[논문]Oxidation of Fe-(5.3-29.8)%Mn-(1.1-1.9)%Al-0.45%C Alloys at 550-650 ℃

Park, Soon Yong; Xiao, Xiao; Kim, Min Ji; Lee, Geun Taek; Hwang, Dae Ho; Woo, Young Ho; Lee, Dong Bok

doi:10.14773/cst.2022.21.1.53

Oxidation of Fe-(5.3-29.8)%Mn-(1.1-1.9)%Al-0.45%C Alloys at 550-650 ℃ 원문보기

Corrosion science and technology, v.21 no.1, 2022년, pp.53 - 61

Park, Soon Yong (R&D Center, PIM KOREA) , Xiao, Xiao (School of Advanced Materials Science and Engineering, Sungkyunkwan University) , Kim, Min Ji (School of Advanced Materials Application, Korea Polytechnics) , Lee, Geun Taek (R&D Center, PIM KOREA) , Hwang, Dae Ho (R&D Center, PIM KOREA) , Woo, Young Ho (R&D Center, PIM KOREA) , Lee, Dong Bok (School of Advanced Materials Science and Engineering, Sungkyunkwan University)

Abstract ▼ AI-Helper

Alloys of Fe-(5.3-29.8)%Mn-(1.1-1.9)%Al-(0.4-0.5)%C were oxidized at 550 ℃ to 650 ℃ for 20 h to understand effects of alloying elements on oxidation. Their oxidation resistance increased with increasing Mn level to a small extent. Their oxidation kinetics changed from parabolic to linear when Mn content was decreased and temperature was increasing. Oxide scales primarily consisted of Fe2O3, Mn2O3, and MnFe2O4 without any protective Al-bearing oxides. During oxidation, Fe, Mn, and a lesser amount of Al diffused outward, while oxygen diffused inward to form internal oxides. Both oxide scales and internal oxides consisted of Fe, Mn, and a small amount of Al. The oxidation of Mn and carbon transformed γ-matrix to α-matrix in the subscale. The oxidation led to the formation of relatively thick oxide scales due to inherently inferior oxidation resistance of alloys and the formation of voids and cracks due to evaporation of manganese, decarburization, and outward diffusion of cations across oxides.

주제어

표/그림 (9)

그림 Fig. 1. XRD patterns of Fe-Mn-Al-C alloys
표 Table 1. Chemical composition of Fe-Mn-Al-C alloys
그림 Fig. 2. Oxidation curves of Fe, Mn, and Fe-Mn-Al-C alloys at (a) 550 ℃, (b) 600 ℃, (c) 650 ℃
그림 Fig. 3. Arrhenius plot of parabolic rate constants for the oxidation of Fe, Mn, and Fe-Mn-Al-C alloys. The k_p values for the oxidation of manganese in 1 atm of air [12,13] and oxygen [14,17] as well as iron in 1 atm of air and oxygen [18] are superimposed
그림 Fig. 4. Iron oxidized for 20 h. (a) XRD patterns at 550, 600, and 650 ℃, (b) cross-sectional SEM image at 600 ℃
그림 Fig. 5. Manganese oxidized for 20 h. (a) XRD patterns at 550, 600, and 650 ℃, (b) cross-sectional SEM image at 600 ℃
그림 Fig. 6. Fe-10.2Mn-1.9Al-0.5C alloy after oxidation at 650 ℃ for 20 h. (a) XRD pattern, (b) SEM cross-sectional image, (c) EPMA cross-sectional image, (d) EPMA maps of (c)
그림 Fig. 7. Fe-10.2Mn-1.9Al-0.5C alloy after oxidation at 600 ℃ for 20 h. (a) EPMA cross-sectional image, (b) EPMA maps of (a), (c) XRD pattern of the oxide scale
그림 Fig. 8. Fe-10.2Mn-1.9Al-0.5C alloy after oxidation at 550 ℃ for 20 h. (a) XRD pattern, (b) EPMA cross-sectional image, (c) EPMA maps of (b)

참고문헌 (24)

S. O. Kim, J. K. Hwang, and S. J. Kim, Effect of Alloying Elements (Cu, Al, Si) on the Electrochemical Corrosion Behaviors of TWIP Steel in a 3.5 % NaCl Solution, Corrosion Science and Technology, 18, 300 (2019). Doi: https://doi.org/10.14773/cst.2019.18.6.300

원문보기 상세보기
S. H. Kim, J. Y. Huh, M. S. Kim, and J. S. Kim, Effects of Oxygen Partial Pressure on Oxidation Behavior of CMnSi TRIP Steel in an Oxidation-Reduction Scheme, Corrosion Science and Technology, 16, 15 (2017). Doi: https://doi.org/10.14773/cst.2017.16.1.15

원문보기 상세보기
O. Bouaziz, S. Allain, C. Scott, P. Cugy, and D. Barbier, High Manganese Austenitic Twinning Induced Plasticity Steels: A Review of the Microstructure Properties Relationships, Current Opinion in Solid State and Materials Science, 15, 141 (2011). Doi: https://doi.org/10.1016/j.cossms.2011.04.002

상세보기
S. W. Park, J. Y. Park, K. M. Cho, J. H. Jang, S. J. Park, J. Moon, T. H. Lee, and J. H. Shin, Effect of Mn and C on Age Hardening of Fe-Mn-Al-C Lightweight Steels, Metals and Materials International, 25, 683 (2019). Doi: https://doi.org/10.1007/s12540-018-00230-x

상세보기
J. Moon, S. J. Park, and C. H. Lee, Current Status on Development of Lightweight Steels and Welding Characteristics, Journal of Welding and Joining, 38, 333 (2020). Doi: https://doi.org/10.5781/JWJ.2020.38.4.1

상세보기
P. R. S. Jackson and G. R. Wallwork, High Temperature Oxidation of Iron-Manganese-Aluminum Based Alloys, Oxidation of Metals, 21, 135 (1984). Doi: https://doi.org/10.1007/bf00741468

상세보기
C. J. Wang and Y. C. Chang, Formation and Growth Morphology of Nodules in the High-Temperature Oxidation of Fe-Mn-Al-C Alloy, Materials Chemistry and Physics, 77, 738 (2003). Doi: https://doi.org/10.1016/S0254-0584(02)00134-7

상세보기
J. G. Duh and C. J. Wang, Formation and Growth Morphology of Oxidation-induced Ferrite Layer in Fe-MnAl-Cr-C Alloys, Journal of Materials Science, 25, 2063 (1990). Doi: https://doi.org/10.1007/BF01045765

상세보기
J. G. Duh and C. J. Wang, High Temperature Oxidation of Fe-31 Mn-9Al-xCr-0.87C Alloys (x 0, 3 and 6), Journal of Materials Science, 25, 268 (1990). Doi: https://doi.org/10.1007/BF00544219

상세보기
J. P. Sauer, R. A. Rapp, and J. P. Hirth, Oxidation of Iron-Manganese-Aluminum Alloys at 850 and 1000 ℃, Oxidation of Metals, 18, 285 (1982). Doi: https://doi.org/10.1007/BF00656572

상세보기
P. Perez, F. J. Perez, C. Gomez, and P. Adevaa, Oxidation Behaviour of an Austenitic Fe-30Mn-5Al-0.5C Alloy, Corrosion Science, 44, 113 (2002). Doi: https://doi.org/10.1016/S0010-938X(01)00043-9

상세보기
H. Buscail and J. P. Larpin, The Influence of Ceria Surface Additions on Manganese Oxidation at High Temperatures, Oxidation of Metals, 43, 237 (1995). Doi: https://doi.org/10.1007/BF01047029

상세보기
E. B. Evans, C. A. Phalnikar, and W. M. Baldwin, High Temperature Scaling of Nickel-Manganese Alloys, Journal of the Electrochemical Society, 103, 367 (1956). Doi: https://doi.org/10.1149/1.2430358

상세보기
F. Gesmundo, C. de Asmundis, and C. Bottino, High-Temperature Corrosion of Manganese in Pure SO 2 , Oxidation of Metals, 14, 15 (1980). Doi: https://doi.org/10.1007/BF00604101

상세보기
V. D. F. C. Lins, M. A. Freitas, and E. M. D. P. e Silva, Oxidation Kinetics of an Fe-31.8Mn-6.09Al-1.60Si0.40C Alloys at Temperature from 600 to 900℃, Corrosion Science, 46, 1895 (2004). Doi: http://doi.org/10.1016/j.corsci.2003.10.015

상세보기
J. G. Duh, J. W. Lee, and C. J. Wang, Microstructural Development in the Oxidation-induced Phase Transformation of Fe-Al-Cr-Mn-C Alloys, Journal of Materials Science, 23, 2649 (1988). Doi: https://doi.org/10.1007/BF01111928

상세보기
F. Gesmundo, P. Nanni, and D. P. Whittle, High Temperature Oxidation of Co-Mn Alloys, Corrosion Science, 19, 675 (1979). Doi: https://doi.org/10.1016/S0010-938X(79)80140-7

상세보기
N. Bertrand, C. Desgranges, D. Poquillon, M. C. Lafont, and D. Monceau, Iron Oxidation at Low Temperature (260-500 ℃) in Air and the Effect of Water Vapor, Oxidation of Metals, 73, 139 (2010). Doi: https://doi.org/10.1007/s11085-009-9171-0

상세보기
N. Birks and G. H. Meier, Introduction to High Temperature Oxidation of Metals, p.72, Edward Arnold, London (1983). Doi: https://doi.org/10.1017/CBO9781139163903
L. Kjellqvist and M. Selleby, Thermodynamic Assessment of the Fe-Mn-O System, Journal of Phase Equilibria and Diffusion, 31, 113 (2010). Doi: https://doi.org/10.1007/s11669-009-9643-6

상세보기
K. Fueki and J. B. Wagner, Oxidation of Manganese in CO 2 -CO Mixtures, Journal of The Electrochemical Society, 112, 970 (1965). Doi: https://doi.org/10.1149/1.2423353

상세보기
I. Barin, Thermochemical Data of Pure Substances, 3rd ed., VCH, Germany (1989). Doi: https://doi.org/10.1002/9783527619825
F. H. Stott, F. I. Wei, and C. A. Enahoro, The Influence of Manganese on the High-Temperature Oxidation of Iron-chromium Alloys, Materials and Corrosion, 40, 198 (1989). Doi: https://doi.org/10.1002/maco.19890400403

상세보기
A. Muan and S. Somiya, The System Iron Oxide-Manganese Oxide in Air, American Journal of Science, 260, 230 (1962). Doi: https://doi.org/10.2475/ajs.260.3.230

상세보기

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증