An apparatus and method for enhancing the yield and purity of hydrogen when reforming hydrocarbons is disclosed in one embodiment of the invention as including receiving a hydrocarbon feedstock fuel (e.g., methane, vaporized methanol, natural gas, vaporized diesel, etc.) and steam at a reaction zone
An apparatus and method for enhancing the yield and purity of hydrogen when reforming hydrocarbons is disclosed in one embodiment of the invention as including receiving a hydrocarbon feedstock fuel (e.g., methane, vaporized methanol, natural gas, vaporized diesel, etc.) and steam at a reaction zone and reacting the hydrocarbon feedstock fuel and steam in the presence of a catalyst to produce hydrogen gas. The hydrogen gas is selectively removed from the reaction zone while the reaction is occurring by selectively diffusing the hydrogen gas through a porous ceramic membrane. The selective removal of hydrogen changes the equilibrium of the reaction and increases the amount of hydrogen that is extracted from the hydrocarbon feedstock fuel.
대표청구항▼
1. An apparatus comprising: material comprising alumina powder reacted with a phosphate-containing reagent, said material forming at least one ceramic microchannel within the apparatus;a reaction zone, positioned within the apparatus and at least partially within at least one microchannel, the react
1. An apparatus comprising: material comprising alumina powder reacted with a phosphate-containing reagent, said material forming at least one ceramic microchannel within the apparatus;a reaction zone, positioned within the apparatus and at least partially within at least one microchannel, the reaction zone configured to receive reactants comprising a hydrocarbon fuel and steam, the reactants reacting to produce reaction products comprising hydrogen gas;a combustion zone, positioned within the apparatus, in fluid communication with the reaction zone, the combustion zone configured to receive at least one of a reactant and a reaction product;a product zone; anda porous membrane positioned between the reaction zone and the product zone, the porous membrane comprising pores of varying size, the porous membrane configured to allow hydrogen gas to diffuse through said pores of the porous membrane at a higher diffusion rate than diffusion rates of reactants within the reaction zone and any other reaction products. 2. The apparatus of claim 1, comprising confined spaces having lateral dimensions of less than 1 mm. 3. The apparatus of claim 1, wherein the at least one ceramic microchannel comprises a very high surface area and a continuous nanopore network. 4. The apparatus of claim 1, wherein, the at least one ceramic microchannel comprises phosphate-bonded ceramic materials. 5. The apparatus of claim 1, wherein the at least one ceramic microchannel comprises at least one of micro-sized pores and nano-sized pores. 6. The apparatus of claim 5, wherein the at least one of micro-sized pores and nano-sized pores are located adjacent to a reaction zone. 7. An apparatus comprising: at least one microchannel formed within the apparatus in material comprising alumina powder reacted with a phosphate-containing reagent, said material comprising confined spaces having lateral dimensions of less than 1 mm;a reaction zone, positioned within the apparatus and at least partially within at least one microchannel, the reaction zone configured to receive reactants comprising hydrocarbon and steam to produce reaction products comprising hydrogen gas;a combustion zone, positioned within the apparatus, in fluid communication with the reaction zone, the combustion zone configured to receive at least one of a reactant and a reaction product;a product zone; anda porous membrane positioned between the reaction zone and the product zone, the porous membrane comprising pores of varying size, the porous membrane configured to allow hydrogen gas to diffuse through said pores of the porous membrane at a higher diffusion rate than diffusion rates of reactants within the reaction zone and any other reaction products, and wherein a first surface of the porous membrane is exposed to the reaction zone and a second surface of the porous membrane opposite the first surface is exposed to the product zone; and wherein at least one of micro-sized pores and nano-sized pores are located adjacent to the reaction zone.
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이 특허에 인용된 특허 (10)
Chellappa, Anand; Vencill, Thomas R.; Powell, Michael Roy; Godshall, Ned A., Compact devices for generating pure hydrogen.
Kapoor Akhilesh (South Orange NJ) Krishnamurthy Ramachandran (Chestnut Ridge NY) MacLean Donald L. (Clinton NJ), Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed.
Helferich Richard L. (Clayton OH) Schenck Robert C. (Kettering OH), Methods for the manufacture of porous ceramic shapes containing membraneous surfaces.
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