicon carbide. 17. The method of claim 1, wherein the base metal component comprises copper. 18. The method of claim 1, wherein the zeolite has a silica to alumina ratio of at least 10. 19. The method of claim 1, wherein the SCR catalyst composition has thermal resistance to temperatures greater than 650° C. 20. The method of claim 1, wherein the SCR catalyst composition is effective to catalyze conversion of the NOx component to N2 in the presence of a reductant. 21. The method of claim 1, wherein the pressure drop of flowing air under ambient conditions across the soot filter is not more than 25% higher than the same soot filter containing no catalyst composition. 22. The method of claim 1, wherein the pressure drop of flowing air under ambient conditions across the soot filter is less than 20 kPa at an air flow of 300 cfm or less. 23. The method of claim 1, wherein the soot filter is effective for removing greater than 80% of particulate matter in an exhaust stream. 24. The method of claim 1, wherein the SCR catalyst composition permeates the walls at a concentration of 1.6 to 2.4 g/in3, which walls have a porosity of from 55 to 75% and an average pore size of from 10 to 30 microns, wherein the wall flow monolith comprises silicon carbide and has from about 100 to 400 cells per square inch and a wall thickness between 0.002 and 0.015 inches, and wherein the SCR catalyst composition comprises a zeolite having a silica to alumina ratio of at least 10 and copper. 25. The method of claim 1, wherein the aqueous slurry is prevented from contacting the open outlet end of the outlet passages during the step of immersing the wall flow monolith in the aqueous slurry from a first direction. 26. A method for disposing a selective catalytic reduction (SCR) catalyst composition on a wall flow monolith, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the method comprising: receiving an aqueous slurry comprising the SCR catalyst composition, the SCR catalyst composition comprising a zeolite and a base metal component;immersing the wall flow monolith vertically in a portion of the aqueous slurry such that a top surface of the wall flow monolith remains above the surface of the slurry and the aqueous slurry contacts an inlet face of each inlet passage, but is prevented from contacting an outlet face of each outlet passage, to form a coated wall flow monolith;removing excess aqueous slurry from the coated wall flow monolith;drying and calcining the coated wall flow monolith to form an integrated soot filter and SCR catalyst, wherein the SCR catalyst composition is present on the coated wall flow monolith at a concentration of at least 1.3 g/in3. 27. The method of claim 26, wherein the step of removing excess aqueous slurry comprises one or more of: (i) allowing excess aqueous slurry to drain from the passages; (ii) forcing a compressed gas stream through the passages against the direction of slurry penetration; and (iii) applying a vacuum to the passages. 28. The method of claim 26, wherein the walls have a porosity of from 55 to 75% and an average pore size of from 10 to 30 microns. 29. The method of claim 26, wherein the base metal component comprises copper. 30. The method of claim 26, wherein the pressure drop of flowing air under ambient conditions across the soot filter is less than 20 kPa at an air flow of 300 cfm or less.
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