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소면적 재배작물의 농약 잔류성 시험 후 작물 그룹화를 통한 외삽적용
An Extrapolation from Crop Classifications Based on Pesticide Residues Trial Data within Vegetables in Minor Crops 원문보기

농약과학회지 = The Korean journal of pesticide science, v.13 no.1, 2009년, pp.28 - 38  

박종혁 (전남대학교 응용생물공학부) ,  최정희 (전남대학교 응용생물공학부) ,  임건재 (농촌진흥청 농업과학기술원) ,  오창환 (세명대학교 한방식품영양학부) ,  심재한 (전남대학교 응용생물공학부)

초록
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Bifenthrin, chlorothalonil, cypermethrin, diazinon, fenvalerate, phenthoate 및 procymidone 등 7종의 농약에 대한 잔류시험을 통해 외삽적용을 위한 연구를 실시하였다. 실험을 위해 소면적 재배작물 중 잔류농약 부적합 사례가 많은 작물을 중심으로 11종의 엽채류, 5종의 근채류, 그리고 6종의 경채류를 포함한 총 22종의 작물을 선정하여 재배한 후 7종의 농약을 각각 처리하여 24시간 경과 시점을 1일로 하여 1, 3, 5, 7 일차에 수확하여 분석하였다. 실험결과 회수율은 엽채류는 $72.0{\sim}117.0%$, 경채류는 $81.3{\sim}105.0%$, 그리고 근채류는 $70.1{\sim}108.1%$ 수준이었고 검출한계는 엽채류는 0.005-0.1 mg/kg, 경채류와 근채류는 0.001-0.005mg/kg 수준이었다. 농약의 감소경향과 작물의 표면 형태학적 차이에 의한 농약 잔류특성을 파악 비교하여 선정된 작물을 고잔류군과 저잔류군으로 그룹화하였고 이 내용을 바탕으로 대상 농약들에 대하여 경채류 및 근채류 작물을 대상으로 농약데이터의 외삽을 통한 안전사용기준 및 MRL의 설정이 가능할 것으로 판단된다.

Abstract AI-Helper 아이콘AI-Helper

An extrapolation of residue data of seven commonly used pesticides namely bifenthrin, chlorothalonil, cypermethrin, diazinon, fenvalerate, phenthoate and procymidone on a total of 22 minor crops has been carried out in an experimental field trial. The pesticides were applied to 11 leafy-, 5 root- an...

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제안 방법

  • All the crops were classified into two groups called 'high residue' and Tow residue5 according to the dissipation rates of pesticides residues by 50% windows in each crops collected at oy 7 day after application. Crown daisy, Korean lettuce, geumgangcho, whorled mallow and chicory were of high residual group.
  • In this study in order to classify the crops into high and low residual group, we have calculated the percent residual ratio of each pesticide using the residue values obtained and the active ingredient present in the commercial products. Because the crop classifications are generally done by the dissipation pattern of pesticides on the agricultural commodities as the active ingredients are different from each other in the commercial formulations.
  • out successfully. It could be concluded from the result obtained in this study that, it might be possible to extrapolate residual data of stem-crops from the data of root-crops within same group and that crops that have currently no registered pesticide for use, would be possible to use the pesticides which are already been registered for the similar crops combining the information about the morphology, growth characteristic, residual trial data, crop processing factor, and Acceptable Daily Intake (ADI).
  • In case of procymidone, the calculation was done separately as it has a systemic action. The percent residual ratios of all pesticides in each crop were calculated at 1, 3, 5, and 7 day after spraying. The results are shown in Table 4 and 5 which shows that the residues of the applied pesticides in all crops were found to be lower than MRL values at seven day after treatment.
  • The spraying concentrations and other information are given in the Table 2. The samples were collected randomly at 1, 3, 5 and 7 days after pesticide plication. After harvesting, collected samples were chopped immediately, mixed, packed separately in plastic bags, labeled and stored at -20℃ until analysis.
  • The samples were allowed to stand for 30 min prior to extraction following the same procedure described for the real samples. Three replicate analyses for each concentration were carried out.

대상 데이터

  • A total of 22 agricultural crops were selected for present study and divided into eleven leafy-, five root and six stem-crops based on the shape of agricultural products and specific pesticide residues given by Korea Food and Drug Administration (KFDA) and from the result of pesticide residue monitoring in Agricultural Products in 2005 from the National Agricultural Products Quality Management (NAQS), Gwangju, Republic of Korea (Table 1).
  • All the selected crops were grown in the in-house experimental farm/green houses of the College of Agricultural and Life Science, Chonnam National University, Gwangju, Republic of Korea. Leafy crops were sown in a dry field dropwort in a green house on a plot measuring 0.

이론/모형

  • The samples were extracted by following the method "Korea Food Code No. 83" described in the guidebook by KFDA (2005). A 20-g representative sample of each leafy crop was homogenized with 50 mL acetonitrile for three minutes by a high-speed homogenizer (WiseMix™ HG-150, Daihan Scientific, Korea).
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