[특허]Particles including zeolite catalysts and their use in oligomerization processes

[미국특허] Particles including zeolite catalysts and their use in oligomerization processes 원문보기

IPC분류정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	C07C-002/12 C07C-011/02 B01J-029/06 B01J-029/70 B01J-035/02 B01J-035/08 B01J-037/00 C10G-050/00
출원번호	US-0096639 (2016-04-12)
등록번호	US-10138175 (2018-11-27)
우선권정보	EP-10174865 (2010-09-11)
발명자 / 주소	Tosin, Geraldine Janssen, Mechilium J. G. Hamilton, Paul Mathys, Georges M. K.
출원인 / 주소	ExxonMobil Chemical Patents Inc.
대리인 / 주소	Tyus, Darryl M.
인용정보	피인용 횟수 : 0 인용 특허 : 23

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Embodiments of an invention disclosed herein relate to particles made from zeolite catalysts and their use in oligomerization processes. In particular, shaped particles (for example, spheroid particles) are made from compositions including the contact product of at least one zeolite catalyst and at

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1. A process for the oligomerization of olefins, the process comprising contacting at least one spheroid particle with a feedstock under oligomerization conditions to form at least one oligomer product, wherein the spheroid particle has an average particle size of from 0.1 mm to 5.0 mm and comprises the product of:(1) at least one zeolite catalyst which comprises TON or MFS framework structure; and(2) at least one binder which comprises metal oxide and/or clay,wherein the feedstock comprises one or more of propene, pentenes, hexenes, their isomers, and mixtures thereof. 2. The process of claim 1, wherein the feedstock comprises one or more of propane, pentane, hexane, their isomers, or a mixture thereof. 3. The process of claim 1, wherein the process comprises a catalyst life of 10% or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 4. The process of claim 1, wherein the process comprises a catalyst life of 30% or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 5. The process of claim 1, wherein the process comprises a catalyst life of 50% or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 6. The process of claim 1, wherein the process comprises a catalyst life of 75% or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 7. The process of claim 1, wherein the process comprises an olefin selectivity increase of 1 wt % or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 8. The process of claim 1, wherein the process comprises an olefin selectivity increase of 2 wt % or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 9. The process of claim 1, wherein the process comprises an olefin selectivity increase of 3 wt % or greater as compared to an extrudate of the same chemical composition in the shape of a ( 1/16th inch (1.5875 mm) quadrulobe or 1/20th inch (1.2700 mm) quadrulobe); at oligomerization temperatures of from 180° C. to 320° C.; at an olefin constant per pass conversion rate of from 60 to 99 wt % based upon the total weight of olefins; and at a space velocity of from 1 to 20 h−1. 10. The process of claim 1, wherein the zeolite having TON framework in ZSM-22. 11. The process of claim 1, wherein the zeolite having MFS framework is ZSM-57.

이 특허에 인용된 특허 (23) 인용/피인용 타임라인 분석

Mathys Georges Marie Karel (Bierbeek BEX) Martens Luc Roger Marc (Meise BEX) Baes Marleen Augusta (Oud-Heverlee BEX) Verduijn Johannes Petrus (Leefdaal BEX) Huybrechts Diane Renata Cornelia (Oud-Turn, Alkene oligomerization.
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Haag Werner O. (Trenton NJ) Olson David H. (Pennington NJ), Alkylation in presence of thermally modified crystalline aluminosilicate catalyst.
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Nozemack, Richard J.; Chi, Chang W.; Schwonke, John J., Binderless zeolite extrudates and method of producing.
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Tabak, Samuel A., Catalytic conversion with catalyst regeneration sequence.
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Givens Edwin N. (Pitman NJ) Plank Charles J. (Woodbury NJ) Rosinski Edward J. (Deptford NJ), Converting low molecular weight olefins over zeolites.
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Plank Charles J. (Woodbury NJ) Rosinski Edward J. (Pedricktown NJ) Givens Edwin N. (Pitman NJ), Converting low molecular weight olefins over zeolites.
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Timken Hye K. C. (Woodbury NJ), Gasoline upgrading process.
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Frame, Robert R.; Jan, Den-Yang; Abrevaya, Hayim, Layered oligomerization catalyst system.
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Duplan,Jean Luc; Lacombe,Sylvie; Bayle,J��r��me; Coupard,Vincent, Method for jointly producing propylene and petrol from a relatively heavy charge.
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Kulprathipanja Santi ; Spehlmann Benjamin C. ; Willis Richard R. ; Sherman John D. ; Leet William A., Method for treating an organic liquid contaminated with an iodide compound.
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Harandi Mohsen N. (Lawrenceville NJ) Owen Hartley (Belle Mead NJ) Tabak Samuel A. (Wenonah NJ), Multistage catalytic reactor system for production of heavy hydrocarbons.
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Mathys, Georges M. K.; Brown, Stephen H.; Beckers, Hubertus Joseph; Caers, Raphael Frans; Godsmark, John Stephen; Martens, Luc R. M.; Shutt, John Richard; Van Driessche, Eddy T., Olefin oligomerization.
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Brown, Stephen Harold; Godsmark, John Stephen; Mathys, Georges Marie Karel, Olefin oligomerization process.
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Hayim Abrevaya ; Robert R. Frame, Olefin oligomerization using surface modified molecular sieve catalyst.
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Verrelst Wim Herman,BEX ; Martens Luc Roger Marc,BEX, Oligomerization and catalysts therefor.
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Brown, Stephen Harold; Mathys, Georges Marie, Oligomerization of isobutene-containing feedstocks.
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Brown,Stephen Harold; Mathys,Georges Marie, Oligomerization of isobutene-containing feedstocks.
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Boulton James R. (Chalfont PA) Kremer Ross A. (Ringoes NJ), Oligomers of cyclopentadiene and process for making them.
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Miller Stephen J. (San Francisco CA), Preparation of aluminosilicate zeolites.
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Verduijn, Johannes P.; Mohr, Gary David, Preparation of high silica zeolites bound by zeolite and use thereof.
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Nesterenko, Nikolai; Vermeiren, Walter; Van Donk, Sander, Process for obtaining catalyst composites comprising MeAPO and their use in conversion of organics to olefins.
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Takahashi Kazuo (Kanagawa JPX) Kumata Fumio (Kanagawa JPX) Nozaki Hitoshi (Kanagawa JPX) Inoue Shinichi (Kanagawa JPX) Makabe Toshiji (Kanagawa JPX), Process for producing spherical zeolite catalyst and apparatus for producing the same.
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Chitnis Girish K. (Chadds Ford PA) Herbst Joseph A. (Turnersville NJ) Valyocsik Ernest W. (Yardley PA), Use of ZSM-57 in catalytic cracking for gasoline octane improvement and co-production of light olefins.
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[미국특허] Particles including zeolite catalysts and their use in oligomerization processes 원문보기

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