[논문]전기화학적 방법을 통한 금속 유기 골격체 합성

문상현; 김지영; 최현국; 김문갑; 이영세; 이기영

doi:10.14478/ace.2021.1036

전기화학적 방법을 통한 금속 유기 골격체 합성
Electrochemical Synthesis of Metal-organic Framework 원문보기

공업화학 = Applied chemistry for engineering, v.32 no.3, 2021년, pp.229 - 236

문상현 (경북대학교 미래과학기술융합학과) , 김지영 (경북대학교 나노소재공학부) , 최현국 (경북대학교 나노소재공학부) , 김문갑 (경북대학교 나노소재공학부) , 이영세 (경북대학교 나노소재공학부) , 이기영 (경북대학교 미래과학기술융합학과)

초록
AI-Helper

금속 유기 골격체는 최근 20년간 센서, 촉매, 에너지 저장과 같은 많은 응용분야에서 관심을 받아온 물질이다. 이 물질을 합성하기 위해 수열 합성, 유기용매열과 같은 합성법이 제시되어 왔으나, 그 공정이 복잡하면서 고비용·장시간이 소요된다는 문제점이 제기되어 왔다. 이를 해결하기 위한 전기화학적 합성법이 새롭게 제시되었는데, 간단한 준비절차와 특정한 온도·압력 조건 없이 합성할 수 있어 기존 합성법의 단점을 보완한다는 특징이 있다. 이에 본 총설논문에서는 전기화학적으로 합성 가능한 금속 유기 골격체의 종류와 전기화학적 합성 메커니즘을 다루고 있다. 전기화학적 합성법을 통해 형성된 금속 유기 골격체를 적용한 응용분야 연구동향을 정리하였다.

Abstract ▼ AI-Helper

During the last two decades, metal-organic frameworks (MOFs) have been drawn attention due to their high specific surface area, porosity, and catalytic activities that allow to use in many applications such as sensor, catalysis, energy storage, etc. To synthesize MOFs hydrothermal or solvothermal method were generally used. However, these methods require high-cost equipment and long time-spend for the synthesis with multi-step process. In contrast, electrochemical synthesis has been considered as a simple and easy process under the ambient conditions. In this review, we described the mechanism of electrochemical MOFs synthesis by the number of configured electrodes system, with the recent reports of various applications.

주제어

표/그림 (6)

그림 Figure 1. Schematic diagram of the metal-organic framework synthesis process of (a) hydrothermal · solvothermal and (b) electrochemical method.
표 Table 1. Electrochemical Synthesis of Metal-organic Framework Reported in Recent 5 Years
그림 Figure 2. (a) Scheme of two-electrode configuration for the electrochemical synthesis of metal-organic framework. (b) Schematic diagram of electrochemical metal-organic framework synthesis in the two-electrode configuration condition. (c) Suggested anodic electrodeposition synthesis mechanism of metal-organic framework and (i~iv) FE-SEM images. Reproduced with permission from ref. [38]. Copyright 2016, the Royal Society of Chemistry.
그림 Figure 3. Schematic diagram of electrochemical conversion synthesis mechanism from Cu nanowires to core-shell Cu₃(BTC)₂ nanowires.
그림 Figure 4. (a) Schematic diagram of three-electrode configuration for the electrochemical synthesis of metal-organic framework and (b) cathodic electrochemical synthesis towards metal-organic frameworks. (c) FE-SEM image of cathodic electrodeposited crystalline MOF-5. Reproduced with permission from ref. [42]. Copyright 2015, the American Chemical Society. (d) PXRD patterns of various electrochemically synthesized MOFs, comparing with calculated XRD pattern of MOF-5. Reproduced with permission from ref. [42]. Copyright 2015, the American Chemical Society.
그림 Figure 5. (a) (i) Comparing fluorescence intensity of UiO-66-NH₂ with different metal ions. (ii) Fluorescence emission spectra of UiO-66-NH₂ from 0 to 1 × 10^-3 mol L^-1 concentration of Fe³⁺. Reproduced with permission from ref. [7]. Copyright 2019, the American Chemical Society. (b) (i) LSV curves, (ii) Tafel plots, and (iii) overall comparison of various electrochemical deposited (ECD) Ni, Fe based MOFs. Reproduced with permission from ref. [52]. Copyright 2016, the American Chemical Society. (c) (i) CV and (ii) GCD curves of Ni-MOFs. Reproduced with permission from ref. [55]. Copyright 2020, the Institute of Physics.

참고문헌 (67)

F. A. A. Paz, J. Klinowski, S. M. F. Vilela, J. P. C. Tome, J. A. S. Cavaleiro, and J. Rocha, Ligand design for functional metal-organic frameworks, Chem. Soc. Rev., 41, 1088-1110 (2012).

상세보기
C. K. Brozek and M. Dinca, Cation exchange at the secondary building units of metal-organic frameworks, Chem. Soc. Rev., 43, 5456-5467 (2014).

상세보기
H. Furukawa, K. E. Cordova, M. O'Keeffe, and O. M. Yaghi, The chemistry and applications of metal-organic frameworks, Science, 341, 123044 (2013).
E. A. Tomic, Thermal stability of coordination polymers, J. Appl. Polym. Sci., 9, 3745-3752 (1965).
O. M. Yaghi, G. Li, and H. Li, Selective binding and removal of guests in a microporous metal-organic framework, Nature, 378, 703-706 (1995).

상세보기
H. Li, M. Eddaoudi, M. O'Keeffe, and O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, 402, 276-279 (1999).

상세보기
J.-Z. Wei, F.-X. Gong, X.-J. Sun, Y. Li, T. Zhang, X.-J. Zhao, and F.-M. Zhang, Rapid and low-cost electrochemical synthesis of UiO-66-NH2 with enhanced fluorescence detection performance, Inorg. Chem., 58, 6742-6747 (2019).

상세보기
H. Furukawa, N. Ko, Y.B. Go, N. Aratani, S. B. Choi, E. Choi, A. O. Yazaydin, R. Q. Snurr, M. O'Keeffe, J. Kim, and O. M. Yaghi, Ultrahigh porosity in metal-organic frameworks, Science, 329, 424-428 (2010).

상세보기
J. Lei, R. Qian, P. Ling, L. Cui, and H. Ju, Design and sensing applications of metal-organic framework composites, Trends Anal. Chem., 58, 71-78 (2014).
Y. Cui, B. Chen, and G. Qian, Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications, Coord. Chem. Rev., 273, 76-86 (2014).

상세보기
S. Achmann, G. Hagen, J. Kita, I.M. Malkowsky, C. Kiener, and R. Moos, Metal-organic frameworks for sensing applications in the gas phase, Sensors, 9, 1574-1589 (2009).

상세보기
J. L. Wang, C. Wang, and W. Lin, Metal-organic frameworks for light harvesting and photocatalysis, ACS Catal., 2, 2630-2640 (2012).

상세보기
M. A. Nasalevich, M. Van Der Veen, F. Kapteijn, and J. Gascon, Metal-organic frameworks as heterogeneous photocatalysts: Advantages and challenges, CrystEngComm, 16, 4919-4926 (2014).

상세보기
M. A. Nasalevich, M. G. Goesten, T. J. Savenije, F. Kapteijn, and J. Gascon, Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis, Chem. Commun., 49, 10575-10577 (2013).
A. Morozan and F. Jaouen, Metal organic frameworks for electrochemical applications, Energy Environ. Sci., 5, 9269-9290 (2012).

상세보기
J. Yang, P. Xiong, C. Zheng, H. Qiu, and M. Wei, Metal-organic frameworks: A new promising class of materials for a high performance supercapacitor electrode, J. Mater. Chem. A, 2, 16640-16644 (2014).

상세보기
N. Campagnol, R. Romero-Vara, W. Deleu, L. Stappers, K. Binnemans, D.E. De Vos, and J. Fransaer, A hybrid supercapacitor based on porous carbon and the metal-organic framework MIL-100 (Fe), ChemElectroChem, 1, 1182-1188 (2014).

상세보기
K. F. Babu, M. A. Kulandainathan, I. Katsounaros, L. Rassaei, A. D. Burrows, P. R. Raithby, and F. Marken, Electrocatalytic activity of basolite TM F300 metal-organic-framework structures, Electrochem. Commun., 12, 632-635 (2010).

상세보기
J. R. Li, J. Sculley, and H. C. Zhou, Metal-organic frameworks for separations, Chem. Rev., 112, 869-932 (2012).
S. Ma and H. C. Zhou, Gas storage in porous metal-organic frameworks for clean energy applications, Chem. Commun., 46, 44-53 (2010).
R. Sabouni, H. Kazemian, and S. Rohani, Carbon dioxide capturing technologies: A review focusing on metal organic framework materials (MOFs), Environ. Sci. Pollut. Res., 21, 5427-5449 (2014).

상세보기
S. Couck, J.F.M. Denayer, G. V. Baron, T. Remy, J. Gascon, and F. Kapteijn, An amine-functionalized MIL-53 metal-organic framework with large separation power for CO 2 and CH 4 , J. Am. Chem. Soc., 131, 6326-6327 (2009).
J. Liu, L. Chen, H. Cui, J. Zhang, L. Zhang, and C. Y. Su, Applications of metal-organic frameworks in heterogeneous supramolecular catalysis, Chem. Soc. Rev., 43, 6011-6061 (2014).

상세보기
J. Gascon, A. Corma, F. Kapteijn, and F. X. Llabres I Xamena, Metal organic framework catalysis: Quo vadis?, ACS Catal., 4, 361-378 (2014).

상세보기
T. Zhang and W. Lin, Metal-organic frameworks for artificial photosynthesis and photocatalysis, Chem. Soc. Rev., 43, 5982-5993 (2014).

상세보기
Y. Li, C. Chen, X. Sun, J. Dou, and M. Wei, Metal-organic frameworks at interfaces in dye-sensitized solar cells, ChemSusChem, 7, 2469-2472 (2014).

상세보기
M. Zhang, Z. Y. Gu, M. Bosch, Z. Perry, and H. C. Zhou, Biomimicry in metal-organic materials, Coord. Chem. Rev., 293, 327-356 (2015).

상세보기
J. Della Rocca, D. Liu, and W. Lin, Nanoscale metal-organic frameworks for biomedical imaging and drug delivery, Acc. Chem. Res., 44, 957-968 (2011).

상세보기
Y. Liu, Z. Ng, E. A. Khan, H. K. Jeong, C. bun Ching, and Z. Lai, Synthesis of continuous MOF-5 membranes on porous α-alumina substrates, Microporous Mesoporous Mater., 118, 296-301 (2009).
J. R. Li, R. J. Kuppler, and H. C. Zhou, Selective gas adsorption and separation in metal-organic frameworks, Chem. Soc. Rev., 38, 1477-1504 (2009).

상세보기
O. Shekhah, H. Wang, D. Zacher, R. A. Fischer, and C. Woll, Growth mechanism of metal-organic frameworks: Insights into the nucleation by employing a step-by-step route, Angew. Chem. Int. Ed., 48, 5038-5041 (2009).
O. Shekhah, H. Wang, M. Paradinas, C. Ocal, B. Schupbach, A. Terfort, D. Zacher, R. A. Fischer, and C. Woll, Controlling interpenetration in metal-organic frameworks by liquid-phase epitaxy, Nat. Mater., 8, 481-484 (2009).

상세보기
X.-L. Liu, Y.-S. Li, G.-Q. Zhu, Y.-J. Ban, L.-Y. Xu, and W.-S. Yang, An organophilic pervaporation membrane derived from metal-organic framework nanoparticles for efficient recovery of bio-alcohols, Angew. Chem., 123, 10824-10827 (2011).

상세보기
F. Zhang, X. Zou, W. Feng, X. Zhao, X. Jing, F. Sun, H. Ren, and G. Zhu, Microwave-assisted crystallization inclusion of spiropyran molecules in indium trimesate films with antidromic reversible photochromism, J. Mater. Chem., 22, 25019-25026 (2012).

상세보기
A. Schoedel, C. Scherb, and T. Bein, Oriented nanoscale films of metal-organic frameworks by room-temperature gel-layer synthesis, Angew. Chem.., 122, 7383-7386 (2010).

상세보기
I. Stassen, M. Styles, G. Grenci, H. Van Gorp, W. Vanderlinden, S. De Feyter, P. Falcaro, D. De Vos, P. Vereecken, and R. Ameloot, Chemical vapour deposition of zeolitic imidazolate framework thin films, Nat. Mater., 15, 304-310 (2016).

상세보기
T. R. C. Van Assche, G. Desmet, R. Ameloot, D. E. De Vos, H. Terryn, and J. F. M. Denayer, Electrochemical synthesis of thin HKUST-1 layers on copper mesh, Microporous Mesoporous Mater., 158, 209-213 (2012).
N. Campagnol, T. R. C. Van Assche, M. Li, L. Stappers, M. Dinca, J. F. M. Denayer, K. Binnemans, D. E. De Vos, and J. Fransaer, On the electrochemical deposition of metal-organic frameworks, J. Mater. Chem. A., 4, 3914-3925 (2016).

상세보기
F. Caddeo, R. Vogt, D. Weil, W. Sigle, M. E. Toimil-Molares, and A. W. Maijenburg, Tuning the size and shape of nanoMOFs via templated electrodeposition and subsequent electrochemical oxidation, ACS Appl. Mater. Interfaces., 11, 25378-25387 (2019).

상세보기
W. W. Lestari, R. E. Nugraha, I. D. Winarni, M. Adreane, and F. Rahmawati, Optimization on electrochemical synthesis of HKUST-1 as candidate catalytic material for green diesel production, AIP Conf. Proc., American Institute of Physics Inc., 020038 (2016).
M. Li and M. Dinca, Reductive electrosynthesis of crystalline metal-organic frameworks, J. Am. Chem. Soc., 133, 12926-12929 (2011).

상세보기
M. Li and M. Dinca, On the mechanism of MOF-5 formation under cathodic bias, Chem. Mater., 27, 3203-3206 (2015).

상세보기
D. J. Tranchemontagne, J. L. Tranchemontagne, M. O'keeffe, and O. M. Yaghi, Secondary building units, nets and bonding in the chemistry of metal-organic frameworks, Chem. Soc. Rev., 38, 1257- 1283 (2009).

상세보기
J. R. Long and O. M. Yaghi, The pervasive chemistry of metal-organic frameworks, Chem. Soc. Rev., 38, 1213-1214 (2009).

상세보기
M. Li and M. Dinca, Selective formation of biphasic thin films of metal-organic frameworks by potential-controlled cathodic electrodeposition, Chem. Sci., 5, 107-111 (2014).

상세보기
G. Zhao, X. Sun, L. Zhang, X. Chen, Y. Mao, and K. Sun, A self-supported metal-organic framework derived Co3O4 film prepared by an in-situ electrochemically assistant process as Li ion battery anodes, J. Power Sources., 389, 8-12 (2018).

상세보기
J. L. Du, X. Y. Zhang, C. P. Li, J. P. Gao, J. X. Hou, X. Jing, Y. J. Mu, and L. J. Li, A bi-functional luminescent Zn(II)-MOF for detection of nitroaromatic explosives and Fe 3+ ions, Sens. Actuators, B Chem., 257, 207-213 (2018).

상세보기
L. Wang, Z. Q. Yao, G. J. Ren, S. De Han, T. L. Hu, and X. H. Bu, A luminescent metal-organic framework for selective sensing of Fe 3+ with excellent recyclability, Inorg. Chem. Commun., 65, 9-12 (2016).

상세보기
S. Pal and P. K. Bharadwaj, A luminescent terbium MOF containing hydroxyl groups exhibits selective sensing of nitroaromatic compounds and Fe(III) ions, Cryst. Growth Des., 16, 5852-5858 (2016).

상세보기
P. Hu, X. Zhu, X. Luo, X. Hu, and L. Ji, Cathodic electrodeposited Cu-BTC MOFs assembled from Cu(II) and trimesic acid for electrochemical determination of bisphenol A, Microchim. Acta, 187, 1-9 (2020).
P. Arul, N. S. K. Gowthaman, S. A. John, and M. Tominaga, Tunable electrochemical synthesis of 3D nucleated microparticles like Cu-BTC MOF-carbon nanotubes composite: Enzyme free ultrasensitive determination of glucose in a complex biological fluid, Electrochim. Acta, 354, 136673 (2020).

상세보기
L. Wang, Y. Wu, R. Cao, L. Ren, M. Chen, X. Feng, J. Zhou, and B. Wang, Fe/Ni metal-organic frameworks and their binder-free thin films for efficient oxygen evolution with low overpotential, ACS Appl. Mater. Interfaces., 8, 16736-16743 (2016).

상세보기
J. Zhao, Y. Wang, J. Zhou, P. Qi, S. Li, K. Zhang, X. Feng, B. Wang, and C. Hu, A copper(II)-based MOF film for highly efficient visible-light-driven hydrogen production, J. Mater. Chem. A, 4, 7174-7177 (2016).

상세보기
S. Jabarian, A. Ghaffarinejad, and H. Kazemi, Electrochemical and solvothermal syntheses of HKUST-1 metal organic frameworks and comparison of their performances as electrocatalyst for oxygen reduction reaction, Anal. Bioanal. Electrochem., 10, 1611-1619 (2018).
W. Cao, Y. Liu, F. Xu, J. Li, D. Li, G. Du, and N. Chen, In situ electrochemical synthesis of Rod-Like Ni-MOFs as battery-type electrode for high performance hybrid supercapacitor, J. Electrochem. Soc., 167, 050503 (2020).

상세보기
N. Campagnol, T. Van Assche, T. Boudewijns, J. Denayer, K. Binnemans, D. De Vos, and J. Fransaer, High pressure, high temperature electrochemical synthesis of metal-organic frameworks: Films of MIL-100 (Fe) and HKUST-1 in different morphologies, J. Mater. Chem. A, 1, 5827-5830 (2013).

상세보기
K. Pirzadeh, A. A. Ghoreyshi, M. Rahimnejad, and M. Mohammadi, Electrochemical synthesis, characterization and application of a microstructure Cu 3 (BTC) 2 metal organic framework for CO 2 and CH 4 separation, Korean J. Chem. Eng., 35, 974-983 (2018).
F. Zhang, T. Zhang, X. Zou, X. Liang, G. Zhu, and F. Qu, Electrochemical synthesis of metal organic framework films with proton conductive property, Solid State Ionics., 301, 125-132 (2017).

상세보기
J. Vehrenberg, M. Vepsalainen, D. S. Macedo, M. Rubio-Martinez, N. A. S. Webster, and M. Wessling, Steady-state electrochemical synthesis of HKUST-1 with polarity reversal, Microporous Mesoporous Mater., 303, 110218 (2020).
T. R. C. Van Assche, N. Campagnol, T. Muselle, H. Terryn, J. Fransaer, and J. F. M. Denayer, On controlling the anodic electrochemical film deposition of HKUST-1 metal-organic frameworks, Microporous Mesoporous Mater., 224, 302-310 (2016).
L. L. Jiang, X. Zeng, M. Li, M. Q. Wang, T. Y. Su, X. C. Tian, and J. Tang, Rapid electrochemical synthesis of HKUST-1 on indium tin oxide, RSC Adv., 7, 9316-9320 (2017).

상세보기
K. Pirzadeh, A. A. Ghoreyshi, M. Rahimnejad, and M. Mohammadi, Optimization of electrochemically synthesized Cu 3 (BTC) 2 by Taguchi method for CO 2 /N 2 separation and data validation through artificial neural network modeling, Front. Chem. Sci. Eng., 14, 233- 247 (2020).
K. Saini, F. Joseph, A. Ramanan, and S. Sharma Bhatia, Electrochemical synthesis of a oxalate-linked copper (II) metal organic frameworks: X-ray crystallographic structure and its magnetic properies, Mater. Today Proc., Elsevier Ltd., 9616-9621 (2017).
S. Jabarian and A. Ghaffarinejad, Electrochemical synthesis of NiBTC metal organic framework thin layer on nickel foam: An efficient electrocatalyst for the hydrogen evolution reaction, J. Inorg. Organomet. Polym. Mater., 29, 1565-1574 (2019).
S. Khazalpour, V. Safarifard, A. Morsali, and D. Nematollahi, Electrochemical synthesis of pillared layer mixed ligand metal-organic framework: DMOF-1-Zn, RSC Adv., 5, 36547-36551 (2015).

상세보기
H. M. Yang, X. Liu, X. L. Song, T. L. Yang, Z. H. Liang, and C. M. Fan, In situ electrochemical synthesis of MOF-5 and its application in improving photocatalytic activity of BiOBr, Trans. Nonferrous Met. Soc. China, 25, 3987-3994 (2015).
R. Wei, H. Y. Chi, X. Li, D. Lu, Y. Wan, C. W. Yang, and Z. Lai, Aqueously cathodic deposition of ZIF-8 membranes for superior propylene/propane separation, Adv. Funct. Mater., 30, 1907089 (2020)

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