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Methods and apparatuses for separating CO2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sul

Methods and apparatuses for separating CO2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.

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1. A method comprising: (a) gasifying a carbonaceous feedstock to form a gasified stream comprising H2S, CO2, CO and H2;(b) converting at least a portion of the CO in the gasified stream to CO2 and H2 using a water-gas shift reaction, resulting in a sour syngas stream;(c) introducing the sour syngas

1. A method comprising: (a) gasifying a carbonaceous feedstock to form a gasified stream comprising H2S, CO2, CO and H2;(b) converting at least a portion of the CO in the gasified stream to CO2 and H2 using a water-gas shift reaction, resulting in a sour syngas stream;(c) introducing the sour syngas stream into a sour pressure swing adsorption (SPSA) system having a plurality of adsorber beds;(d) performing a cyclic PSA process using the SPSA system comprising the following steps:(i) pressurizing a first bed of the plurality of adsorber beds to a first pressure;(ii) feeding the sour syngas stream into an inlet end of the pressurized first bed and discharging a first gas stream from an outlet end of the first bed;(iii) after the feeding step, introducing a rinse gas comprising at least 99 mol % N2 into the first bed, the rinse gas being from a source other than directly from another of the plurality of adsorber beds;(e) removing a product stream from the SPSA system, the product stream having a greater concentration of H2 than the sour syngas stream and comprising at least 80 mol % H2 and at least 10 mol % N2;(f) removing a tail gas stream from the SPSA system, the tail gas stream having a greater concentration of CO2 and H2S than the sour syngas stream; and(g) separating the tail gas stream into an H2S-enriched stream and a H2S-depleted stream using an acid gas enrichment (AGE) system. 2. The method of claim 1, wherein step (a) comprises gasifying a carbonaceous feedstock to form a gasified stream comprising CO, H2, at least 1000 ppm H2S, and at least 20 mol % CO2. 3. The method of claim 1, further comprising: (h) synthesizing a reactor product stream comprising at least 10 mol % NH3 from the product stream. 4. The method of claim 1, wherein step (d) further comprises: (iv) reducing the pressure of the first bed to a second pressure by placing the outlet end of the first bed in flow communication with an outlet end of a second bed of the plurality of adsorber beds while performing step (d)(iii). 5. The method of claim 4, wherein step (d) further comprises: (v) further reducing the pressure of the first bed to a third pressure by placing the outlet end of the first bed in flow communication with an outlet end of a third bed of the plurality of adsorber beds while performing (d)(iii). 6. The method of claim 5, wherein step (d) further comprises: (vi) after performing step (d)(iii) in the first bed, further reducing the pressure of the first bed to a fourth pressure by placing the outlet end of the first bed in flow communication with an outlet end of a fourth bed of the plurality of adsorber beds. 7. The method of claim 1, wherein step (d)(iii) comprises after the feeding step, introducing a rinse gas into the inlet end of the first bed, the rinse gas being from a source other than directly from another of the plurality of adsorber beds. 8. The method of claim 1, wherein step (d) further comprises: (iv) after performing step (d)(iii) in the first bed, reducing the pressure of the first bed to a second pressure by placing the outlet end of the first bed in flow communication with an outlet end of a second bed of the plurality of adsorber beds. 9. The method of claim 1, wherein step (g) comprises separating the tail gas stream into an H2S-enriched stream and a H2S-depleted stream using an acid gas enrichment (AGE) system, the H2S-enriched stream comprising at least 5 mol % H2S and no more than 95 mol % CO2. 10. The method of claim 1, further comprising: (k) converting at least a portion of the H2S-enriched stream to one or more selected from the group of sulfuric acid, elemental sulfur, a product derived from sulfuric acid, and a product derived from elemental sulfur using a sulfur recovery unit. 11. The method of claim 1, wherein step (b) comprises converting at least a portion of the CO in the gasified stream to CO2 and H2 using a water-gas shift reaction, resulting in a sour syngas stream comprising at least 0.02 mol % sulfur-containing species and 25 mol % CO2. 12. The method of claim 1, wherein step (c) comprises introducing the sour syngas stream into a sour pressure swing adsorption (SPSA) system having at least ten adsorber beds. 13. The method of claim 1, further comprising: (I) cooling the sour syngas stream after step (b) and before step (c). 14. The method of claim 1, further comprising: (m) after performing step (b) and before performing step (c), passing the sour syngas stream through a guard bed containing an adsorber adapted to remove organic tar compounds. 15. A method comprising: (a) gasifying a carbonaceous feedstock to form a gasified stream comprising H2S, CO2, CO and H2;(b) converting at least a portion of the CO in the gasified stream to CO2 and H2 using a water-gas shift reaction, resulting in a sour syngas stream;(c) introducing the sour syngas stream into a sour pressure swing adsorption (SPSA) system having a plurality of adsorber beds;(d) performing a cyclic PSA process using the SPSA system comprising the following steps:(i) pressurizing a first bed of the plurality of adsorber beds to a first pressure;(ii) feeding the sour syngas stream into an inlet end of the pressurized first bed and discharging a first gas stream from an outlet end of the first bed;(iii) after the feeding step, introducing a rinse gas comprising at least 85 mol % of one or more selected from the group of CO2 and H2S into the first bed, the rinse gas being from a source other than directly from another of the plurality of adsorber beds.(e) removing a product stream from the SPSA system, the product stream having a greater concentration of H2 than the sour syngas stream;(f) removing a tail gas stream from the SPSA system, the tail gas stream having a greater concentration of CO2 and H2S than the sour syngas stream; and(g) separating the tail gas stream into an H2S-enriched stream and a H2S-depleted stream using an acid gas enrichment (AGE) system. 16. The method of claim 15, wherein step (e) comprises removing a product stream from the PSA system, the product stream comprising at least 60 mol % H2 and at least 25 mol % CO. 17. The method of claim 15, further comprising: (i) synthesizing a reactor product stream comprising at least 10 mol % MeOH from the product stream. 18. A method comprising: (a) gasifying a carbonaceous feedstock to form a gasified stream comprising H2S, CO2, CO and H2;(b) converting at least a portion of the CO in the gasified stream to CO2 and H2 using a water-gas shift reaction, resulting in a sour syngas stream;(c) introducing the sour syngas stream into a sour pressure swing adsorption (SPSA) system having a plurality of adsorber beds;(d) performing a cyclic PSA process using the SPSA system comprising the following steps:(i) pressurizing a first bed of the plurality of adsorber beds to a first pressure;(ii) feeding the sour syngas stream into an inlet end of the pressurized first bed and discharging a first gas stream from an outlet end of the first bed;(iii) after the feeding step, introducing a rinse gas into the first bed, the rinse gas being from a source other than directly from another of the plurality of adsorber beds;(e) removing a product stream from the SPSA system, the product stream having a greater concentration of H2 than the sour syngas stream;(f) removing a tail gas stream from the SPSA system, the tail gas stream having a greater concentration of CO2 and H2S than the sour syngas stream;(g) separating the tail gas stream into an H2S-enriched stream and a H2S-depleted stream using an acid gas enrichment (AGE) system; and(h) recycling at least a portion of the H2S-depleted stream for pneumatically conveying the carbonaceous feedstock in step (a).