Hydroconversion multi-metallic catalyst and method for making thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-037/34
B01J-023/85
B01J-023/888
B01J-037/03
B01J-027/051
B01J-037/04
B01J-037/08
B01J-037/20
출원번호
US-0664123
(2015-03-20)
등록번호
US-9776181
(2017-10-03)
발명자
/ 주소
Kuperman, Alexander
Maesen, Theodorus Ludovicus Michael
Dykstra, Dennis
출원인 / 주소
Chevron U.S.A. Inc.
대리인 / 주소
Flaherty, Terrence M.
인용정보
피인용 횟수 :
0인용 특허 :
91
초록▼
In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can b
In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered in a chemical precipitation step, wherein the supernatant is mixed with at least one of an acid, a sulfide-containing compound, a base, and combinations thereof to precipitate at least 50% of metal ions in at least one of the metal residuals, wherein the precipitation is carried out at a pre-select pH. The precipitate is isolated and recovered, yielding an effluent stream. The precipitate and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction. The process generates an effluent to waste treatment containing less than 50 ppm metals.
대표청구항▼
1. In a process for forming a bulk hydroprocessing catalyst, the process comprising: co-precipitating at reaction conditions at least a Group VIB metal precursor feed and at least a Promoter metal precursor feed selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, to f
1. In a process for forming a bulk hydroprocessing catalyst, the process comprising: co-precipitating at reaction conditions at least a Group VIB metal precursor feed and at least a Promoter metal precursor feed selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, to form a mixture comprising a catalyst precursor;isolating the catalyst precursor from the mixture, forming a supernatant containing at least a Promoter metal residual and at least a Group VIB metal residual in an amount of at least 10 mole % of the metal precursor feeds;calcining the catalyst precursor to form a catalyst precursor of the formula (X)b(Mo)c(W)dOz; wherein X is Ni or Co, the molar ratio of b:(c+d) is 0.5/1 to 3/1, the molar ratio of c:d is >0.01/1, and z=[2b+6 (c+d)]/2; and sulfiding the catalyst precursor forming the bulk catalyst, the improvement comprising:mixing the supernatant with at least one of an acid, a base, and combinations thereof under mixing conditions at a temperature from ambient to 90° C. for a sufficient amount of time to precipitate at least 50 mole % of metal ions in at least one of the metal residuals, wherein the precipitation is carried out at a pre-select pH;isolating the precipitate to recover a first effluent containing less than 20 mole % of metal ions in at least one of the metal residuals in the supernatant;dissolving the precipitate with at least a base to convert the metal ions in the precipitate into at least a metal precursor feed; andrecycling the at least a metal precursor feed obtained in the dissolving step to the co-precipitating step, wherein the at least a Group VIB metal precursor feed comprises Mo and W compounds and the first effluent comprising less than 1000 ppm each of Mo and W. 2. The process of claim 1, further comprising: treating the first effluent in a reactor vessel having a plurality of electrodes having a positive or a negative charge provided by a power supply, and wherein the electrodes react with at least one of the metal residuals, forming a slurry containing at least a precipitate;isolating the precipitate from the slurry to recover a second effluent containing less than 5000 ppm of metal ions in at least one of the metal residuals. 3. The process of claim 2, further comprising: adding to the second effluent at least an additive selected from the group of an acid, a sulfide-containing compound, a base, and combinations thereof, under mixing conditions for a sufficient amount of time to precipitate at a first pre-selected pH at least a portion of at least one of the metal residuals, generating a third effluent containing less than 1000 ppm of metal ions in at least one of the metal residuals. 4. The process of claim 1, wherein the supernatant is mixed with at least an acid selected from the group of sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid, acetic acid, oxalic acid, nitric acid, and mixtures thereof for a pre-select pH of less than 3.
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