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A method of producing a hydrogenation catalyst, for example, a phthalate hydrogenation catalyst, comprising contacting a silica support having a medium pore size of at least about 10 nm with an acid to produce a treated silica support, and depositing a noble metal, preferably ruthenium, on the treat

A method of producing a hydrogenation catalyst, for example, a phthalate hydrogenation catalyst, comprising contacting a silica support having a medium pore size of at least about 10 nm with an acid to produce a treated silica support, and depositing a noble metal, preferably ruthenium, on the treated silica support to produce a noble metal-containing silica support, and optionally contacting the noble metal-containing silica support with a chelating agent to form the hydrogenation catalyst; a hydrogenation catalyst prepared by that method; and a method of hydrogenating unsaturated hydrocarbons, such as, phthalates, in which an unsaturated hydrocarbon is contacted with hydrogen gas in the presence of the hydrogenation catalyst of the invention.

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1. A method for the preparation of a silica-supported noble metal hydrogenation catalyst comprising the steps of: (a0) steam treating a silica material to obtain a steam-treated silica support having a median pore size of at least about 10 nm and no more than about 300 nm and a silica content of at

1. A method for the preparation of a silica-supported noble metal hydrogenation catalyst comprising the steps of: (a0) steam treating a silica material to obtain a steam-treated silica support having a median pore size of at least about 10 nm and no more than about 300 nm and a silica content of at least 60 wt %;(a) contacting the steam-treated silica support with an acid to make an acid-treated silica support, thereafter calcining the acid-treated silica support at a temperature in the range of from about 250° C. to about 1000° C. to obtain a calcined silica support; and(b) contacting the calcined silica support obtained in step (a) with a solution comprising a noble metal salt and a chelating agent to produce a noble metal-containing silica support, wherein the chelating agent has at least one carboxylic acid functional group or hydroxyl functional group and from 2 to 20 carbon atoms. 2. The method of claim 1, wherein the noble metal is selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof. 3. The method of claim 1, wherein the noble metal is ruthenium. 4. The method of claim 1, further comprising the step of calcining the noble metal-containing silica support obtained in step (b). 5. The method of claim 1, wherein the noble metal-containing silica support has a hydrogen to noble metal chemisorption ratio of at least about 0.50. 6. The method of claim 1, wherein the silica support used in step (a) has a median pore size of at least about 20 nm. 7. The method of claim 1, wherein the hydroxyl group concentration of the surface of the acid-treated silica support obtained in step (a) is at least 1 Si—OH group per nm2 greater than that of the silica support used in step (a). 8. The method of claim 1, wherein the acid used in step (a) is in the form of an aqueous solution having a pH of from about 0.0 to about +3.0. 9. The method of claim 1, wherein the acid used in step (a) is nitric acid. 10. The method of claim 1, wherein the steam-treated silica support used in step (a) has a crush strength of at least 800 g/mm. 11. The method of claim 1, further comprising the step of activating the catalyst by contacting the noble metal-containing silica support obtained in step (b) with hydrogen gas. 12. The method of claim 1, wherein the steam-treated silica support has a silica content of at least 80 wt %. 13. The method of claim 1, wherein in step (a0), the silica material is steam treated at a temperature of at least 400° C. 14. The method of claim 1, wherein in step (a0), the silica material is steam treated at a temperature in a range from about 500° C. to about 800° C.