[미국특허]
Glycol ether-based cyclohexanoate ester plasticizers and blends therefrom
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08K-005/12
C08K-005/10
C10M-105/36
C10M-129/72
C08K-005/00
출원번호
US-0527480
(2014-10-29)
등록번호
US-9771466
(2017-09-26)
발명자
/ 주소
Patil, Abhimanyu O.
Bodige, Satish
출원인 / 주소
ExxonMobil Chemical Patents Inc.
인용정보
피인용 횟수 :
1인용 특허 :
20
초록
Plasticizers of glycol ether-based cyclohexanoate esters and blends thereof with thermoplastic polymers, such as PVC, are disclosed.
대표청구항▼
1. A composition comprising a thermoplastic polymer and a first plasticizer compound of the formula: wherein each R1 is, independently, C1 to C12 linear or branched alkyl; each R2 is, independently, H or CH3; each n is, independently, 1, 2, 3 or 4, and when n=4, R1 is C2 to C12 linear or branched al
1. A composition comprising a thermoplastic polymer and a first plasticizer compound of the formula: wherein each R1 is, independently, C1 to C12 linear or branched alkyl; each R2 is, independently, H or CH3; each n is, independently, 1, 2, 3 or 4, and when n=4, R1 is C2 to C12 linear or branched alkyl,wherein the composition further comprises a second plasticizer comprising a compound of the formula: wherein R*1 is a saturated or unsaturated cyclic hydrocarbon substituted with an alkyl and/or an OXO-ester, and R*2 is a C4 to C20 hydrocarbyl, and wherein the second plasticizer compound comprises at least two cyclic moieties directly bonded to each other. 2. The composition of claim 1, wherein each R1 is independently, C2 to C6 alkyl. 3. The composition of claim 1, wherein each R1 is independently, C1 to C6 alkyl, R2 is H, and n is 2 or 3. 4. The composition of claim 1, wherein R1 is C1 to C6 alkyl, R2 is CH3, and n is 2 or 3. 5. The composition of claim 1, wherein R1 is C2 to C12 alkyl, R2 is H, and n is 4. 6. The composition of claim 1, where the first plasticizer compound is represented by one or more of the following formulae: 7. The composition of claim 1, wherein the thermoplastic polymer comprises at least one of vinyl chloride resins, polyesters, polyurethanes, ethylene-vinyl acetate copolymer, rubbers, poly(meth)acrylics and combinations thereof. 8. The composition of claim 1, wherein the thermoplastic polymer is polyvinyl chloride. 9. The composition of claim 1, wherein the thermoplastic polymer is present at 99 to 40 wt % and the first plasticizer is present at 1 to 60 wt %. 10. The composition of claim 1, wherein the thermoplastic polymer is a PVC suspension, a PVC microsuspension, a PVC emulsion, or a combination thereof. 11. The polymer composition of claim 1, further comprising: an additive of at least one of a filler, a pigment, a matting agent, a heat stabilizer, an antioxidant, a UV stabilizer, a flame retardant, a viscosity regulator, a solvent, a deaerating agent, an adhesion promoter, a process aid, and a lubricant. 12. A floor covering, wallpaper, tarpaulin, coated textile, wall covering comprising the composition of claim 1. 13. A film comprising the composition of claim 1 wherein the film is a roofing sheet, a tarpaulin, a banner, synthetic leather, packaging film, a medical article, a toy, a seal, or an automobile interior article. 14. The composition of claim 1, wherein the first plasticizer is one or more of: di(ethylene glycol)monohexyl cyclohexane-1,2-dicarboxylate,tri(ethylene glycol)monomethyl cyclohexane-1,2-dicarboxylate,tri(propylene glycol)monomethyl cyclohexane-1,2-dicarboxylate,tri(ethylene glycol)monoethyl cyclohexane-1,2-dicarboxylate,tri(ethylene glycol)monobutyl cyclohexane-1,2-dicarboxylate,di(ethylene glycol)monoethyl cyclohexane-1,2-dicarboxylate,di(ethylene glycol)monobutyl cyclohexane-1,2-dicarboxylate,tri(propylene glycol)monopropyl cyclohexane-1,2-dicarboxylate,tri(propylene glycol)monobutyl cyclohexane-1,2-dicarboxylate,poly(ethylene glycol)(4)dodecyl cyclohexane-1,2-dicarboxylate,ethylene glycol mono-2-ethylhexyl cyclohexane-1,2-dicarboxylate,tetra(ethylene glycol) mono methyl cyclohexane-1,2-dicarboxylate,di(ethylene glycol)hexadecyl cyclohexane-1,2-dicarboxylate,di(ethylene glycol)octadecyl cyclohexane-1,2-dicarboxylate,propylene glycol butyl cyclohexane-1,2-dicarboxylate, anddi(propylene glycol)methyl cyclohexane-1,2-dicarboxylate.
Dakka, Jihad; DeCaul, Lorenzo C.; Costello, Christine A.; Mozeleski, Edmund J.; Osterrieth, Pierre J.; Smirnova, Diana S.; Zushma, Stephen; Godwin, Allen D., Alkyl aromatic hydroalkylation for the production of plastisizers.
Patil, Abhimanyu O.; Smith, Nicholas V.; Santiesteban, Jose G.; Godwin, Allen D.; Rucker, Steven P.; Zushma, Stephen, Geminally disubstituted olefin-carbon monoxide-ethylene polymer useful as a polyvinyl chloride plasticizer and a method of making same.
Habeeb Jacob J. (Westfield NJ) Espino Ramon L. (Califon NJ) Vrahopoulou Elisavet P. (Chatham NJ), Lubricant composition containing alkoxylated amine salt of a dihydrocarbyldithiophosphoric acid (law024).
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