초록

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Abstract ▼ AI-Helper

The purpose of this study was to elucidate the chemical changes and formation of sulfur minerals following reduction and subsequent oxidation of the acid sulfate soils derived from the fluvio-marine plains in Gimhae area. Changes in pH, Eh and water soluble $SO_4$, Fe, Al, K, na and Ca we...

The purpose of this study was to elucidate the chemical changes and formation of sulfur minerals following reduction and subsequent oxidation of the acid sulfate soils derived from the fluvio-marine plains in Gimhae area. Changes in pH, Eh and water soluble $SO_4$, Fe, Al, K, na and Ca were determined in the soil under the reduced and oxidized conditions. These chemical properties were related to the formation of the pyrite and jarosite, the major sulfur minerals in the acid sulfate soils. On incubation, suspension pH tended to increase with decreaseing Eh in the reduction periods. Jarosite formation was favored by maintaining continuous low pH(below 4.0) and high Eh(above 400mV) during the oxidation periods, however, the conditions were not favorable for the soils with $Ca(OH)_2$. Water soluble K increased by reduction but decreased by oxidation, while the jarosite of the soil with $Ca(OH)_2$ was dissolved even under the oxidation conditon, resulting in rapid increase of water soluble K. The water soluble Ca decreased rapidly, indicating that gypsum was formed with $Ca(OH)_2$ during the oxidation periods. The formation of jarosite was favored by the oxidation condition, and hindered by the reduction condition. But the formation of pyrite was favored by reduction and hindered by oxidation. When the troll was treated with $Ca(OH)_2$, Jarosite was dissolved in both oxidized and reduced conditions.