[논문]Influence of Extender Oil on Properties of Solution Styrene-Butadiene Rubber Composites

Choi, Sung-Seen; Ko, Eunah

doi:10.7473/ec.2015.50.3.196

Influence of Extender Oil on Properties of Solution Styrene-Butadiene Rubber Composites 원문보기

Elastomers and composites = 엘라스토머 및 콤포지트, v.50 no.3, 2015년, pp.196 - 204

Choi, Sung-Seen (Department of Chemistry, Sejong University) , Ko, Eunah (Department of Chemistry, Sejong University)

Abstract ▼ AI-Helper

Crosslink density of a rubber vulcanizate determines the chemical and physical properties, while bound rubber is an important factor to estimate reinforcement of a filled rubber compound. Extender oil is added to a raw rubber with very high molecular weight for improving processability of a rubber composite. Influence of extender oil on crosslink density, bound rubber formation, and physical properties of solution styrene-butadiene rubber (SSBR) composites with differing microstructures was investigated. Crosslink densities of non-oil-extended SSBR (NO-SSBR) vulcanizates were higher than those of oil-extended SSBR (OE-SSBR) ones. Bound rubber contents of NO-SSBR compounds were also greater than those of OE-SSBR ones. The experimental results could be explained by interfering of extender oil. The OE-SSBR vulcanizates had low modulus but long elongation at break, whereas the NO-SSBR ones had high modulus but short elongation at break. It was found that the crosslink densities affected the physical properties more than the bound rubber contents. The moduli increased with increase in the crosslink density irrespective of extender oil, while the elongation at break decreased. Each variation of the tensile strengths of NO-SSBR and OE-SSBR vulcanizates with the crosslink density showed a decreasing trend. Tear strength of the OE-SSBR vulcanizate increased with increase in the crosslink density, whereas variation of the tear strength of NO-SSBR vulcanizate with the crosslink density showed a weak decreasing trend.

주제어

AI 본문요약
AI-Helper

* AI 자동 식별 결과로 적합하지 않은 문장이 있을 수 있으니, 이용에 유의하시기 바랍니다.

가설 설정

Figure 10 shows the modulus variations with the core shell bound rubber content, and it shows a good relationship. There is one specific trend in Figure 10. The moduli on the whole increase with increase in the core shell bound rubber content. This indicates that the core shell bound rubber content influences the moduli.

참고문헌 (55)

G. R. Cotton, "Mixing of carbon black with rubber I. Measurement of dispersion rate by changes in mixing torque", Rubber Chem. Technol., 57, 118 (1984).

상세보기
S. Wolff and U. Gorl, "The influence of modified carbon-blacks on viscoelastic compound properties", Kautsch. Gummi Kunstst., 44, 941 (1991).
T. C. Gruber and C. R. Herd, "Anisometry measurements in carbon black aggregate populations", Rubber Chem. Technol., 70, 727 (1997).

상세보기
A. K. Ghosh and B. Adhikari, "Reinforcing properties of a modified carbon black in NR and in an NR-NBR blend", Kautsch. Gummi Kunstst., 52, 681 (1999).
S. Wolff and M.-J. Wang, "Filler-elastomer interactions. Part IV. The effect of the surface energies of fillers on elastomer reinforcement", Rubber Chem. Technol., 65, 329 (1992).

상세보기
S.-S. Choi, "Filler-polymer interactions in both silica and carbon black-filled styrene-butadiene rubber compounds", J. Polym. Sci.: Part B: Polym. Phys., 39, 439 (2001).
S.-S. Choi, "Influence of polymer-filler interactions on retraction behaviors of natural rubber vulcanizates reinforced with silica and carbon black", J. Appl. Polym. Sci., 99, 691 (2006).

상세보기
S.-S. Choi and J.-C. Kim, "Thermal aging behaviors of weather resistant rubber composites of EPDM, IIR, and BIIR", Elast. Compos., 47, 148 (2012).

원문보기 상세보기
Y. Kim and S.-S. Choi, "Microstructural analysis of SBR blends using infrared spectroscopy", Elast. Compos., 49, 103 (2014).

원문보기 상세보기
S.-H. Jang, W.-S. Kim, Y.-G. Kang, M.-H. Han, and S.-M. Chang, "Study on mixing condition of the rubber composite containing functionalized S-SBR, silica and silane: II. Effect of mixing temperature and time", Elast. Compos., 48, 103 (2013).

원문보기 상세보기
S.-H. Jang, W.-S. Kim, Y.-G. Kang, M.-H. Han, and S.-M. Chang, "Study on mixing condition of the rubber composite containing functionalized S-SBR, silica and silane: I. Effect of mixing temperature", Elast. Compos., 48, 94 (2013).

원문보기 상세보기
J. H. Shin, A. M. Shanmugharaj, P. C. Lee, S. K. Jeoung, and S. H. Ryu, "Properties of SBR compound using silica-graphite dual phase filler", Elast. Compos., 49, 66 (2014).

원문보기 상세보기
D.-H. Kim and S. Kaang, "Determination of abrasion rate of SBR rubber compounds using a knife-blade abrader", Elast. Compos., 49, 149 (2014).

원문보기 상세보기
Y.-C. Ou, Z.-Z. Yu, A. Vidal, and J. B. Donnet, "Effects of alkylation of silica filler on rubber reinforcement", Rubber Chem. Technol., 67, 834 (1994).

상세보기
Y. Li, M. J. Wang, T. Zhang, F. Zhang, and X. Fu, "Study on Dispersion Morphology of Silica in Rubber", Rubber Chem. Technol., 67, 693 (1994).

상세보기
Choi, S.-S. "Improvement of filler dispersion in silica-filled styrene-butadiene rubber compounds using low molecular weight polybutadiene treated with maleic anhydride", Elastomer, 41, 10 (2006).
E. Ko and S.-S. Choi, "Characterization and formation of chemical bonds of silica-coupling agent-rubber", Elast. Compos., 49, 239 (2014).

원문보기 상세보기
S. Wolff, U. Gorl, M. J. Wang, and W. Wolff, "Silane modified silicas", Eur. Rubber J., 16, 16 (1994).
W. J. Kern and S. Futamura, "Effect of tread polymer structure on tyre performance Effect of tread polymer structure on tyre performance Effect of tread polymer structure on tyre performance Effect of tread polymer structure on tyre performance", Polymer, 29, 1801 (1988).

상세보기
S. Wolff, "Chemical aspects of rubber reinforcement by fillers", Rubber Chem. Technol., 69, 325 (1996).

상세보기
M.-J. Wang, P. Zhang, and K. Mahmud, "Carbon-silica dual phase filler, a new generation reinforcing agent for rubber: Part IX. Application to truck tire tread compound", Rubber Chem. Technol., 74, 124 (2001).

상세보기
J. T. Byers, "Fillers for balancing passenger tire tread properties", Rubber Chem. Technol., 75, 527 (2002).

상세보기
S.-S. Choi, I.-S. Kim, and C.-S. Woo, "Influence of TESPT content on crosslink types and rheological behaviors of natural rubber compounds reinforced with silica", J. Appl. Polym. Sci., 106, 2753 (2007).

상세보기
N. J. Morrison and M. Porter, "Temperature effects on the stability of intermediates and crosslinks in sulfur vulcanization", Rubber Chem. Technol., 57, 63 (1984).

상세보기
A. Y. Coran, "Vulcanization: Conventional and dynamic", Rubber Chem. Technol., 68, 351 (1995).

상세보기
A. Mousa and J. Karger-Kocsis, "Rheological and thermodynamical behavior of styrene/butadiene rubber-organoclay nanocomposites", Macromol. Mater. Eng., 286, 260 (2001).
M. Jacoba, S. Thomasa, and K. T. Varughese, "Mechanical properties of sisal/oil palm hybrid fiber reinforced natural rubber composites", Compos. Sci. Technol., 64, 955 (2004).

상세보기
P. B. Stickney and R. D. Falb, "Carbon black-rubber interactions and bound rubber", Rubber Chem. Technol., 37, 1299 (1964).

상세보기
G. Kraus, "Reinforcement of elastomers by carbon black", Adv. Polym. Sci., 8, 155 (1971).
C. M. Blow, "Polymer/particulate filler interaction - the bound rubber phenomena Polymer/particulate filler interaction - the bound rubber phenomenaPolymer/particulate filler interaction - the bound rubber phenomena Polymer/particulate filler interaction - the bound rubber phenome", Polymer, 14, 309 (1973).

상세보기
E. M. Dannberg, "Bound rubber and carbon black reinforcement", Rubber Chem. Technol., 59, 512 (1986).

상세보기
S. Wolff, M.-J. Wang, and E.-H. Tan, "Improved quantitative determination of elastomers in tire rubber by kinetic simulation of DTG curves", Rubber Chem. Technol., 66, 163 (1993).

상세보기
A. I. Medalia, "Morphology of aggregates: VI. Effective volume of aggregates of carbon black from electron microscopy; Application to vehicle absorption and to die swell of filled rubber", J. Colloid Interface Sci., 32, 115 (1970).
G. Kraus, "A carbon black structure-concentration equivalence principle. Application to stress-strain relationships of filled rubbers", Rubber Chem. Technol., 44, 199 (1971).

상세보기
P. P. A. Smit, "Glass transition in carbon black reinforced rubber", Rubber Chem. Technol., 41, 1194 (1968).

상세보기
I. Pliskin and N. Tokita, "Bound rubber in elastomers: Analysis of elastomer-filler interaction and its effect on viscosity and modulus of composite systems", J. Appl. Polym. Sci., 16, 473 (1972).

상세보기
J. O'Brien, E. Cashell, G. E. Wardell, and V. J. McBrierty, "An NMR investigation of the interaction between carbon black and cis-polybutadiene", Macromolecules, 9, 653 (1976).

상세보기
A. L. Gal, X. Yang, and M. Kluppel, "Evaluation of sliding friction and contact mechanics of elastomers based on dynamic-mechanical analysis", J. Chem. Phys., 123, 014704 (2005).

상세보기
J. L. Leblanc, "Elastomer-filler interactions and the rheology of filled rubber compounds", J. Appl. Polym. Sci., 78, 1541 (2000).

상세보기
J. L. Leblanc, "Rubber-filler interactions and rheological properties in filled compounds", Prog. Polym. Sci., 27, 627 (2002).

상세보기
J. Leopoldes, C. Barres, J. L. Leblanc, and P. Georget, "Influence of filler-rubber interactions on the viscoelastic properties of carbon-black-filled rubber compounds", J. Appl. Polym. Sci., 91, 577 (2004).

상세보기
S.-S. Choi and E. Ko, "Novel test method to estimate bound rubber formation of silica-filled solution styrene-butadiene rubber compounds", Polym. Test., 40, 170 (2014).

상세보기
E. Ardrizzi and R. Vivirito, "Rubber processing or and rubber products containing it", US Patent No. 05504135 (1996).
C. Flanigan, L. Beyer, D. Klekamp, D. Rohweder, and D. Haakenson, "Using bio-based plasticizers, alternative rubber", Rubber & Plastics News, Feb. 11, 15 (2013).
S. S. Fernandez and S. Kunchandy, "Effect of nano $CaCO_3$ as a filler and linseed oil as an extender on the cure and mechanical properties of natural rubber vulcanizates", Orient. J. Chem., 29, 219 (2013).
S. Mishra and N. G. Shimpi, "Mechanical and flame-retarding properties of styrene-butadiene rubber filled with nano- $CaCO_3$ as a filler and linseed oil as an extender", J. Appl. Polym. Sci., 98, 2563 (2005).

상세보기
S.-S. Choi and D.-H. Han, "Strain effect on recovery behaviors from circular deformation of natural rubber vulcanizate", J. Appl. Polym. Sci., 114, 935 (2009).

상세보기
S.-S. Choi and J.-C. Kim, "Lifetime prediction and thermal aging behaviors of SBR and NBR composites using crosslink density changes", J. Ind. Eng. Chem., 18, 1166 (2012).

상세보기
S.-S. Choi, H.-M. Kwon, Y. Kim, J. W. Bae, and J.-S. Kim, "Characterization of maleic anhydride-grafted ethylene-propylene-diene terpolymer (MAH-g-EPDM) based thermoplastic elastomers by formation of zinc ionomer", J. Ind. Eng. Chem., 19, 1990 (2013).

상세보기
P. J. Flory, "Statistical mechanics of swelling of network structures", J. Chem. Phys., 18, 108 (1950).

상세보기
J. S. Deng and A. I. Isayev, "Injection molding of rubber compounds: Experimentation and simulation", Rubber Chem. Technol., 64, 296 (1991).

상세보기
A. J. Marzocca, "Evaluation of the polymer-solvent interaction parameter $\chi$ for the system cured styrene butadiene rubber and toluene", Eur. Polym. J., 43, 2682 (2007).

상세보기
S.-S. Choi, "Influence of storage time and temperature and silane coupling agent on bound rubber formation in filled styrene-butadiene rubber compounds", Polym. Test., 21, 201 (2002).

상세보기
S.-S. Choi, "Difference in bound rubber formation of silica and carbon black with styrene-butadiene rubber", Polym. Adv. Technol., 13, 466 (2002).

상세보기
S.-S. Choi, K.-J. Hwang, and B.-T. Kim, "Influence of bound polymer on cure characteristics of natural rubber compounds reinforced with different types of carbon blacks", J. Appl. Polym. Sci., 98, 2282 (2005).

상세보기

저자의 다른 논문 :

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증