Method for producing a polylactic acid-based film or sheet
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08J-005/18
B29C-043/00
B29C-043/24
C08L-023/02
C08L-067/02
C08L-067/04
C09D-004/06
B29C-047/00
B29K-067/00
C08L-023/26
C08L-027/18
C08L-051/06
B29C-047/88
B29C-047/90
출원번호
US-0875736
(2015-10-06)
등록번호
US-10253145
(2019-04-09)
우선권정보
JP-2008-257383 (2008-10-02)
발명자
/ 주소
Ishiguro, Shigeki
Senda, Hiroki
출원인 / 주소
NITTO DENKO CORPORATION
대리인 / 주소
Sughrue Mion, PLLC
인용정보
피인용 횟수 :
0인용 특허 :
3
초록▼
A method of producing a polylactic acid based film or sheet with improved heat resistance and comprised of a resin composition containing a polylactic acid according to a melt film forming method, wherein the resin composition comprises polylactic acid (A), an acidic functional group-denatured olefi
A method of producing a polylactic acid based film or sheet with improved heat resistance and comprised of a resin composition containing a polylactic acid according to a melt film forming method, wherein the resin composition comprises polylactic acid (A), an acidic functional group-denatured olefin based polymer (B) containing an acidic functional group, and having an acid number of 10-70 mg KOH/g and a weight average molecular weight of 10,000-80,000, and a tetrafluoroethylene based polymer (C), which method comprises performing melt film formation at a temperature of the resin composition between the crystallization temperature (Tc) in a decreasing temperature process of the resin composition +15° C. and the melting temperature (Tm) in a raising temperature process −5° C., or solidifying the resin composition melt-formed in a film state by cooling after a temperature controllable step at crystallization temperature (Tc) in the decreasing temperature process ±10° C.
대표청구항▼
1. A method of producing a film or sheet of a resin composition containing a polylactic acid according to a melt film forming method, wherein the resin composition comprises polylactic acid (A), an acidic functional group-denatured olefin based polymer (B) containing an acidic functional group, and
1. A method of producing a film or sheet of a resin composition containing a polylactic acid according to a melt film forming method, wherein the resin composition comprises polylactic acid (A), an acidic functional group-denatured olefin based polymer (B) containing an acidic functional group, and having an acid number of 10-70 mg KOH/g and a weight average molecular weight of 10,000-80,000, and a tetrafluoroethylene based polymer (C), which method comprises forming the film or sheet from the resin composition by a melt film formation,wherein, during the melt film formation, the resin composition has a temperature between a temperature 15° C. higher than a crystallization temperature (Tc) of the resin composition in a decreasing temperature process and a temperature 5° C. lower than a melting temperature (Tm) of the resin composition in a raising temperature process, orthe melt film formed resin composition is solidified by cooling the melt film formed resin composition after a crystallization promoting step at a temperature which is between 10° C. below and 10° C. above the crystallization temperature (Tc) of the resin composition in the decreasing temperature process. 2. The production method according to claim 1, wherein, during the melt film formation, the resin composition has the temperature between the temperature 15° C. higher than the crystallization temperature (Tc) of the resin composition in the decreasing temperature process and the temperature 5° C. lower than the melting temperature (Tm) of the resin composition in the raising temperature process, and the melt film formed resin composition is solidified by cooling the melt film formed resin composition after the crystallization promoting step at the temperature which is between 10° C. below and 10° C. above the crystallization temperature (Tc) of the resin composition in the decreasing temperature process. 3. The production method according to claim 1, wherein the resin composition comprises the acidic functional group-denatured olefin based polymer (B) in an amount of 0.1-5.0 parts by weight per 100 parts by weight of the polylactic acid (A). 4. The production method according to claim 1, wherein the resin composition comprises the tetrafluoroethylene based polymer (C) in an amount of 0.1-10.0 parts by weight per 100 parts by weight of the polylactic acid (A). 5. The production method according to claim 1, wherein the melt film forming method is a technique comprising finally passing the resin composition in a molten state through a gap between two metal rolls to achieve a desired film thickness. 6. The production method according to claim 5, wherein the melt film forming method is a calender film forming method. 7. The production method according to claim 1, wherein the acidic functional group in the acidic functional group-denatured olefin based polymer is an acid anhydride. 8. The production method according to claim 1, wherein the resin composition further comprises 0.1-5.0 parts by weight of crystallizing agent (D) per 100 parts by weight of the polylactic acid (A). 9. The production method according to claim 1, wherein the crystallization promoting step of the resin composition is achieved by a metal roll. 10. A method of producing a film or sheet of a resin composition containing a polylactic acid according to a calender film forming method, wherein the resin composition comprises 100 parts by weight of polylactic acid (A), 0.1-5.0 parts by weight of an acidic functional group-denatured olefin based polymer (B) containing an acidic functional group, and having an acid number of 10-70 mg KOH/g and a weight average molecular weight of 10,000-80,000, and 0.1-10.0 parts by weight of a tetrafluoroethylene based polymer (C), which method comprises forming the film or sheet from the resin composition by calender-rolling,wherein, during the calender-rolling, the resin composition has a temperature between a temperature 15° C. higher than a crystallization temperature (Tc) of the resin composition in a decreasing temperature process and a temperature 5° C. lower than a melting temperature (Tm) of the resin composition in a raising temperature process, orthe melt film formed resin composition is solidified by cooling the melt film formed resin composition after a crystallization promoting step at a temperature which is between 10° C. below and 10° C. above the crystallization temperature (Tc) of the resin composition in the decreasing temperature process. 11. The production method according to claim 10, wherein, during the calender-rolling the resin composition has the temperature between the temperature 15° C. higher than the crystallization temperature (Tc) of the resin composition in the decreasing temperature process and the temperature 5° C. lower than the melting temperature (Tm) of the resin composition in the raising temperature process, and the melt film formed resin composition is solidified by cooling the melt film formed resin composition after the crystallization promoting step at the temperature which is between 10° C. below and 10° C. above the crystallization temperature (Tc) of the resin composition in the decreasing temperature process. 12. The production method according to claim 10, wherein the acidic functional group in the acidic functional group-denatured olefin based polymer is an acid anhydride. 13. The production method according to claim 10, wherein the resin composition further comprises 0.1-5.0 parts by weight of crystallizing agent (D) per 100 parts by weight of the polylactic acid (A). 14. The production method according to claim 10, wherein the crystallization promoting step of the resin composition is achieved by a metal roll.
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이 특허에 인용된 특허 (3)
Ishiguro, Shigeki; Senda, Hiroki, Flame-retardant poly lactic acid-containing film or sheet, and method for manufacturing thereof.
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