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The thermal decomposition and flame inhibition behaviors of poly(1,4-cyclohexylene dimethylene terephthalate) (PCT) with aluminum phosphinate as flame retardant were investigated. The thermal decomposition behaviors of various formulations were studied using thermogravimetric analysis, and chemical ...

The thermal decomposition and flame inhibition behaviors of poly(1,4-cyclohexylene dimethylene terephthalate) (PCT) with aluminum phosphinate as flame retardant were investigated. The thermal decomposition behaviors of various formulations were studied using thermogravimetric analysis, and chemical analysis was carried out for the residues using FTIR. We found that the action of AlPi was based mainly on the flame inhibition effect in the gas-phase and showed only a limited contribution from the condensed-phase mode of action through the formation of aluminum phosphate in the solid state. A UL-94 V-0 rating was achieved by using a PCT formulation containing 11 phr of AlPi, and a noticeable reduction in the cone calorimeter experiment was observed in this sample.

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