Energetic materials that are photoactive or believed to be photoactive may include a conventional explosive (e.g. PETN, nitroglycerine) derivatized with an energetic UV-absorbing and/or VIS-absorbing chromophore such as 1,2,4,5-tetrazine or 1,3,5-triazine. Absorption of laser light having a suitably
Energetic materials that are photoactive or believed to be photoactive may include a conventional explosive (e.g. PETN, nitroglycerine) derivatized with an energetic UV-absorbing and/or VIS-absorbing chromophore such as 1,2,4,5-tetrazine or 1,3,5-triazine. Absorption of laser light having a suitably chosen wavelength may result in photodissociation, decomposition, and explosive release of energy. These materials may be used as ligands to form complexes. Coordination compounds include such complexes with counterions. Some having the formula M(L)n2+ were synthesized, wherein M is a transition metal and L is a ligand and n is 2 or 3. These may be photoactive upon exposure to a laser light beam having an appropriate wavelength of UV light, near-IR and/or visible light. Photoactive materials also include coordination compounds bearing non-energetic ligands; in this case, the counterion may be an oxidant such as perchlorate.
대표청구항▼
1. A compound of the formula or of the formula or of the formula or of the formula wherein X is selected from chloride, bromide, or iodide, andwherein Y is selected from —OCH2C(CH2ONO2)3, —OCH2C((F)(NO2)2), —OCH(ONO2)2, orwherein X is and wherein Y is orwherein X and Y are each independently select
1. A compound of the formula or of the formula or of the formula or of the formula wherein X is selected from chloride, bromide, or iodide, andwherein Y is selected from —OCH2C(CH2ONO2)3, —OCH2C((F)(NO2)2), —OCH(ONO2)2, orwherein X is and wherein Y is orwherein X and Y are each independently selected from —OCH2C(CH2ONO2)3, —OCH2C((F)(NO2)2), —OCH(ONO2)2, or NH2, with the exception that if X is NH2, then Y is not NH2. 2. The compound of claim 1, wherein the formula is wherein X is selected form chloride, bromide, and iodide, andwherein Y is —OCH2C(CH2ONO2)3. 3. The compound of claim 1, wherein X=Y=—OCH2C(CH2ONO2)3. 4. The compound of claim 1, wherein X=Y=—OCH2C((F)(NO2)2). 5. The compound of claim 1, wherein X=Y=—OCH(ONO2)2. 6. The compound of claim 1, wherein X=Y= 7. The compound of claim 1, wherein X=Y=
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이 특허에 인용된 특허 (1)
Coburn Michael D. (Los Alamos NM) Ott Donald G. (Los Alamos NM), Synthesis of 3,6-diamino-1,2,4,5-tetrazine.
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