[논문]페로브스카이트 태양전지 상용화를 위한 자외선 및 수분 안정성 향상 전략

황은혜; 권태혁

doi:10.21218/cpr.2022.10.2.049

페로브스카이트 태양전지 상용화를 위한 자외선 및 수분 안정성 향상 전략
A Brief Review on Strategies for Improving UV and Humidity Stability of Perovskite Solar Cells Towards Commercialization 원문보기

Current photovoltaic research = 한국태양광발전학회논문지, v.10 no.2, 2022년, pp.49 - 55

황은혜 (화학과 및 파동 에너지 재료 연구센터, 울산과학기술원) , 권태혁 (화학과 및 파동 에너지 재료 연구센터, 울산과학기술원)

Abstract ▼ AI-Helper

With rapid growth in light-harvesting efficiency from 3.8 to 25.8%, organic-inorganic hybrid perovskite solar cells (PSCs) have attracted great attention as promising photovoltaic devices. However, despite of their outstanding performance, the commercialization of PSCs has been suffered from severe stability issues, especially for UV and humidity: (i) UV irradiation towards PSCs is able to lead UV-induced decomposition of perovskite films or catalytic reactions of charge-transporting layers, and (ii) exposure to surrounding humidity causes irreversible hydration of perovskite layers by the penetration of water molecules, resulting considerable decrease in their power-conversion efficiency (PCE). This review investigates current status of strategies to enhance UV and humidity stability of PSCs in terms of UV-management and moisture protection, respectively. Furthermore, the multifunctional approach to increase long-term stability as well as performance is discussed as advanced research directions for the commercialization of PSCs.

주제어

표/그림 (7)

표 Table 1. Summarization of PSC performance with different strategies to improve stability
$Fig. 1. (a) Available fraction of AM 1.5G spectrum which PSC turns into electricity. Schematic diagram of (b) UV-induced degradation of PSCs, (c) UV cutoff strategy, and (d) frequency conversion strategy$ 그림 Fig. 1. (a) Available fraction of AM 1.5G spectrum which PSC turns into electricity. Schematic diagram of (b) UV-induced degradation of PSCs, (c) UV cutoff strategy, and (d) frequency conversion strategy
그림 Fig. 2. (a) Schematic diagram of UV cutoff for PSCs using UVabsorber (UV-234) (Top), EQE spectra (Bottom-left) and UV stability test of PSCs with and without UV-absorber coating (Bottom-right). Copyright 2017 Royal Society of Chemistry¹¹⁾. (b) Energy level diagram (Top-left) and UV-vis absorption spectra (Top-right) of the designed hole-transporting layers for p-i-n PSCs, EQE spectra (Bottom-left) and UV stability test of PSCs (Bottom-right). Copyright 2018 Royal Society of Chemistry¹²⁾
그림 Fig. 3. (a) Schematic diagram of outside photon downconversion coating for PSCs, and the resulting EQE and UV stability test. Copyright 2017 American Chemical Society¹⁸⁾. (b) Schematic diagram of photon downconversion as an interfacial layer for PSCs, and the resulting EQE and UV stability test. Copyright 2019 Royal Society of Chemistry¹⁹⁾
그림 Fig. 4. (a) Encapsulation of PSCs with adamantane (ADA) polymer. Copyright 2018 American Chemical Society²¹⁾. (b) Schematic diagram of sulfur-oleylamine surface modification. Copyright 2019 Royal Society of Chemistry²²⁾
그림 Fig. 5. (a) Normalized absorption and emission spectra of the photon downshifting layer (PDL) and the EQE of PSCs. (b) EQE of PSCs with and without PDL coating. (c) Contact angle of the PDL with water. (d) UV and humidity stability test of PSCs with and without PDL coating. Copyright 2016 American Association for the Advancement of Science²³⁾
그림 Fig. 6. (a) Schematic diagram of water-repellent photon downshifting layer (Pt-F) for PSCs. (b) Simultaneous side-coating of Pt-F by ultrasonic spray deposition (USD) method. (c) EQE spectra, (d) UV stability test, and (e) humidity stability test of PSCs with and without Pt-F coating. Copyright 2020 John Wiley and Sons²⁴⁾

참고문헌 (24)

Kojima, A., Teshima, K., Shirai, Y. and Miyasaka, T., "Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells," J. Am. Chem. Soc., 131, 6050-6051 (2009).

상세보기
Min, H., Lee, D. Y., Kim, J., Kim, G., Lee, K. S., Kim, J., Paik, M. J., Kim, Y. K., Kim, K. S., Kim, M. G., Shin, T. J., and Seok, S. I., "Perovskite solar cells with atomically coherent interlayers on SnO 2 electrodes," Nature, 598, 444-450 (2021).

상세보기
Saki, Z., Byranvand, M. M., Taghavinia, N., Kedia, M., and Saliba, M., "Solution-processed perovskite thin-films: the journey from lab- to large-scale solar cells," Energy Environ. Sci., 14, 5690-5722 (2021).

상세보기
Sum, T. C., Chen, S., Xing, G., Liu, X., and Wu, B., "Energetics and dynamics in organic-inorganic halide perovskite photovoltaics and light emitters," Nanotechnology, 26, 342001 (2015).

상세보기
Herz, L. M., "Charge-Carrier Mobilities in Metal Halide Perovskites: Fundamental Mechanisms and Limits," ACS Energy Lett., 2, 1539-1548 (2017).

상세보기
Ito, S., Tanaka, S., Manabe, K., and Nishino, H., "Effects of Surface Blocking Layer of Sb 2 S 3 on Nanocrystalline TiO 2 for CH 3 NH 3 PbI 3 Perovskite Solar Cells," J. Phys. Chem. C, 118, 30, 16995-17000 (2014).

상세보기
Ji, J., Liu, X., Jiang, H., Duan, M., Liu, B., Huang, H., Wei, D., Li, Y., and Li, M., "Two-Stage Ultraviolet Degradation of Perovskite Solar Cells Induced by the Oxygen Vacancy-Ti 4+ States," iScience, 23, 101013 (2020).

상세보기
Li, B., Li, Y., Zheng, C., Gao, D., and Huang, W., "Advancements in the stability of perovskite solar cells: degradation mechanisms and improvement approaches," RSC Adv., 6, 38079-38091 (2016).

상세보기
Chen, W., Wu, Y., Yue, Y., Liu, J., Zhang, W., Yang, X., Chen, H., Bi, E., Ashraful, I., Gratzel, M., and Han, L., "Efficient and stable large-areaperovskite solar cells with inorganiccharge extraction layers," Science, 350, 944-948 (2015).

상세보기
Tan, F., Saidaminov, M. I., Tan, H., Fan, J. Z., Wang, Y., Yue, S., Wang, X., Shen, Z., Li, S., Kim, J., Gao, Y., Yue, G., Liu, R., Huang, Z., Dong, C., Hu, X., Zhang, W., Wang, Z., Qu, S., Wang, Z., and Sargent, E. H., "Dual Coordination of Ti and Pb Using Bilinkable Ligands Improves Perovskite Solar Cell Performance and Stability," Adv. Funct. Mater., 30, 2005155 (2020).

상세보기
Sun, Y., Fang, X., Ma, Z., Xu, L., Lu, Y., Yu, Q., Yuan, N., and Ding, J., "Enhanced UV-light stability of organometal halide perovskite solar cells with interface modification and a UV absorption layer," J. Mater. Chem. C, 5, 8682-8687 (2017).

상세보기
Tsai, C.-H., Li, N., Lee, C.-C., Wu, H.-C., Zhu, Z., Wang, L., Chen, W.-C., Yan, H., and Chueh, C.-C., "Efficient and UV-stable perovskite solar cells enabled by side chain-engineered polymeric hole transporting layers," J. Mater. Chem. A, 6, 12999-13004 (2018).

상세보기
An, Y., Wang, C., Cao, G., and Li, X., "Heterojunction Perovskite Solar Cells: OptoElectro-Thermal Physics, Modeling, and Experiment," ACS Nano, 14, 5017-5026 (2020).

상세보기
Trupke, T., Green, M. A., and Wurfel, P., "Improving solar cell efficiencies by down-conversion of high-energy photons," J. Appl. Phys. 92, 1668 (2002).

상세보기
Florencio, L. A., Gomez-Malagon, L. A., Lima, B. C., Gomes, A. S.L., Garcia, J.A.M., and Kassab, L. R.P., "Efficiency enhancement in solar cells using photon down-conversion in Tb/Yb-doped tellurite glass," Sol. Energy Mater. Sol. Cells, 157, 468-475 (2016).

상세보기
Wang, H.-P. and He, Jr-H., "Toward Highly Efficient Nanostructured Solar Cells Using Concurrent Electrical and Optical Design," Adv. Energy Mater., 7, 1602385 (2017).

상세보기
Mora, M.B., Amelines-Sarria, O., Monroy, B.M., Hernandez-Perez, C.D., and Lugo, J.E., "Materials for downconversion in solar cells: Perspectives," Sol. Energy Mater Sol. Cells, 165, 59-71 (2017).

상세보기
Jiang, L., Chen, W. Zheng, J., Zhu, L., Mo, L., Li, Z., Hu, L., Hayat, T., Alsaedi, A. Zhang, C., and Dai, S., "Enhancing the Photovoltaic Performance of Perovskite Solar Cells with a Down-Conversion Eu-Complex," ACS Appl. Mater. Interfaces, 9, 26958-26964 (2017).

상세보기
Rahman, N. U., Khan, W. U., Khan, S., Chen, X., Khan, J., Zhao, J., Yang, Z., Wu, M., and Chi, Z., "A promising europium-based down conversion material: organic-inorganic perovskite solar cells with high photovoltaic performance and UV-light stability," J. Mater. Chem. A, 7, 6467-6474 (2019).

상세보기
Tai, Q., You, P., Sang, H., Liu, Z., Hu, C., Chan, H. L.W., and Yan, F., "Efficient and stable perovskite solar cells prepared in ambient air irrespective of the humidity," Nat. Commun., 7, 11105 (2016).

상세보기
Idigoras, J., Aparicio, F. J., Contreras-Bernal, L., Ramos-Terron, S., Alcaire, M., Sanchez-Valencia, J. R., Borras, A., Barranco, A., and Anta, J. A., "Enhancing Moisture and Water Resistance in Perovskite Solar Cells by Encapsulation with Ultrathin Plasma Polymers," ACS Appl. Mater. Interfaces, 10, 11587-11594 (2018).

상세보기
Hou, Y., Zhou, Z. R., Wen, T. Y., Qiao, H. W., Lin, Z. Q., Ge, B., and Yang, H. G., "Enhanced moisture stability of metal halide perovskite solar cells based on sulfur-oleylamine surface modification," Nanoscale Horiz., 4, 208-213 (2019).

상세보기
Bella, F., Griffini, G., Correa-Baena, J.-P., Saracco, G., Gratzel, M., Hagfeldt, A., Turri, S., and Gerbaldi, C., "Improving efficiency and stability ofperovskite solar cells withphotocurable fluoropolymers," Science, 354, 203-206 (2016).

상세보기
Hwang, E., Kim, H., Lee, S.-H., Seo, J. H., Kim, H.-T., Lee, C., Jang, S.-Y., Seo, K., Kwon, T.-H., "Fabrication of Water-Repellent Platinum(II) Complex-Based Photon Downshifting Layers for Perovskite Solar Cells by Ultrasonic Spray Deposition," Adv. Energy Mater., 10, 2001238 (2020).

상세보기

저자의 다른 논문 :

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증