Mardani, Zahra
(Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
,
Golsanamlou, Vali
(Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
,
Jabbarzadeh, Zahra
(Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
,
Moeini, Keyvan
(Chemistry Department, Payame Noor University,)
,
Carpenter-Warren, Cameron
(EaStCHEM School of Chemistry, University of St Andrews)
,
Slawin, Alexandra M.Z.
(EaStCHEM School of Chemistry, University of St Andrews)
,
Woollins, J. Derek
(EaStCHEM School of Chemistry, University of St Andrews)
A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$$\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elem...
A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$$\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.
A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$$\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.
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제안 방법
71075 Å) was used for all the compounds and intensity data were collected using ω steps accumulating area detector images spanning at least a hemisphere of reciprocal space. All data were corrected for Lorentz polarization effects. A multiscan absorption correction was applied by using CrystalClear7 or CrysAlisPro.
In this work, a new coordination polymer, 1D-{Cu(μ-picolinato)2}n (1), was synthesized in a reaction between AEPC and copper(II) halides and its spectral (IR, UV-Vis, 1 H NMR) and structural (single crystal X-ray diffraction) properties were investigated.
참고문헌 (24)
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