[논문]양극산화 방법을 이용한 기능성 알루미늄 3003 합금의 표면 특성 및 부식 거동 연구

김지수; 정찬영

doi:10.14773/cst.2022.21.4.290

양극산화 방법을 이용한 기능성 알루미늄 3003 합금의 표면 특성 및 부식 거동 연구
A Study on the Surface Properties and Corrosion Behavior of Functional Aluminum 3003 Alloy using Anodization Method 원문보기

Corrosion science and technology, v.21 no.4, 2022년, pp.290 - 299

Abstract ▼ AI-Helper

Anodizing is an electrochemical surface treatment method conferring corrosion resistance and durability by forming a thick anodization film on the metal surface. Aluminum has a long service life and high thermal conductivity and formability, as well as excellent corrosion resistance. Aluminum 3003 alloy has improved formability, strength, and corrosion resistance due to the addition of a small amount of manganese. However, corrosion occurs in seawater and environments polluted with corrosion-inducing substances, which reduce corrosion resistance. Therefore, it is necessary to artificially form a thick anodized film to improve corrosion resistance. In this study, the anodization treatment time was 4 minutes, and voltages of 10 V, 20 V, 30 V, 40 V, 50 V, 60 V, 70 V, 80 V, 90 V, and 100 V were applied. The thickness and pore size of the oxide film increased according to the applied voltage. A barrier film was formed under voltage conditions from 10 V to 50 V, and a porous film was formed under voltage conditions from 60 V to 100 V. After anodizing, coating was applied. Wettability and corrosion resistance were observed before and after coating according to the surface shape and thickness of the oxide film.

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표/그림 (15)

그림 Fig. 1. Schematic diagram of penetration of corrosion-inducing substances in anodized films produced at low and high voltages
그림 Fig. 2. Top view and cross view of aluminum 3003 alloy SEM image that is anodized by applying a voltage of 10 V, 20 V, 30 V, 40 V, 50 V, 60 V, 70 V, 80 V, 90 V and 100 V
그림 Fig. 3. A graph of oxide film thickness growth according to applied voltage for anodization
$Table 1. Measurement of oxide film thickness, pore size, interpore distance, and solid fraction of anodized aluminum 3003 alloy by applying different voltages$ 표 Table 1. Measurement of oxide film thickness, pore size, interpore distance, and solid fraction of anodized aluminum 3003 alloy by applying different voltages
표 Table 2. Analysis of composition and content by EDS of oxide film for different applied voltages
그림 Fig. 4. EDS component analysis result, aluminum and oxygen content graph by anodization at different voltages
그림 Fig. 5. XPS spectra of (a) Al 2p and (b) O 1s regions after anodization at 100 V for 4 minutes
그림 Fig. 6. Contact angle images of the surface after anodization for different voltages
그림 Fig. 7. Contact angle images of SAM coated surfaces after preliminary anodized for different voltages
그림 Fig. 8. Graphs of contact angles before and after coating of surfaces anodized with different voltages; (a) before coating (b) after coating
표 Table 3. Contact angles before and after coating of anodized oxide films with different voltages
그림 Fig. 9. Electrochemical polarization curves in 3.5 wt% NaCl solution of oxide films produced by anodization at different voltages
그림 Fig. 10. Electrochemical polarization curves in 3.5 wt% NaCl solution after coating of aluminum oxide films produced by anodization at different voltages
표 Table 4. Corrosion current density (I_corr) and corrosion potential (E_corr) of the uncoated surface after anodization as a result of the Potential polarization test
표 Table 5. Corrosion current density (I_corr) and corrosion potential (E_corr) of the coated surface after anodization as a result of the potential polarization test

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