Ionic liquids containing symmetric quaternary phosphonium cations and phosphorus-containing anions, and their use as lubricant additives
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C10M-137/12
C10M-137/04
C10M-137/10
C10M-171/00
출원번호
US-0184754
(2014-02-20)
등록번호
US-9957460
(2018-05-01)
발명자
/ 주소
Qu, Jun
Luo, Huimin
출원인 / 주소
UT-BATTELLE, LLC
대리인 / 주소
Scully Scott Murphy & Presser
인용정보
피인용 횟수 :
0인용 특허 :
5
초록▼
An ionic liquid composition having the following generic structural formula: wherein R1, R2, R3, and R4 are equivalent and selected from hydrocarbon groups containing at least three carbon atoms, and X− is a phosphorus-containing anion, particularly an organophosphate, organophosphonate, or organop
An ionic liquid composition having the following generic structural formula: wherein R1, R2, R3, and R4 are equivalent and selected from hydrocarbon groups containing at least three carbon atoms, and X− is a phosphorus-containing anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base oil, wherein the ionic liquid is dissolved in the base oil. Further described are methods for applying the ionic liquid or lubricant composition onto a mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.
대표청구항▼
1. A lubricant composition comprising: (i) an ionic liquid having the following generic structural formula: wherein R1, R2, R3, and R4 are equivalent and selected from alkyl groups containing at least six carbon atoms, and X− is a phosphorus-containing anion having the following generic structural f
1. A lubricant composition comprising: (i) an ionic liquid having the following generic structural formula: wherein R1, R2, R3, and R4 are equivalent and selected from alkyl groups containing at least six carbon atoms, and X− is a phosphorus-containing anion having the following generic structural formula: wherein R5 and R6 are independently selected from alkyl groups having at least four carbon atoms, wherein the alkyl groups are optionally substituted with one or more fluorine atoms, and R5 and R6 optionally interconnect to form a ring; and X1, X2, W, and Y are independently selected from O and S atoms; and(ii) a base oil;wherein said ionic liquid is dissolved in an amount of 2 to 10 wt % in said base oil. 2. The lubricant composition of claim 1, wherein said base oil is a mechanical lubricating oil. 3. The lubricant composition of claim 1, wherein said ionic liquid is included in said base oil in an amount of 2 to 5 wt %. 4. The lubricant composition of claim 1, wherein R1, R2, R3, and R4 are equivalent and selected from alkyl groups containing at least eight carbon atoms. 5. The lubricant composition of claim 1, wherein said phosphorus-containing anion has the formula: 6. The lubricant composition of claim 1, wherein R5 and R6 are alkyl groups containing at least six carbon atoms. 7. The lubricant composition of claim 1, wherein R5 and R6 are branched alkyl groups. 8. The lubricant composition of claim 1, wherein said lubricant composition further comprises a metal-containing anti-wear additive. 9. The lubricant composition of claim 8, wherein said metal-containing anti-wear additive is a zinc dialkyldithiophosphate.
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이 특허에 인용된 특허 (5)
Singh Gurdial (Hockessin DE) Von Rutte Richard Edward (Riehen-Basel CH), Antistatic composition containing an aliphatic polyester or polyether ester and a phosphonium salt.
Habeeb, Jacob Joseph; Prince, Jessica Lee; Landis, Michael Eugene, Method for reducing friction/wear of formulated lubricating oils by use of ionic liquids as anti-friction/anti-wear additives.
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