Catalyzed SCR filter and emission treatment system
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-053/34
B01J-029/76
B01D-005/00
B01D-019/00
B01D-053/94
B01J-037/02
F01N-003/023
F01N-003/10
F01N-003/20
F01N-013/00
F01N-003/28
B01J-035/04
B01J-035/10
B01J-037/08
출원번호
US-0672932
(2017-08-09)
등록번호
US-10258972
(2019-04-16)
발명자
/ 주소
Patchett, Joseph A.
Dettling, Joseph C.
Przybylski, Elizabeth A.
출원인 / 주소
BASF CORPORATION
대리인 / 주소
Womble Bond Dickinson (US) LLP
인용정보
피인용 횟수 :
0인용 특허 :
76
초록▼
Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by
Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.
대표청구항▼
1. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the emission treatment system comprising: (a) a diesel oxidation catalyst comprising a platinum group metal dispersed on a refractory oxide support positioned downstream from a diesel engine;(b)
1. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the emission treatment system comprising: (a) a diesel oxidation catalyst comprising a platinum group metal dispersed on a refractory oxide support positioned downstream from a diesel engine;(b) an injector in fluid communication with and downstream of the oxidation catalyst, wherein the injector periodically meters ammonia or an ammonia precursor into the exhaust stream; and(c) a catalyst article in fluid communication with and downstream of the injector, the catalyst article comprising a wall flow monolith and a catalytic material contained within the wall flow monolith, wherein the wall flow monolith has a wall porosity of at least 50% and comprises a plurality of longitudinally extending passages formed by longitudinally extending porous walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, and wherein the catalytic material comprises a zeolite and a base metal selected from copper and iron present in an amount of from about 0.1 to 30 percent by weight of the total weight of base metal plus zeolite, the zeolite having pores connected in three dimensions and a silica to alumina ratio of at least about 10, the wall flow monolith having integrated NOx and particulate removal efficiency when exposed to diesel engine exhaust and ammonia or an ammonia precursor. 2. The emission treatment system of claim 1, wherein the injector periodically meters urea into the exhaust stream. 3. The emission treatment system of claim 2, further comprising a reservoir for storage of a solution of water and urea. 4. The emission treatment system of claim 1, further comprising an additional SCR catalyst downstream of the catalyst article. 5. The emission treatment system of claim 1, further comprising a slip oxidation catalyst downstream of the catalyst article. 6. The emission treatment system of claim 1, wherein the base metal selected from copper and iron is present in an amount of from about 1 to 5 percent by weight of the total weight of base metal plus zeolite. 7. A method for treating emissions produced in an exhaust stream from a diesel engine comprising NOx and particulate matter, the method comprising: (a) passing the exhaust stream through a diesel oxidation catalyst comprising a platinum group metal dispersed on a refractory oxide support such that a portion of NO is oxidized to NO2 to provide an NO2-enriched exhaust stream;(b) metering, at periodic intervals, ammonia or an ammonia precursor into the NO1-enriched exhaust stream using an injector in fluid communication with and downstream of the oxidation catalyst: and(c) subsequently passing the exhaust stream treated with ammonia or an ammonia precursor through a catalyst article such that particulate matter is filtered and a substantial portion of NOx is reduced to N2, the catalyst article comprising a wall flow monolith and a catalytic material contained within the wall flow monolith, wherein the wall flow monolith has a wall porosity of at least 50% and comprises a plurality of longitudinally extending passages formed by longitudinally extending porous wails bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, and wherein the catalytic material comprises a zeolite and a base metal selected from copper and iron present in an amount of from about 0.1 to 30 percent by weight of the total weight of base metal plus zeolite, the zeolite. having pores connected in three dimensions and a silica to alumina ratio of at least about 10, the wall flow monolith having integrated NOx and particulate removal efficiency when exposed to diesel engine exhaust and ammonia or an ammonia precursor. 8. The method of claim 7, wherein step (b) comprises metering urea into the NO2-enriched exhaust stream. 9. The method of claim 7, wherein the base metal selected from copper and iron is present in an amount of from about 1 to 5 percent by weight of the total weight of base metal plus zeolite. 10. The method of claim 7, wherein greater than 80% of the particulate matter is filtered by the catalyst article. 11. The method of claim 7, wherein the catalyst article converts at least 50% of the NOx to N2. 12. The method of claim 7, further comprising the step of regenerating the catalyst article by combustion of soot trapped on the catalyst article, the combustion of soot taking place at a temperature greater than 650° C. 13. The method of claim 7, wherein the exhaust stream contains one or more sulfur components.
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이 특허에 인용된 특허 (76)
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Brand Reinhold (Hanau DEX) Engler Bernd (Hanau DEX) Kleine-Moellhoff Peter (Alzenau DEX) Koberstein Edgar (Alzenau DEX), Method for the catalytic removal of nitrogen oxides from exhaust gases by means of a reducing agent.
Voss Kenneth E. (Somerville NJ) Yavuz Bulent O. (Plainfield NJ) Farrauto Robert J. (Westfield NJ) Galligan Michael P. (Clark NJ), Oxidation catalyst with bulk ceria, a second bulk metal oxide, and platinum.
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