[논문]40 wt% Ni 촉매에서 바이오가스 중 CO2로부터 메탄제조에 관한 연구: Commercial Catalyst와의 특성 비교분석

한단비; 백영순

doi:10.7316/khnes.2021.32.5.388

40 wt% Ni 촉매에서 바이오가스 중 CO2로부터 메탄제조에 관한 연구: Commercial Catalyst와의 특성 비교분석
A Study on the Synthesis of CH4 from CO2 of Biogas Using 40 wt% Ni-Mg Catalyst: Characteristic Comparison of Commercial Catalyst and 40 wt% Ni Catalyt 원문보기

한국수소 및 신에너지학회 논문집 = Transactions of the Korean Hydrogen and New Energy Society, v.32 no.5, 2021년, pp.388 - 400

한단비 (수원대학교 환경에너지공학과) , 백영순 (수원대학교 환경에너지공학과)

Abstract ▼ AI-Helper

Power to gas (P2G) is one of the energy storage technologies that can increase the storage period and storage capacity compared to the existing battery type. One of P2G technology produces hydrogen by decomposing water from renewable energy (electricity) and the other produces CH4 by reacting hydrogen with CO2. This study is an experimental study to produce CH4 by reacting CO2 of biogas with hydrogen using a 40 wt% Ni-Mg-Al catalyst and a commercial catalyst. Catalyst characteristics were analyzed through H2-TPR, XRD, and XPS instruments of 40% Ni catalyst and commercial catalyst. The effect on the CO2 conversion rate and CH4 selectivity was analyzed, and the activities of a 40% Ni catalyst and a commercial catalyst were compared. As a result of experiment, In the case of a 40 wt% catalyst, the maximum CO2 conversion rate showed 77% at the reaction temperature of 400℃. Meanwhile, the commercial catalyst showed a maximum CO2 conversion rate of 60% at 450℃. When 50% of CO was added to the CO2 methanation reaction, the CO2 conversion rate was increased by about 5%. This is considered to be due to the atmosphere in which the CO reaction can occur without the process of converting to CH4 after forming carbon and CO as intermediates in terms of the CO2 mechanism on the catalyst surface.

주제어

참고문헌 (39)

G. Wojciech, Z. Witold, S. Grzegorz, S. Andrzej, and K. Agnieszka, "Nickel catalysts supported on silica microspheres for CO2 methanation", Microporous and Mesoporous Materials, Vol. 272, 2018, pp. 79-91, doi: https://doi.org/10.1016/j.micromeso.2018.06.022.

상세보기
Z. Guojie, L. Jiwei, X. Ying, and S. Yinghui, "A review of CH4-CO2 reforming to synthesis gasover Ni-based catalysts in recent years (2010-2017)", International Journal of Hydrogen Energy, Vol. 43, No. 32, 2018, pp. 15030-15054, doi: https://doi.org/10.1016/j.ijhydene.2018.06.091.

상세보기
L. Wenhui, L. Yi, M. Minchen, D. Fanshu, L. Zhongmin, G. Xinwen, and S. Chunshan, "Organic acid-assisted preparation of highly dispersed Co/ZrO2 catalysts with superior activity for CO2 methanation", Applied Catalysis B: Environmental, Vol. 254, 2019, pp. 531-540, doi: https://doi.org/10.1016/j.apcatb.2019.05.028.

상세보기
B. Zhoufeng, M. C. Yi, Y. Yang, and K. Sibudjing, "Morphology dependence of catalytic properties of Ni/CeO2 for CO2 methanation: a kinetic and mechanism study", Catalysis Today, Vol. 347, 2020, pp. 31-38, doi: https://doi.org/10.1016/j.cattod.2018.04.067.

상세보기
E. E. Benson, C. P. Kubiak, A. J. Sathrum, and J. M. Smieja, "Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels" Chem. Soc. Rev. Vol. 38, 2009, pp. 89-99, doi: https://doi.org/10.1039/B804323J.

상세보기
S. Alfredo, F. Jose, A. Armando, and C. Juan, "Participation of surface bicarbonate, formate and methoxy species in the carbon dioxide methanation catalyzed by ZrO2-supported Ni", Applied Catalysis B: Environmental, Vol. 218, 2017, pp. 611-620, doi: https://doi.org/10.1016/j.apcatb.2017.06.063.

상세보기
S. G. Edwin C. Narendraraj, V. K. Ivan, G. Aida, V. Enrique, S. Antonio, and N. Raveendran, "Highly efficient nickel-niobia composite catalysts for hydrogenation of CO2 to methane", Chemical Engineering Science, Vol. 194, 2019, pp. 2-9, doi: https://doi.org/10.1016/j.ces.2018.08.038.

상세보기
"InfoMine: Mining Intelligence & Technology".
J. B. Powell and S. H. Langer, "Low-temperature methanation and fischer-tropsch activity over supported ruthenium, nickel, and cobalt catalysts", J Catal, Vol. 94, 1985, pp. 556-569, doi: https://doi.org/10.1016/0021-9517(85)90222-2.

상세보기
E. Kok , J. Scott, N. Cant and D. Trimm, "The impact of ruthenium, lanthanum and activation conditions on the methanation activity of alumina-supported cobalt catalysts" Catal Today, Vol. 164, No. 1, 2011, pp. 297-301, doi: https://doi.org/10.1016/j.cattod.2010.11.011.

상세보기
G. H. Watson, "Methanation catalysts", IEA Coal Research, 1980.
P. Gerard and A. Beenackers, "Kinetics and selectivity of fischer-tropsch synthesis: a literature review', Catal Rev - Sci Eng, Vol. 41, No. 3-4, 1999, pp. 255-318, doi: https://doi.org/10.1081/CR-100101170.

상세보기
G. Iglesias, C. de Vries, M. Claeys, and G. Schaub, "Chemical energy storage in gaseous hydrocarbons via iron Fischer-Tropsch synthesis from H2/CO2 -kinetics, selectivity and process considerations", Catal Today, Vol. 242, 2015, pp. 184-192, doi: https://doi.org/10.1016/j.cattod.2014.05.020.

상세보기
G. Mills and F. Steffgen, "Catalytic methanation", Catal Rev, Vol. 8, No. 1, 1974, pp. 159-210, doi: https://doi.org/10.1080/01614947408071860.

상세보기
J. Gao, Q. Liu , F. Gu, B. Liu, Z. Zhong, and F. Su, "Recent advances in methanation catalysts for the production of synthetic natural gas", RSC Adv, Vol. 29, 2015, pp. 22759-22776, doi: https://doi.org/10.1039/C4RA16114A.

상세보기
M. Fan, K. Miao, J. Lin, H. Zhang, and D. Liao. "Mg-Al oxide supported Ni catalysts with enhanced stability for efficient synthetic natural gas from syngas", Appl Surf Sci, Vol. 307, 2014, pp. 682-688, doi: https://doi.org/10.1016/j.apsusc.2014.04.098.

상세보기
B. Wang, Y. Yao, M. Jiang, Z. Li, X. Ma, S. Qin, and Q. Sun, "Effect of cobalt and its adding sequence on the catalytic performance of MoO3/Al2O3 toward sulfur-resistant methanation", J Energy Chem, Vol. 23, No. 1, 2014, pp. 35-42, doi: https://doi.org/10.1016/S2095-4956(14)60115-7.

상세보기
H. Qin, C. Guo, Y. Wu, and J. Zhang, "Effect of La2O3 promoter on NiO/Al2O3 catalyst in CO methanation", Korean J Chem Eng, Vol. 31, 2014, pp. 1168-1173, doi: https://doi.org/10.1007/s11814-014-0013-7.

상세보기
Q. Liu, F. Gu, X. Lu, Y. Liu, H. Li, Z. Zhong, G. Xu, and F. Su, "Enhanced catalytic performances of Ni/Al2O3 catalyst via addition of V2O3 for CO methanation" Appl Catal A, Vol. 488, 2014, pp. 37-47, doi: https://doi.org/10.1016/j.apcata.2014.09.028.

상세보기
H. Liu, X. Zou, X. Wang, X. Lu, and W. Ding, "Effect of CeO2 addition on Ni/Al2O3 catalysts for methanation of carbon dioxide with hydrogen", J Nat Gas Chem, Vol. 21, No. 6, 2012, pp. 703-707, doi: https://doi.org/10.1016/S1003-9953(11)60422-2.

상세보기
C. Campbell and D. Goodman, "A surface science investigation of the role of potassium promoters in nickel catalysts for CO hydrogenation", Surf Sci, Vol. 123, 1982, pp. 413-426, doi: https://doi.org/10.1016/0039-6028(82)90337-5.

상세보기
S. Xiong, X. Jinghua, L. Binglian, D. Hongmin, H. Baolin, and H. Yanqiang, "Catalytic carbon dioxide hydrogenation to methane: a review of recent studies", Journal of energy chemistry, Vol. 25, No. 4, 2016, pp. 553-565, doi: https://doi.org/10.1016/j.jechem.2016.03.009.

상세보기
C. Isabelle, B. Alain, C. Albin, T. Sebastien, and R. Anne-Cecile, "Carbon dioxide methanation kinetic model on a commercial Ni/Al2O3 catalyst", Journal of CO2 Utilization, Vol. 34, 2019, pp. 256-265, doi: https://doi.org/10.1016/j.jcou.2019.05.030.

상세보기
H. Feiyang, T. Sai, L. Kun, C. Cheng-Meng, S. Fang-Yuan, Z. Jian, H. Zhang, W. Xuewen, F. Gang, and Z. Rongbin, "Reduced graphene oxide supported Ni-Ce catalysts for CO2 methanation: the support and ceria promotion effects", Journal of CO2 Utilization, Vol. 34, 2019, pp. 676-687, doi: https://doi.org/10.1016/j.jcou.2019.08.020.

상세보기
J. Haoxi, G. Qiang, W. Shutian, C. Yife, and .Z Minhua, "The synergistic effect of Pd NPs and UiO-66 for enhanced activity of carbon dioxide methanation", Journal of CO2 Utilization, Vol. 31, 2019, pp.167-172, doi: https://doi.org/10.1016/j.jcou.2019.03.011.

상세보기
O. Zhiliang, Q. Changlei, N. Juntian, Z. Lihui, and R. Jingyu, "A comprehensive DFT study of CO2 catalytic conversion by H2 over Pt-doped Ni catalysts", Journal of hydrogen energy, Vol. 44, No. 2, 2019, pp. 819-834, doi: https://doi.org/10.1016/j.ijhydene.2018.11.008.

상세보기
J. Y. Lim, J. McGregor, A. J. Sederman, and J. S. Dennis, "Kinetic studies of CO2 methanation over a Ni/γ-Al2O3 catalyst using a batch reactor", Chemical Engineering Science, Vol. 141, 2016, pp. 28-45, doi: https://doi.org/10.1016/j.ces.2015.10.026.

상세보기
A. Westermann, B. Azambre, M. C. Bacariza, I. Graca, M. F. Ribeiro, J. M. Lopes, and C. Henriques, "Insight into CO2 methanation mechanism over Ni-USY zeolites: anoperandoIR study", Applied Catalysis B: Environmental, Vol. 174-175, 2015, pp.120-125, doi: https://doi.org/10.1016/j.apcatb.2015.02.026.

상세보기
C.V. Miguel, A. Mendes, and L.M. Madeira, "Intrinsic kinetics of CO2 methanation over an industrial nickel-based catalyst", Journal of CO2 Utilization, Vol. 25, 2018, pp. 128-136, doi: https://doi.org/10.1016/j.jcou.2018.03.011.

상세보기
L. Yanping, Z. Hui, Z. Lianhong, and Z. Han, "Bimetallic NiePd/SBA-15 alloy as an effectivecatalyst for selective hydrogenation of CO2 to methane", International Journal of Hydrogen Energy, Vol. 44, No. 26, 2019, pp. 13354-13363, doi: https://doi.org/10.1016/j.ijhydene.2019.03.276.

상세보기
W. Li, H. Wang, Z. Jiang, J. Zhu, Z. Liu, X. Guo, and C. Song, "A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts", RSC Adv, Vol. 14, 2018, pp. 7651-7669, Retrieved from https://pubs.rsc.org/en/content/articlelanding/2018/ra/c7ra13546g.
W. Li, H.Wang, Z. Jiang, J. Zhu, Z. Liu, X. Guo, and C. Song, "A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts", RSC Adv, Vol. 14, 2018, pp. 7651-7669, Retrieved from https://pubs.rsc.org/en/content/articlelanding/2018/ra/c7ra13546g.
D. B. Han, Y. J. kim, H. S. Byun, W. J. Cho, and Y. S. Baek, "CO2 Methanation of Biogas over 20 wt% Ni-Mg-Al Catalyst: on the Effect of N2, CH4, and O2 on CO2 Conversion Rate", Catalysts, Vol. 10, No. 10, 2020, pp. 1201, doi: https://doi.org/10.3390/catal10101201.

상세보기
M. Benjamin, W.P. Carvalho, M. Stefan, K. Wolfgang, and G. Jan-Dierk, "Methanation of CO2: structural response of a Ni-based catalyst underfluctuating reaction conditions unraveled byoperandospectroscopy", Journal of Catalysis, Vol. 327, 2015, pp.48-53, doi: https://doi.org/10.1016/j.jcat.2015.04.006.

상세보기
M. J. Mohammad, A. N. Mohamad, and T. W. Paul, "Parametric study of CO2 methanation for synthetic natural gas production", Energy technology, Vol. 7, No. 11, 2019, pp. 1990795, doi: https://doi.org/10.1002/ente.201900795.

상세보기
X, Jia, X. Zhang, N. Rui, X. Hu, and C. J. Liu, "Structural effect of Ni/ZrO2 catalyst on CO2 methanation with enhanced activity", Applied Catalysis B: Environmental, Vol. 244, 2019, pp. 159-169, doi: https://doi.org/10.1016/j.apcatb.2018.11.024.

상세보기
L. Jurgensen, E.A Ehimen, J. Born, and J. B. Holm-Nielsen, "Dynamic biogas upgrading based on the sabatier process: thermodynamic and dynamic process simulation", Bioresour. Technol, Vol. 178, 2015, pp. 323-329, doi: https://doi.org/10.1016/j.biortech.2014.10.069.

상세보기
V. M. Vlasenko, G. E. Yuzefovich, and M. T. Rusov, "Kinet. Catal.", USER, Vol. 6, 1965, pp. 938.
J. Gao, Y. Wang, Y. Ping, D. Hu, G. Xu, F. Gu, and F. Su, "A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas", RSC Adv, Vol. 2, 2012, pp. 2358-2368, doi: https://doi.org/10.1039/C2RA00632D.

상세보기

저자의 다른 논문 :

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증